Displaying publications 1 - 20 of 67 in total

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  1. Shahul Hamid F, Bhatti MS, Anuar N, Anuar N, Mohan P, Periathamby A
    Waste Manag Res, 2018 Oct;36(10):873-897.
    PMID: 30103651 DOI: 10.1177/0734242X18785730
    The widespread occurrence of microplastic has invaded the environment to an extent that it appears to be present throughout the globe. This review investigated the global abundance and distribution of microplastics in marine and freshwater ecosystems. Furthermore, the issues and challenges have been addressed for better findings in microplastics studies. Findings revealed that the accumulation of microplastics varies geographically, with locations, hydrodynamic conditions, environmental pressure, and time. From this review, it is crucial that proper regulations are proposed and implemented in order to reduce the occurrence of microplastics in the aquatic environment. Without appropriate law and regulations, microplastic pollution will eventually threaten human livelihood.
  2. Azri S, Ujang U, Abdullah NS
    Waste Manag Res, 2023 Mar;41(3):687-700.
    PMID: 36129019 DOI: 10.1177/0734242X221123489
    Despite the government's policies and objectives, Malaysia lags behind in sustainable waste management techniques, particularly recycling. Bins should be located conveniently to encourage recycling and reduce waste. The current model of bin location-allocation is mostly determined by distance. However, it has been identified that previous studies excluded an important factor: litter pattern identification. Litter pattern is important to identify waste generation hotspots and litter distribution. Thus, we proposed the within cluster pattern identification (WCPI) approach to optimize the recycle point distribution. WCPI gathers the information on litter distribution using geotagged images and analyses the pattern distribution. The optimal location for recycle bin can be identified by incorporating k-means clustering to the pattern distribution. Since k-means faces the non-deterministic polynomial-time-hard challenge of selecting the ideal cluster and cluster centre, WCPI used the total within-cluster sum of square on top of k-means clustering. The proposed location by WCPI is validated in terms of accessibility and suitability. Furthermore, this study provides further analysis of carbon footprint that can be reduced by simulating the data from geotagged images. The results show that 10,323.55 kg of carbon emission can be reduced if the litter is sent for recycling. Thus, we believe that locating bins at an optimal location will embark on consumer motivation to dispose of recycled waste, reduce litter and lessen the carbon footprint. At the same time, these efforts could transform Malaysia into a clean and sustainable nation that aims to achieve Agenda 2030.
  3. Maalouf A, Agamuthu P
    Waste Manag Res, 2023 Sep;41(9):1420-1434.
    PMID: 37125680 DOI: 10.1177/0734242X231160099
    This review provides the history and current paradigms of waste management (WM) practices in developing nations during the last five decades. It explores the evolution of the challenges, complexities, and trends during this period. This paper, for the first time, presents an estimation of the amount of municipal solid waste (MSW) generated in developing nations in the last five decades based on the material flow analysis approach. Overall, the amount of MSW in developing countries has increased from about 0.64 billion Mt in 1970 to 2 billion Mt in 2019. This review demonstrates the importance of finding new WM approaches in developing nations in the context of formulating policies, strategies, and highlights the major trends that re-define WM in developing countries. It also aims to present the holistic changes in technology, economic and environmental feasibility aspects to attain an integrated sustainable WM system in developing countries. Specific focus on open-burning, open-dumping, informal recycling, food waste, plastic pollution, and waste collection with reference to Sustainable Development Goals are explained. Drivers for the way forward including circular economy are investigated.
  4. Agamuthu P, Babel S
    Waste Manag Res, 2023 Dec;41(12):1699-1716.
    PMID: 37823520 DOI: 10.1177/0734242X231199938
    Solid waste management was explored in Asia's last five decades, and the issues and challenges were identified. Waste generation has increased in all nations in the previous 50 years, although more recently, a declining trend has been observed in Japan and Korea. The composition has been predominantly organic, with 45-50% being kitchen waste. Material extraction and productivity to sustain the most populous part of the globe are explained. Waste management technologies have evolved, with more nations slowly transitioning from landfills to using waste-to-energy options. However, landfilling and open dumps are still the major disposal choice in most developing countries in Asia. Thus, the issues of concern include dumpsites management, the informal sector, waste collection, open burning and food waste. Changes (increasing trends) in the recycling technologies and quantum are evident, as seen in several country reports from India, Indonesia, Japan, Malaysia, Singapore, South Korea, Thailand and Vietnam. There are several issues and challenges for recycling, which are explored in the text. Lastly, the drivers that propel the whole scenario of waste management in Asia and the evolution of these drivers over time are discussed. Several recommendations are included to achieve sustainable waste management in Asia.
  5. Murad MW, Siwar C
    Waste Manag Res, 2007 Feb;25(1):3-13.
    PMID: 17346002
    This study assesses waste management and recycling practices of the urban poor households residing as squatters and in low-cost flats of Kuala Lumpur city, Malaysia. To attain the objective, the study employed some statistical techniques such as t-tests of equality of means, one-way analysis of variance, chi-squared 'likelihood ratio' tests, and simple descriptive statistics. The statistical techniques were used to determine and analyse the factors that significantly influence the environmental behaviour of the urban poor concerning solid waste management, particularly their recycling practices. The findings of the study show that the urban poor and low-income communities have been proved to behave in ways that are consistent with and conducive to environmentally friendly solid waste management. This study provides evidence that the urban poor and low-income communities are the main recyclers, re-users, and source-reducers of their household solid waste. The study, however, suggests that policies should be formulated to focus on promoting knowledge, education, and the skills of the urban poor and, in addition, to empower them as a means of improving their quality of life.
  6. Agamuthu P, Hansen JA
    Waste Manag Res, 2007 Jun;25(3):241-6.
    PMID: 17612324
    This paper analyses some of the higher education and research capacity building experiences gained from 1998-2006 by Danish and Malaysian universities. The focus is on waste management, directly relating to both the environmental and socio-economic dimensions of sustainable development. Primary benefits, available as an educational legacy to universities, were obtained in terms of new and enhanced study curricula established on Problem-oriented Project-based Learning (POPBL) pedagogy, which strengthened academic environmental programmes at Malaysian and Danish universities. It involved more direct and mutually beneficial cooperation between academia and businesses in both countries. This kind of university reach-out is considered vital to development in all countries actively striving for global and sustainable development. Supplementary benefits were accrued for those involved directly in activities such as the 4 months of field studies, workshops, field courses and joint research projects. For students and academics, the gains have been new international dimensions in university curricula, enhanced career development and research collaboration based on realworld cases. It is suggested that the area of solid waste management offers opportunities for much needed capacity building in higher education and research, contributing to sustainable waste management on a global scale. Universities should be more actively involved in such educational, research and innovation programmes to make the necessary progress. ISWA can support capacity building activities by utilizing its resources--providing a lively platform for debate, securing dissemination of new knowledge, and furthering international networking beyond that which universities already do by themselves. A special challenge to ISWA may be to improve national and international professional networks between academia and business, thereby making education, research and innovation the key driving mechanisms in sustainable development in solid waste management.
  7. Fauziah SH, Agamuthu P
    Waste Manag Res, 2012 Jul;30(7):656-63.
    PMID: 22455994 DOI: 10.1177/0734242X12437564
    In Malaysia, landfills are being filled up rapidly due to the current daily generation of approximately 30,000 tonnes of municipal solid waste. This situation creates the crucial need for improved landfilling practices, as sustainable landfilling technology is yet to be achieved here. The objective of this paper is to identify and evaluate the development and trends in landfilling practices in Malaysia. In 1970, the disposal sites in Malaysia were small and prevailing waste disposal practices was mere open-dumping. This network of relatively small dumps, typically located close to population centres, was considered acceptable for a relatively low population of 10 million in Malaysia. In the 1980s, a national programme was developed to manage municipal and industrial wastes more systematically and to reduce adverse environmental impacts. The early 1990s saw the privatization of waste management in many parts of Malaysia, and the establishment of the first sanitary landfills for MSW and an engineered landfill (called 'secure landfill' in Malaysia) for hazardous waste. A public uproar in 2007 due to contamination of a drinking water source from improper landfilling practices led to some significant changes in the government's policy regarding the country's waste management strategy. Parliament passed the Solid Waste and Public Cleansing Management (SWPCM) Act 2007 in August 2007. Even though the Act is yet to be implemented, the government has taken big steps to improve waste management system further. The future of the waste management in Malaysia seems somewhat brighter with a clear waste management policy in place. There is now a foundation upon which to build a sound and sustainble waste management and disposal system in Malaysia.
  8. Ali G, Nisar J, Iqbal M, Shah A, Abbas M, Shah MR, et al.
    Waste Manag Res, 2019 Aug 13.
    PMID: 31405341 DOI: 10.1177/0734242X19865339
    Due to a huge increase in polymer production, a tremendous increase in municipal solid waste is observed. Every year the existing landfills for disposal of waste polymers decrease and the effective recycling techniques for waste polymers are getting more and more important. In this work pyrolysis of waste polystyrene was performed in the presence of a laboratory synthesized copper oxide. The samples were pyrolyzed at different heating rates that is, 5°Cmin-1, 10°Cmin-1, 15°Cmin-1 and 20°Cmin-1 in a thermogravimetric analyzer in inert atmosphere using nitrogen. Thermogravimetric data were interpreted using various model fitting (Coats-Redfern) and model free methods (Ozawa-Flynn-Wall, Kissinger-Akahira-Sunose and Friedman). Thermodynamic parameters for the reaction were also determined. The activation energy calculated applying Coats-Redfern, Ozawa-Flynn-Wall, Kissinger-Akahira-Sunose and Friedman models were found in the ranges 105-148.48 kJmol-1, 99.41-140.52 kJmol-1, 103.67-149.15 kJmol-1 and 99.93-141.25 kJmol-1, respectively. The lowest activation energy for polystyrene degradation in the presence of copper oxide indicates the suitability of catalyst for the decomposition reaction to take place at lower temperature. Moreover, the obtained kinetics and thermodynamic parameters would be very helpful in determining the reaction mechanism of the solid waste in a real system.
  9. Aziz HA, Alias S, Assari F, Adlan MN
    Waste Manag Res, 2007 Dec;25(6):556-65.
    PMID: 18229750
    Suspended solids, colour and chemical oxygen demand (COD) are among the main pollutants in landfill leachate. Application of physical or biological processes alone is normally not sufficient to remove these constituents, especially for leachate with a lower biochemical oxygen demand (BOD)/ COD ratio. The main objective of this research was to investigate the efficiency of coagulation and flocculation processes for removing suspended solids, colour and COD from leachate produced in a semi-aerobic landfill in Penang, Malaysia. A 12-month characterization study of the leachate indicated that it had a mean annual BOD/COD ratio of 0.15 and was partially stabilized, with little further biological degradation likely to occur. Particle size analysis of the raw leachate indicated that its 50th percentile (d50) was 11.68 microm. Three types of coagulants were examined in bench scale jar test studies: aluminium sulphate (alum), ferric chloride (FeCl3) and ferrous sulphate (FeSO4). The effects of agitation speed, settling time, pH, coagulant dosages and temperature were examined. At 300 rpm of rapid mixing, 50 rpm of slow mixing, and 60 min settling time, higher removals of suspended solids (over 95%), colour (90%) and COD (43%) were achieved at pH 4 and 12. FeCl3 was found to be superior to other coagulants tested. At pH 4 and 12, fair removal of suspended solids was observed at a reasonably low coagulant dose, i.e., 600 mg L(-1); hHowever, about 2500 mg L(-1) of coagulant was required to achieve good removals at pH 6. Better removals were achieved at higher temperature. The d50 of sludge after coagulation at pH 4 with a 2500 mg L(-1) FeCl3 dose was 60.16 microm, which indicated that the particles had been removed effectively from the leachate. The results indicate that coagulation and flocculation processes can be used effectively in integrated semi-aerobic leachate treatment systems, especially for removing suspended solids, colour and COD.
  10. Scharff H, Soon HY, Rwabwehare Taremwa S, Zegers D, Dick B, Villas Bôas Zanon T, et al.
    Waste Manag Res, 2023 Oct 12.
    PMID: 37823371 DOI: 10.1177/0734242X231200742
    This article reports on how management approaches influence methane emissions from landfills. The project team created various landfill operational scenarios for different regions of the planet with respect to waste composition, organic waste reduction and landfill gas recovery timing. These scenarios were modelled by applying a basic gas generation model according to the United Nations Intergovernmental Panel on Climate Change (IPCC) recommendations. In general, the IPCC's recommended modelling parameters and default values were used. Based on the modelling undertaken, two options stand out as being the most effective methane mitigation measures in a wide range of conditions throughout the world: (a) early gas recovery and (b) reduction of the amount of biodegradable organic waste accepted in a landfill. It is noted that reduction of organic input to any given landfill can take many years to realize. Moreover, suitable alternative processing or disposal options for the organic waste can be unaffordable for a significant percentage of the planet's population. Although effective, organic waste reduction cannot therefore be the only landfill methane mitigation measure. Early landfill gas recovery can be very effective by applying basic technologies that can be deployed relatively quickly, and at modest cost. Policymakers and regulators from around the globe can significantly reduce adverse environmental impacts from landfill gas emissions by stimulating both the early capture and flaring and/or energy recovery of landfill gas and programmes to reduce the inflow of organic waste into landfills.
  11. Yuik CJ, Mat Saman MZ, Ngadiman NHA, Hamzah HS
    Waste Manag Res, 2023 Mar;41(3):554-565.
    PMID: 36134680 DOI: 10.1177/0734242X221123486
    End-of-life vehicles (ELV) management is becoming a global concern in the automotive industry. However, there is still limited study on supply chain optimisation that focusses on specific ELV treatments. Therefore, this mini-review article analyses the supply chain optimisation for recycling and remanufacturing sustainable management in ELV. A total of 51 papers were reviewed from the year 2016 to 2021. The key topics in each article were assessed and classified into various themes, followed by the content analysis. The percentage breakdown for the six main themes are ELV recovery management system (37.25%), reverse logistic network design (29.41%), ELV economy analysis (15.69%), government regulation or subsidies (7.84%), ELV quantity forecast (5.88%) and ELV part design (3.92%). It can be concluded that ELV recovery management and reverse logistic network design are the top two key focusses of supply chain optimisation priorities that have been extensively applied to improve ELV development. The literature gap has shown that the study on remanufacturing in the ELV supply chain is minimal compared to recycling. The classification of ELV recycling and remanufacturing supply chain optimisation in this study will be beneficial in supporting real-life problem-solving for industrial applications. This study serves as a valuable reference guide to identifying more sustainable solutions in ELV management and promoting the critical focus area for academicians and industry players.
  12. Idris J, Shirai Y, Andou Y, Mohd Ali AA, Othman MR, Ibrahim I, et al.
    Waste Manag Res, 2016 Feb;34(2):176-80.
    PMID: 26612557 DOI: 10.1177/0734242X15616472
    An appropriate technology for waste utilisation, especially for a large amount of abundant pressed-shredded oil palm empty fruit bunch (OFEFB), is important for the oil palm industry. Self-sustained pyrolysis, whereby oil palm biomass was combusted by itself to provide the heat for pyrolysis without an electrical heater, is more preferable owing to its simplicity, ease of operation and low energy requirement. In this study, biochar production under self-sustained pyrolysis of oil palm biomass in the form of oil palm empty fruit bunch was tested in a 3-t large-scale pool-type reactor. During the pyrolysis process, the biomass was loaded layer by layer when the smoke appeared on the top, to minimise the entrance of oxygen. This method had significantly increased the yield of biochar. In our previous report, we have tested on a 30-kg pilot-scale capacity under self-sustained pyrolysis and found that the higher heating value (HHV) obtained was 22.6-24.7 MJ kg(-1) with a 23.5%-25.0% yield. In this scaled-up study, a 3-t large-scale procedure produced HHV of 22.0-24.3 MJ kg(-1) with a 30%-34% yield based on a wet-weight basis. The maximum self-sustained pyrolysis temperature for the large-scale procedure can reach between 600 °C and 700 °C. We concluded that large-scale biochar production under self-sustained pyrolysis was successfully conducted owing to the comparable biochar produced, compared with medium-scale and other studies with an electrical heating element, making it an appropriate technology for waste utilisation, particularly for the oil palm industry.
  13. Michel Devadoss PS, Pariatamby A, Bhatti MS, Chenayah S, Shahul Hamid F
    Waste Manag Res, 2021 Jul;39(7):914-927.
    PMID: 33506744 DOI: 10.1177/0734242X20983927
    The studies on municipal solid waste (MSW) management in Pakistan and its impacts on greenhouse gas (GHG) emissions are glaringly missing. Therefore, this study examines the effect of MSW management on GHG emissions in Pakistan and suggests the best suitable strategies for alleviating GHG emissions. The Intergovernmental Panel on Climate Change (IPCC) 2006 waste model (WM) was used to create inventory of GHG emissions from landfilling. The solid waste management GHG (SWM-GHG) calculator and strengths-weaknesses-opportunities-threat (SWOT) analyses were used as strategic planning tools to reduce GHG emissions by improving MSW management in Pakistan. The IPCC 2006 WM estimated 14,987,113 metric tonnes (Mt) carbon dioxide equivalents (CO2-eq) of GHG emissions in 2016. The SWM-GHG calculator, on the other hand, estimated 23,319,370 Mt CO2-eq of GHG emissions from management of 30,764,000 Mt of MSW in 2016, which included 8% recycling, 2% composting, and 90% disposal in open dumps. To reduce GHG emissions, two strategies including recycling-focused and incineration-focused were analysed. The recycling approach can reduce more GHG emissions than incineration, as it can reduce 36% of GHG emissions (as compared to GHG emission in 2016) by recycling 23% of MSW, anaerobically digesting 10% of MSW, and disposing of 67% of MSW in sanitary landfills (with energy recovery). Moreover, the SWOT analysis suggested integration of the informal sector, adoption of anaerobic digestion and formulation of explicit MSW regulations for improving the current management of MSW which will also result in lower GHG emissions.
  14. Ahmad SZ, Ahamad MS, Yusoff MS
    Waste Manag Res, 2014 Jan;32(1):24-33.
    PMID: 24241167 DOI: 10.1177/0734242X13507313
    Proper implementation of landfill siting with the right regulations and constraints can prevent undesirable long-term effects. Different countries have respective guidelines on criteria for new landfill sites. In this article, we perform a comparative study of municipal solid waste landfill siting criteria stated in the policies and guidelines of eight different constitutional bodies from Malaysia, Australia, India, U.S.A., Europe, China and the Middle East, and the World Bank. Subsequently, a geographic information system (GIS) multi-criteria evaluation model was applied to determine new suitable landfill sites using different criterion parameters using a constraint mapping technique and weighted linear combination. Application of Macro Modeler provided in the GIS-IDRISI Andes software helps in building and executing multi-step models. In addition, the analytic hierarchy process technique was included to determine the criterion weight of the decision maker's preferences as part of the weighted linear combination procedure. The differences in spatial results of suitable sites obtained signifies that dissimilarity in guideline specifications and requirements will have an effect on the decision-making process.
  15. Akinbile CO, Yusoff MS
    Waste Manag Res, 2012 May;30(5):498-505.
    PMID: 21930519 DOI: 10.1177/0734242X11417974
    Solid waste comprised of a grass clippings mixture was decomposed using a locally-made compost bin in Pulau Pinang, Malaysia, to eliminate challenges associated with improper waste disposal. Bulk density, pH, moisture content, nutrients content, nitrogen (N), phosphorus (P), potassium (K), iron (Fe), zinc (Zn), copper (Cu) and carbon/nitrogen (C/N) ratio were determined over 77 days. A 34% reduction in compost bin volume was observed and bulk density and pH were also reduced from 732 to 482 kg m(-3) and 7.82 to 8.41, respectively, indicating fairly good performance. The final moisture content and C/N ratio were 44.06% and 14 : 1, respectively, and the results also showed that the presence of nutrients and heavy metals in the final compost were within acceptable limits for use as a soil conditioner. Final concentrations of N, P and K were 347 mg kg(-1), 510 mg kg(-1) and 14.8 g kg(-1) and for heavy metals, Fe, Zn and Cu were 5308, 300 and 20 mg kg(-1), respectively, which considerably assisted in the decomposition process. Processed waste materials from the bin were shown to be excellent organic fertilizers with over 75% germination index for seeds grown into bean sprouts in 72 h. An improved bin design to eliminate greenhouse gas emission into the environment is suggested.
  16. Isa MH, Asaari FA, Ramli NA, Ahmad S, Siew TS
    Waste Manag Res, 2005 Dec;23(6):565-70.
    PMID: 16379126
    The implementation of a suitable solid waste management programme with appropriate methods of recycling as an inherent element is vital to the alleviation of the problems associated with solid waste generation, handling and disposal, environmental conservation, public hygiene, etc. The present work is a case study on solid waste collection and recycling practices in Nibong Tebal town, Penang, Malaysia. The amount and types of domestic waste generated, household participation in recycling, identification of existing problems related to the implementation of the recycling programme, etc. formed the basis of this study. Surveys (interviews/questionnaires) and on-site observations were conducted to gather information on the solid waste collection and recycling practice of the residents. A focus group of 60 individuals was selected and their response to a questionnaire, prepared according to a Likert scale, was obtained and analysed. The majority of the respondents expressed concerns about recycling and wanted more to be done in this regard. Illegal collection, aesthetically displeasing sites and a lack of public awareness were problems of major concern. Issues related to inadequate funding and manpower as well as end market are also addressed and suggestions made.
  17. Mohd Adnan SN, Yusoff S, Piaw CY
    Waste Manag Res, 2013 Jun;31(6):599-612.
    PMID: 23528999 DOI: 10.1177/0734242X13482031
    A total of 20 landfills are located in State of Selangor, Malaysia. This includes the Ampar Tenang landfill site, which was closed on 26 January 2010. It was reported that the landfill has been upgraded to a level I type of sanitary classification. However, the dumpsite area is not being covered according to the classification. In addition, municipal solid waste was dumped directly on top of the unlined natural alluvium formation. This does not only contaminate surface and subsurface soils, but also initiates the potential risk of groundwater pollution. Based on previous studies, the Ampar Tenang soil has been proven to no longer be capable of preventing pollution migration. In this study, metal concentrations of soil samples up to 30 m depth were analyzed based on statistical analysis. It is very significant because research of this type has not been carried out before. The subsurface soils were significantly polluted by arsenic (As), lead (Pb), iron (Fe), copper (Cu) and aluminium (Al). As and Pb exceeded the safe limit values of 5.90 mg/kg and 31.00 mg/kg, respectively, based on Provincial Sediment Quality Guidelines for Metals and the Interim Sediment Quality Values. Furthermore, only Cu concentrations showed a significantly decreasing trend with increasing depth. Most metals were found on clay-type soils based on the cluster analysis method. Moreover, the analysis also differentiates two clusters: cluster I-Pb, As, zinc, Cu, manganese, calcium, sodium, magnesium, potassium and Fe; cluster II-Al. Different clustering may suggest a different contamination source of metals.
  18. Fauzi MA, Abidin NHZ, Omer MM, Kineber AF, Rahman ARA
    Waste Manag Res, 2023 Sep 08.
    PMID: 37681563 DOI: 10.1177/0734242X231196765
    The purpose of this study is to review the relationship between the highly anticipated concept of circular economy (CE) and sustainable development goals (SDGs). These two sustainability principles have transformed organizations and countries in their quest to achieve sustainable development. Despite their importance to the business and corporate realm, the discussion of these two concepts has been developed in silos, arbitrarily connected. Through a bibliometric approach, this study reviewed 226 journal publications and 16,008 cited references from the Web of Science (WoS) to understand the past, present and future trends of the two concepts and their impact on the sustainability development. The bibliometric approach of citation, co-citation and co-word analysis uncovers the relevant and significant themes and research streams. Theoretical and practical implications were discussed within the broader business and governance perspective to develop a substantial triple bottom line in creating a sustainable future for civil society.
  19. Johari K, Alias AS, Saman N, Song ST, Mat H
    Waste Manag Res, 2015 Jan;33(1):81-8.
    PMID: 25492720 DOI: 10.1177/0734242X14562660
    The preparation of chars and activated carbon as low-cost elemental mercury adsorbents was carried out through the carbonisation of coconut husk (pith and fibre) and the activation of chars with potassium hydroxide (KOH), respectively. The synthesised adsorbents were characterised by using scanning electron microscopy, Fourier transform infrared spectroscopy and nitrogen adsorption/desorption analysis. The elemental mercury removal performance was measured using a conventional flow type packed-bed adsorber. The physical and chemical properties of the adsorbents changed as a result of the carbonisation and activation process, hence affecting on the extent of elemental mercury adsorption. The highest elemental mercury (Hg°) adsorption capacity was obtained for the CP-CHAR (3142.57 µg g(-1)), which significantly outperformed the pristine and activated carbon adsorbents, as well as higher than some adsorbents reported in the literature.
  20. Ishak AR, Hamid FS, Mohamad S, Tay KS
    Waste Manag Res, 2017 Jul;35(7):739-746.
    PMID: 28539097 DOI: 10.1177/0734242X17707572
    The treatment of stabilized landfill leachate (SLL) by conventional biological treatment is often inefficient due to the presence of bio-recalcitrant substances. In this study, the feasibility of coagulation-flocculation coupled with the Fenton reaction in the treatment of SLL was evaluated. The efficiency of the selected treatment methods was evaluated through total organic carbon (TOC) removal from SLL. With ferric chloride as the coagulant, coagulation-flocculation was found to achieve the highest TOC removal of 71% at pH 6. Then, the pretreated SLL was subjected to the Fenton reaction. Nearly 50% of TOC removal was achieved when the reaction was carried out at pH 3, H2O2:Fe2+ ratio of 20:1, H2O2 dosage of 240 mM and 1 h of reaction time. By coupling the coagulation-flocculation with the Fenton reaction, the removal of TOC, COD (chemical oxygen demand) and turbidity of SLL were 85%, 84% and 100%, respectively. The ecotoxicity study performed using zebrafish revealed that 96 h LC50 for raw SLL was 1.40% (v/v). After coagulation-flocculation, the LC50 of the pretreated SLL was increased to 25.44%. However, after the Fenton reaction, the LC50 of the treated SLL was found to decrease to 10.96% due to the presence of H2O2 residue. In this study, H2O2 residue was removed using powdered activated charcoal. This method increased the LC50 of treated effluent to 34.48% and the removal of TOC and COD was further increased to 90%. This finding demonstrated that the combination of the selected treatment methods can be an efficient treatment method for SLL.
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