Displaying publications 1 - 20 of 51 in total

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  1. Alsalahi MA, Latif MT, Ali MM, Magam SM, Wahid NB, Khan MF, et al.
    Mar Pollut Bull, 2014 Mar 15;80(1-2):344-50.
    PMID: 24373668 DOI: 10.1016/j.marpolbul.2013.12.019
    This study aims to determine the levels of methylene blue active substances (MBAS) and ethyl violet active substances (EVAS) as anionic surfactants and of disulphine blue active substances (DBAS) as cationic surfactants in the surface microlayer (SML) around an estuarine area using colorimetric methods. The results show that the concentrations of surfactants around the estuarine area were dominated by anionic surfactants (MBAS and EVAS) with average concentrations of 0.39 and 0.51 μmol L⁻¹, respectively. There were significant between-station differences in surfactant concentrations (p<0.05) with higher concentrations found at the stations near the sea. The concentration of surfactants was higher during the rainy season than the dry season due to the influence of runoff water. Further investigation using total organic carbon (TOC) and total organic nitrogen (TON) shows that there is a significant correlation (p<0.05) between both anionic and cationic surfactants and the TON concentration.
  2. Mustaffa NI, Latif MT, Ali MM, Khan MF
    Environ Sci Pollut Res Int, 2014 May;21(10):6590-602.
    PMID: 24532245 DOI: 10.1007/s11356-014-2562-z
    This study aims to determine the source apportionment of surfactants in marine aerosols at two selected stations along the Malacca Straits. The aerosol samples were collected using a high volume sampler equipped with an impactor to separate coarse- and fine-mode aerosols. The concentrations of surfactants, as methylene blue active substance and disulphine blue active substance, were analysed using colorimetric method. Ion chromatography was employed to determine the ionic compositions. Principal component analysis combined with multiple linear regression was used to identify and quantify the sources of atmospheric surfactants. The results showed that the surfactants in tropical coastal environments are actively generated from natural and anthropogenic origins. Sea spray (generated from sea-surface microlayers) was found to be a major contributor to surfactants in both aerosol sizes. Meanwhile, the anthropogenic sources (motor vehicles/biomass burning) were predominant contributors to atmospheric surfactants in fine-mode aerosols.
  3. Latif MT, Dominick D, Ahamad F, Khan MF, Juneng L, Hamzah FM, et al.
    Sci Total Environ, 2014 Jun 1;482-483:336-48.
    PMID: 24662202 DOI: 10.1016/j.scitotenv.2014.02.132
    Rural background stations provide insight into seasonal variations in pollutant concentrations and allow for comparisons to be made with stations closer to anthropogenic emissions. In Malaysia, the designated background station is located in Jerantut, Pahang. A fifteen-year data set focusing on ten major air pollutants and four meteorological variables from this station were analysed. Diurnal, monthly and yearly pollutant concentrations were derived from hourly continuous monitoring data. Statistical methods employed included principal component regression (PCR) and sensitivity analysis. Although only one of the yearly concentrations of the pollutants studied exceeded national and World Health Organisation (WHO) guideline standards, namely PM10, seven of the pollutants (NO, NO2, NOx, O3, PM10, THC and CH4) showed a positive upward trend over the 15-year period. High concentrations of PM10 were recorded during severe haze episodes in this region. Whilst, monthly concentrations of most air pollutants, such as: PM10, O3, NOx, NO2, CO and NmHC were recorded at higher concentrations between June and September, during the southwest monsoon. Such results correspond with the mid-range transport of pollutants from more urbanised and industrial areas. Diurnal patterns, rationed between major air pollutants and sensitivity analysis, indicate the influence of local traffic emissions on air quality at the Jerantut background station. Although the pollutant concentrations have not shown a rapid increase, an alternative background station will need to be assigned within the next decade if development projects in the surrounding area are not halted.
  4. Jaafar SA, Latif MT, Chian CW, Han WS, Wahid NB, Razak IS, et al.
    Mar Pollut Bull, 2014 Jul 15;84(1-2):35-43.
    PMID: 24930738 DOI: 10.1016/j.marpolbul.2014.05.047
    This study was conducted to determine the composition of surfactants in the sea-surface microlayer (SML) and atmospheric aerosol around the southern region of the Peninsular Malaysia. Surfactants in samples taken from the SML and atmospheric aerosol were determined using a colorimetric method, as either methylene blue active substances (MBAS) or disulphine blue active substances (DBAS). Principal component analysis with multiple linear regressions (PCA-MLR), using the anion and major element composition of the aerosol samples, was used to determine possible sources of surfactants in atmospheric aerosol. The results showed that the concentrations of surfactants in the SML and atmospheric aerosol were dominated by anionic surfactants and that surfactants in aerosol were not directly correlated (p>0.05) with surfactants in the SML. Further PCA-MLR from anion and major element concentrations showed that combustion of fossil fuel and sea spray were the major contributors to surfactants in aerosol in the study area.
  5. Ee-Ling O, Mustaffa NI, Amil N, Khan MF, Latif MT
    Bull Environ Contam Toxicol, 2015 Apr;94(4):537-42.
    PMID: 25652682 DOI: 10.1007/s00128-015-1477-9
    This study determined the source contribution of PM2.5 (particulate matter <2.5 μm) in air at three locations on the Malaysian Peninsula. PM2.5 samples were collected using a high volume sampler equipped with quartz filters. Ion chromatography was used to determine the ionic composition of the samples and inductively coupled plasma mass spectrometry was used to determine the concentrations of heavy metals. Principal component analysis with multilinear regressions were used to identify the possible sources of PM2.5. The range of PM2.5 was between 10 ± 3 and 30 ± 7 µg m(-3). Sulfate (SO4 (2-)) was the major ionic compound detected and zinc was found to dominate the heavy metals. Source apportionment analysis revealed that motor vehicle and soil dust dominated the composition of PM2.5 in the urban area. Domestic waste combustion dominated in the suburban area, while biomass burning dominated in the rural area.
  6. Razak IS, Latif MT, Jaafar SA, Khan MF, Mushrifah I
    Environ Sci Pollut Res Int, 2015 Apr;22(8):6024-33.
    PMID: 25382497 DOI: 10.1007/s11356-014-3781-z
    This study was conducted to determine the composition of surfactants in atmospheric aerosols and rainwater in the vicinity of Lake Chini, Malaysia. Samples of atmospheric aerosol and rainwater were collected between March and September 2011 using a high volume air sampler (HVAS) and glass bottles equipped with funnel. Colorimetric analysis was undertaken to determine the concentration of anionic surfactants as methylene blue active substances (MBAS) and cationic surfactants as disulphine blue active substances (DBAS). The water-soluble ionic compositions were determined using inductively coupled plasma mass spectrometry for cations (Na, K, Mg and Ca) and ion chromatography equipped with a conductivity detector for anions (F(-), Cl(-), NO3(-), and SO4(2-)) and the Nessler Method was used to obtain the NH4(+) concentrations. The source apportionment of MBAS and DBAS in atmospheric aerosols was identified using a combination of principal component analysis (PCA) and multiple linear regression (MLR). The results revealed that the concentrations of surfactants in atmospheric aerosols and rainwater were dominated by anionic surfactants as MBAS. The concentration of surfactants as MBAS and DBAS was dominated in fine mode compared to coarse mode aerosols. Using PCA/MLR analysis, two major sources of atmospheric surfactants to Lake Chini were identified as soil dust (75 to 93%) and biomass burning (2 to 22%).
  7. Alsalahi MA, Latif MT, Ali MM, Dominick D, Khan MF, Mustaffa NI, et al.
    Mar Pollut Bull, 2015 Apr 15;93(1-2):278-83.
    PMID: 25682566 DOI: 10.1016/j.marpolbul.2015.01.011
    This study aims to determine the concentration of sterols used as biomarkers in the surface microlayer (SML) in estuarine areas of the Selangor River, Malaysia. Samples were collected during different seasons through the use of a rotation drum. The analysis of sterols was performed using gas chromatography equipped with a flame ionisation detector (GC-FID). The results showed that the concentrations of total sterols in the SML ranged from 107.06 to 505.55 ng L(-1). The total sterol concentration was found to be higher in the wet season. Cholesterol was found to be the most abundant sterols component in the SML. The diagnostic ratios of sterols show the influence of natural sources and waste on the contribution of sterols in the SML. Further analysis, using principal component analysis (PCA), showed distinct inputs of sterols derived from human activity (40.58%), terrigenous and plant inputs (22.59%) as well as phytoplankton and marine inputs (17.35%).
  8. Khan MF, Latif MT, Amil N, Juneng L, Mohamad N, Nadzir MS, et al.
    Environ Sci Pollut Res Int, 2015 Sep;22(17):13111-26.
    PMID: 25925145 DOI: 10.1007/s11356-015-4541-4
    Principal component analysis (PCA) and correlation have been used to study the variability of particle mass and particle number concentrations (PNC) in a tropical semi-urban environment. PNC and mass concentration (diameter in the range of 0.25->32.0 μm) have been measured from 1 February to 26 February 2013 using an in situ Grimm aerosol sampler. We found that the 24-h average total suspended particulates (TSP), particulate matter ≤10 μm (PM10), particulate matter ≤2.5 μm (PM2.5) and particulate matter ≤1 μm (PM1) were 14.37 ± 4.43, 14.11 ± 4.39, 12.53 ± 4.13 and 10.53 ± 3.98 μg m(-3), respectively. PNC in the accumulation mode (<500 nm) was the most abundant (at about 99 %). Five principal components (PCs) resulted from the PCA analysis where PC1 (43.8 % variance) predominates with PNC in the fine and sub-microme tre range. PC2, PC3, PC4 and PC5 explain 16.5, 12.4, 6.0 and 5.6 % of the variance to address the coarse, coarser, accumulation and giant fraction of PNC, respectively. Our particle distribution results show good agreement with the moderate resolution imaging spectroradiometer (MODIS) distribution.
  9. Mohamad N, Latif MT, Khan MF
    Ecotoxicol Environ Saf, 2016 Feb;124:351-362.
    PMID: 26590697 DOI: 10.1016/j.ecoenv.2015.11.002
    This study aimed to investigate the chemical composition and potential sources of PM10 as well as assess the potential health hazards it posed to school children. PM10 samples were taken from classrooms at a school in Kuala Lumpur's city centre (S1) and one in the suburban city of Putrajaya (S2) over a period of eight hours using a low volume sampler (LVS). The composition of the major ions and trace metals in PM10 were then analysed using ion chromatography (IC) and inductively coupled plasma-mass spectrometry (ICP-MS), respectively. The results showed that the average PM10 concentration inside the classroom at the city centre school (82µg/m(3)) was higher than that from the suburban school (77µg/m(3)). Principal component analysis-absolute principal component scores (PCA-APCS) revealed that road dust was the major source of indoor PM10 at both school in the city centre (36%) and the suburban location (55%). The total hazard quotient (HQ) calculated, based on the formula suggested by the United States Environmental Protection Agency (USEPA), was found to be slightly higher than the acceptable level of 1, indicating that inhalation exposure to particle-bound non-carcinogenic metals of PM10, particularly Cr exposure by children and adults occupying the school environment, was far from negligible.
  10. Jaafar SA, Latif MT, Razak IS, Shaharudin MZ, Khan MF, Wahid NBA, et al.
    Mar Pollut Bull, 2016 Aug 15;109(1):480-489.
    PMID: 27230987 DOI: 10.1016/j.marpolbul.2016.05.017
    This study determined the effect of monsoonal changes on the composition of atmospheric surfactants in coastal areas. The composition of anions (SO4(2-), NO3(-), Cl(-), F(-)) and the major elements (Ca, K, Mg, Na) in aerosols were used to determine the possible sources of surfactants. Surfactant compositions were determined using a colorimetric method as methylene blue active substances (MBAS) and disulphine blue active substances (DBAS). The anion and major element compositions of the aerosol samples were determined by ion chromatography (IC) and inductively coupled plasma mass spectrometry (ICP-MS), respectively. The results indicated that the concentrations of surfactant in aerosols were dominated by MBAS (34-326pmolm(-3)). Monsoonal changes were found to significantly affect the concentration of surfactants. Using principal component analysis-multiple linear regressions (PCA-MLR), major possible sources for surfactants in the aerosols were motor vehicle emissions, secondary aerosol and the combustion of biomass along with marine aerosol.
  11. Rana MM, Sulaiman N, Sivertsen B, Khan MF, Nasreen S
    Environ Sci Pollut Res Int, 2016 Sep;23(17):17393-403.
    PMID: 27230142 DOI: 10.1007/s11356-016-6950-4
    Dhaka and its neighboring areas suffer from severe air pollution, especially during dry season (November-April). We investigated temporal and directional variations in particulate matter (PM) concentrations in Dhaka, Gazipur, and Narayanganj from October 2012 to March 2015 to understand different aspects of PM concentrations and possible sources of high pollution in this region. Ninety-six-hour backward trajectories for the whole dry season were also computed to investigate incursion of long-range pollution into this area. We found yearly PM10 concentrations in this area about three times and yearly PM2.5 concentrations about six times greater than the national standards of Bangladesh. Dhaka and its vicinity experienced several air pollution episodes in dry season when PM2.5 concentrations were 8-13 times greater than the World Health Organization (WHO) guideline value. Higher pollution and great contribution of PM2.5 most of the time were associated with the north-westerly wind. Winter (November to January) was found as the most polluted season in this area, when average PM10 concentrations in Dhaka, Gazipur, and Narayanganj were 257.1, 240.3, and 327.4 μg m(-3), respectively. Pollution levels during wet season (May-October) were, although found legitimate as per the national standards of Bangladesh, exceeded WHO guideline value in 50 % of the days of that season. Trans-boundary source identifications using concentration-weighted trajectory method revealed that the sources in the eastern Indian region bordering Bangladesh, in the north-eastern Indian region bordering Nepal and in Nepal and its neighboring areas had high probability of contributing to the PM pollutions at Gazipur station.
  12. Sahani M, Sulaiman NS, Tan BS, Yahya NA, Anual ZF, Mahiyuddin WR, et al.
    J Air Waste Manag Assoc, 2016 Nov;66(11):1077-1083.
    PMID: 27192328 DOI: 10.1080/10962247.2016.1188866
    Dental amalgam in fillings exposes workers to mercury. The exposure to mercury was investigated among 1871 dental health care workers. The aim of the study was to evaluate the risk of mercury exposure among dental compared to nondental health care workers and to determine other risk factors for mercury exposure. Respondents answered questionnaires to obtain demographic, personal, professional, and workplace information and were examined for their own amalgam fillings. Chronic mercury exposure was assessed through urinary mercury levels. In total, 1409 dental and 462 nondental health care workers participated in the study. Median urine mercury levels for dental and nondental health care workers were 2.75 μg/L (interquartile range [IQR] = 3.0175) and 2.66 μg/L (IQR = 3.04) respectively. For mercury exposure, there were no significant risk factor found among the workers involved within the dental care. The Mann-Whitney test showed that urine mercury levels were significantly different between respondents who eat seafood more than 5 times per week compared to those who eat it less frequently or not at all (p = 0.003). The urinary mercury levels indicated significant difference between dental workers in their practice using squeeze cloths (Mann-Whitney test, p = 0.03). Multiple logistic regression showed that only the usage of cosmetic products that might contain mercury was found to be significantly associated with the urinary mercury levels (odds ratio [OR] = 15.237; CI: 3.612-64.276). Therefore, mean urinary mercury levels of health care workers were low. Exposure to dental amalgam is not associated with high mercury exposure. However, usage of cosmetic products containing mercury and high seafood consumption may lead to the increase of exposure to mercury.

    IMPLICATIONS: Exposure to the high levels of mercury from dental amalgam can lead to serious health effects among the dental health care workers. Nationwide chronic mercury exposure among dental personnel was assessed through urinary mercury levels. Findings suggest low urinary mercury levels of these health care workers. Exposure to dental amalgam is not associated with high mercury exposure. However, the usage of cosmetic products containing mercury and high seafood consumption may lead to the increase of exposure to mercury.
  13. Latif MT, Dominick D, Ahamad F, Ahamad NS, Khan MF, Juneng L, et al.
    Sci Total Environ, 2016 Dec 15;573:494-504.
    PMID: 27572541 DOI: 10.1016/j.scitotenv.2016.08.121
    Malaysian Borneo has a lower population density and is an area known for its lush rainforests. However, changes in pollutant profiles are expected due to increasing urbanisation and commercial-industrial activities. This study aims to determine the variation of surface O3concentration recorded at seven selected stations in Malaysian Borneo. Hourly surface O3data covering the period 2002 to 2013, obtained from the Malaysian Department of Environment (DOE), were analysed using statistical methods. The results show that the concentrations of O3recorded in Malaysian Borneo during the study period were below the maximum Malaysian Air Quality Standard of 100ppbv. The hourly average and maximum O3concentrations of 31 and 92ppbv reported at Bintulu (S3) respectively were the highest among the O3concentrations recorded at the sampling stations. Further investigation on O3precursors show that sampling sites located near to local petrochemical industrial activities, such as Bintulu (S3) and Miri (S4), have higher NO2/NO ratios (between 3.21 and 5.67) compared to other stations. The normalised O3values recorded at all stations were higher during the weekend compared to weekdays (unlike its precursors) which suggests the influence of O3titration by NO during weekdays. The results also show that there are distinct seasonal variations in O3across Borneo. High surface O3concentrations were usually observed between August and September at all stations with the exception of station S7 on the east coast. Majority of the stations (except S1 and S6) have recorded increasing averaged maximum concentrations of surface O3over the analysed years. Increasing trends of NO2and decreasing trends of NO influence the yearly averaged maximum of O3especially at S3. This study also shows that variations of meteorological factors such as wind speed and direction, humidity and temperature influence the concentration of surface O3.
  14. Sakai N, Yamamoto S, Matsui Y, Khan MF, Latif MT, Ali Mohd M, et al.
    Sci Total Environ, 2017 May 15;586:1279-1286.
    PMID: 28236484 DOI: 10.1016/j.scitotenv.2017.02.139
    Volatile Organic Compounds (VOCs) in indoor air were investigated at 39 private residences in Selangor State, Malaysia to characterize the indoor air quality and to identify pollution sources. Twenty-two VOCs including isomers (14 aldehydes, 5 aromatic hydrocarbons, acetone, trichloroethylene and tetrachloroethylene) were collected by 2 passive samplers for 24h and quantitated using high performance liquid chromatography and gas chromatography mass spectrometry. Source profiling based on benzene/toluene ratio as well as statistical analysis (cluster analysis, bivariate correlation analysis and principal component analysis) was performed to identify pollution sources of the detected VOCs. The VOCs concentrations were compared with regulatory limits of air quality guidelines in WHO/EU, the US, Canada and Japan to clarify the potential health risks to the residents. The 39 residences were classified into 2 groups and 2 ungrouped residences based on the dendrogram in the cluster analysis. Group 1 (n=30) had mainly toluene (6.87±2.19μg/m3), formaldehyde (16.0±10.1μg/m3), acetaldehyde (5.35±4.57μg/m3) and acetone (11.1±5.95μg/m3) at background levels. Group 2 (n=7) had significantly high values of formaldehyde (99.3±10.7μg/m3) and acetone (35.8±12.6μg/m3), and a tendency to have higher values of acetaldehyde (23.7±13.5μg/m3), butyraldehyde (3.35±0.41μg/m3) and isovaleraldehyde (2.30±0.39μg/m3). The 2 ungrouped residences showed particularly high concentrations of BTX (benzene, toluene and xylene: 235μg/m3 in total) or acetone (133μg/m3). The geometric mean value of formaldehyde (19.2μg/m3) exceeded an 8-hour regulatory limit in Canada (9μg/m3), while those in other compounds did not exceed any regulatory limits, although a few residences exceeded at least one regulatory limit of benzene or acetaldehyde. Thus, the VOCs in the private residences were effectively characterized from the limited number of monitoring, and the potential health risks of the VOCs exposure, particularly formaldehyde, should be considered in the study area.
  15. Nadzir MSM, Lin CY, Khan MF, Latif MT, Dominick D, Hamid HHA, et al.
    Environ Sci Pollut Res Int, 2017 Jun;24(18):15278-15290.
    PMID: 28500553 DOI: 10.1007/s11356-017-9131-1
    Open biomass burning in Peninsula Malaysia, Sumatra, and parts of the Indochinese region is a major source of transboundary haze pollution in the Southeast Asia. To study the influence of haze on rainwater chemistry, a short-term investigation was carried out during the occurrence of a severe haze episode from March to April 2014. Rainwater samples were collected after a prolonged drought and analyzed for heavy metals and major ion concentrations using inductively coupled plasma mass spectroscopy (ICP-MS) and ion chromatography (IC), respectively. The chemical composition and morphology of the solid particulates suspended in rainwater were examined using a scanning electron microscope coupled with energy-dispersive X-ray spectroscopy (SEM-EDS). The dataset was further interpreted using enrichment factors (EF), statistical analysis, and a back trajectory (BT) model to find the possible sources of the particulates and pollutants. The results show a drop in rainwater pH from near neutral (pH 6.54) to acidic (
  16. Sulong NA, Latif MT, Khan MF, Amil N, Ashfold MJ, Wahab MIA, et al.
    Sci Total Environ, 2017 Dec 01;601-602:556-570.
    PMID: 28575833 DOI: 10.1016/j.scitotenv.2017.05.153
    This study aims to determine PM2.5concentrations and their composition during haze and non-haze episodes in Kuala Lumpur. In order to investigate the origin of the measured air masses, the Numerical Atmospheric-dispersion Modelling Environment (NAME) and Global Fire Assimilation System (GFAS) were applied. Source apportionment of PM2.5was determined using Positive Matrix Factorization (PMF). The carcinogenic and non-carcinogenic health risks were estimated using the United State Environmental Protection Agency (USEPA) method. PM2.5samples were collected from the centre of the city using a high-volume air sampler (HVS). The results showed that the mean PM2.5concentrations collected during pre-haze, haze and post-haze periods were 24.5±12.0μgm-3, 72.3±38.0μgm-3and 14.3±3.58μgm-3, respectively. The highest concentration of PM2.5during haze episode was five times higher than World Health Organisation (WHO) guidelines. Inorganic compositions of PM2.5, including trace elements and water soluble ions were determined using inductively coupled plasma-mass spectrometry (ICP-MS) and ion chromatography (IC), respectively. The major trace elements identified were K, Al, Ca, Mg and Fe which accounted for approximately 93%, 91% and 92% of the overall metals' portions recorded during pre-haze, haze and post-haze periods, respectively. For water-soluble ions, secondary inorganic aerosols (SO42-, NO3-and NH4+) contributed around 12%, 43% and 16% of the overall PM2.5mass during pre-haze, haze and post-haze periods, respectively. During haze periods, the predominant source identified using PMF was secondary inorganic aerosol (SIA) and biomass burning where the NAME simulations indicate the importance of fires in Sumatra, Indonesia. The main source during pre-haze and post-haze were mix SIA and road dust as well as mineral dust, respectively. The highest non-carcinogenic health risk during haze episode was estimated among the infant group (HI=1.06) while the highest carcinogenic health risk was estimated among the adult group (2.27×10-5).
  17. Nadzir MSM, Ashfold MJ, Khan MF, Robinson AD, Bolas C, Latif MT, et al.
    Environ Sci Pollut Res Int, 2018 Jan;25(3):2194-2210.
    PMID: 29116536 DOI: 10.1007/s11356-017-0521-1
    The Antarctic continent is known to be an unpopulated region due to its extreme weather and climate conditions. However, the air quality over this continent can be affected by long-lived anthropogenic pollutants from the mainland. The Argentinian region of Ushuaia is often the main source area of accumulated hazardous gases over the Antarctic Peninsula. The main objective of this study is to report the first in situ observations yet known of surface ozone (O3) over Ushuaia, the Drake Passage, and Coastal Antarctic Peninsula (CAP) on board the RV Australis during the Malaysian Antarctic Scientific Expedition Cruise 2016 (MASEC'16). Hourly O3 data was measured continuously for 23 days using an EcoTech O3 analyzer. To understand more about the distribution of surface O3 over the Antarctic, we present the spatial and temporal of surface O3 of long-term data (2009-2015) obtained online from the World Meteorology Organization of World Data Centre for greenhouse gases (WMO WDCGG). Furthermore, surface O3 satellite data from the free online NOAA-Atmospheric Infrared Sounder (AIRS) database and online data assimilation from the European Centre for Medium-Range Weather Forecasts (ECMWF)-Monitoring Atmospheric Composition and Climate (MACC) were used. The data from both online products are compared to document the data sets and to give an indication of its quality towards in situ data. Finally, we used past carbon monoxide (CO) data as a proxy of surface O3 formation over Ushuaia and the Antarctic region. Our key findings were that the surface O3 mixing ratio during MASEC'16 increased from a minimum of 5 ppb to ~ 10-13 ppb approaching the Drake Passage and the Coastal Antarctic Peninsula (CAP) region. The anthropogenic and biogenic O3 precursors from Ushuaia and the marine region influenced the mixing ratio of surface O3 over the Drake Passage and CAP region. The past data from WDCGG showed that the annual O3 cycle has a maximum during the winter of 30 to 35 ppb between June and August and a minimum during the summer (January to February) of 10 to 20 ppb. The surface O3 mixing ratio during the summer was controlled by photochemical processes in the presence of sunlight, leading to the depletion process. During the winter, the photochemical production of surface O3 was more dominant. The NOAA-AIRS and ECMWF-MACC analysis agreed well with the MASEC'16 data but twice were higher during the expedition period. Finally, the CO past data showed the surface O3 mixing ratio was influenced by the CO mixing ratio over both the Ushuaia and Antarctic regions. Peak surface O3 and CO hourly mixing ratios reached up to ~ 38 ppb (O3) and ~ 500 ppb (CO) over Ushuaia. High CO over Ushuaia led to the depletion process of surface O3 over the region. Monthly CO mixing ratio over Antarctic (South Pole) were low, leading to the production of surface O3 over the Antarctic region.
  18. Khan MF, Maulud KNA, Latif MT, Chung JX, Amil N, Alias A, et al.
    Sci Total Environ, 2018 Feb 01;613-614:1401-1416.
    PMID: 29898507 DOI: 10.1016/j.scitotenv.2017.08.025
    Air pollution can be detected through rainwater composition. In this study, long-term measurements (2000-2014) of wet deposition were made to evaluate the physicochemical interaction and the potential sources of pollution due to changes of land use. The rainwater samples were obtained from an urban site in Kuala Lumpur and a highland-rural site in the middle of Peninsular Malaysia. The compositions of rainwater were obtained from the Malaysian Meteorological Department. The results showed that the urban site experienced more acidity in rainwater (avg=277mm, range of 13.8 to 841mm; pH=4.37) than the rural background site (avg=245mm, range of 2.90 to 598mm; pH=4.97) due to higher anthropogenic input of acid precursors. The enrichment factor (EF) analysis showed that at both sites, SO42-, Ca2+ and K+ were less sensitive to seawater but were greatly influenced by soil dust. NH4+ and Ca2+ can neutralise a larger fraction of the available acid ions in the rainwater at the urban and rural background sites. However, acidifying potential was dominant at urban site compared to rural site. Source-receptor relationship via positive matrix factorisation (PMF 5.0) revealed four similar major sources at both sites with a large variation of the contribution proportions. For urban, the major sources influence on the rainwater chemistry were in the order of secondary nitrates and sulfates>ammonium-rich/agricultural farming>soil components>marine sea salt and biomass burning, while at the background site the order was secondary nitrates and sulfates>marine sea salt and biomass burning=soil components>ammonia-rich/agricultural farming. The long-term trend showed that anthropogenic activities and land use changes have greatly altered the rainwater compositions in the urban environment while the seasonality strongly affected the contribution of sources in the background environment.
  19. Ali MYM, Hanafiah MM, Khan MF
    Sci Total Environ, 2018 Jun 01;626:1-10.
    PMID: 29331833 DOI: 10.1016/j.scitotenv.2018.01.080
    This study aimed to measure the equilibrium equivalent radon (EECRn) concentration in an old building (Building-1) and a new building (Building-2) with mechanical ventilation and a natural ventilation system, respectively. Both buildings were located at the campus of University Kebangsaan Malaysia. The concentration of indoor radon was measured at 25 sampling stations using a radon detector model DOSEman PRO. The sampling was conducted for 8 h to represent daily working hours. A correlation of the radon concentration was made with the annual inhalation dose of the occupants at the indoor stations. The equilibrium factor and the annual effective dose on the lung cancer risks of each occupant were calculated at each sampling station. The average equilibrium equivalent radon measured in Building-1 and Building-2 was 2.33 ± 0.99 and 3.17 ± 1.74 Bqm-3, respectively. The equilibrium factor for Building 1 ranged from 0.1053 to 0.2273, and it ranged from 0.1031 to 0.16 for Building 2. The average annual inhalation doses recorded at Building-1 and Building-2 were 0.014 ± 0.005 mSv y-1and 0.020 ± 0.013 mSv y-1, respectively. The annual effective dose for Building-1 was 0.034 ± 0.012 mSv y-1, and it was 0.048 ± 0.031 mSv y-1for Building-2. The values of equilibrium equivalent radon concentration for both buildings were below the standard recommended by the International Commission on Radiological Protection (ICRP). However, people may have different radon tolerance levels. Therefore, the inhalation of the radon concentration can pose a deleterious health effect for people in an indoor environment.
  20. Samsuddin NAC, Khan MF, Maulud KNA, Hamid AH, Munna FT, Rahim MAA, et al.
    Sci Total Environ, 2018 Jul 15;630:1502-1514.
    PMID: 29554768 DOI: 10.1016/j.scitotenv.2018.02.289
    Southeast Asian haze is a semi-natural phenomenon that chokes the region each year during the dry monsoon season. Smoke-haze episodes caused by the vegetation and peat fires in Indonesia severely affected large parts of Malaysia during the 2015 El Niño phenomenon. This study aimed to evaluate the factors that influenced the concentrations of aerosol and trace gases during the 2015 haze and non-haze period on a semi-urban site in the southern part of Malaysian peninsula that facing Sumatra (Muar, Site A), and on an urban site near to Kuala Lumpur, influenced by the city centre (Cheras, Site B). Local land use data and the cluster of air mass weighted backward trajectory were used to identify the potential factors from local sources and the transboundary region, respectively. The annual median concentrations of PM10 for semi-urban and urban sites were 45.0μg/m3 and 47.0μg/m3, respectively for the study period (Jan-Dec 2015) from the hourly observation dataset. The highest PM10 concentrations during the haze were 358μg/m3 and 415μg/m3 for the two sites, respectively, representing absolutely unhealthy air. However, the trace gases were within the safe threshold. The average concentrations of PM10 and carbon monoxide were two fold higher during the haze than the non-haze episodes on both sites. Nitrogen dioxide was more influenced by haze compared with sulphur dioxide and ozone. The results of the land use change suggest that the local factor can also partially affect the air pollution on the urban area (Site B) but more visible in 2015. The results of the backward trajectory and the wildfire radiative power showed that the smoke-haze episodes that affected Malaysia in 2015 were mainly initiated in the Indonesian Sumatra and Kalimantan regions. This study provides a very useful information towards the impacted region during El Niño haze episode.
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