Displaying publications 1 - 20 of 52 in total

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  1. Anuar K, Hamdan S
    Talanta, 1992 Dec;39(12):1653-6.
    PMID: 18965586
    A new lead(II) electrode has been constructed with poly(hydroxamic acid) (PHXA) as the active material and silicone rubber as the supporting material. The electrode gave near Nerstian response over the concentration range 4 x 10(-5)-1 x 10(-2)M lead(II). The detection limit of the electrode is approximately 4 x 10(-6)M and the electrode works well in the pH range 4.5-6.0. The response time was 50-120 sec over the whole concentration range and the electrode has a working life of at least 4 weeks. Iron(III) severely poisoned the electrode membrane. Nickel(II) and mercury(II) gave very strong interference compared to copper(II), silver(I), cobalt(II), sodium(I), potassium(I), zinc(II) and cadmium(II) which gave some or little interference. Values determined with atomic absorption (AAS) and a commercial lead(II) electrode were in good agreement with those measured with the lead(II) electrode reported here.
    Matched MeSH terms: Silicone Elastomers
  2. Yang T, Xiao Y, Zhang Z, Liang Y, Li G, Zhang M, et al.
    Sci Rep, 2018 09 28;8(1):14518.
    PMID: 30266999 DOI: 10.1038/s41598-018-32757-9
    Soft robots driven by stimuli-responsive materials have their own unique advantages over traditional rigid robots such as large actuation, light weight, good flexibility and biocompatibility. However, the large actuation of soft robots inherently co-exists with difficulty in control with high precision. This article presents a soft artificial muscle driven robot mimicking cuttlefish with a fully integrated on-board system including power supply and wireless communication system. Without any motors, the movements of the cuttlefish robot are solely actuated by dielectric elastomer which exhibits muscle-like properties including large deformation and high energy density. Reinforcement learning is used to optimize the control strategy of the cuttlefish robot instead of manual adjustment. From scratch, the swimming speed of the robot is enhanced by 91% with reinforcement learning, reaching to 21 mm/s (0.38 body length per second). The design principle behind the structure and the control of the robot can be potentially useful in guiding device designs for demanding applications such as flexible devices and soft robots.
    Matched MeSH terms: Elastomers
  3. Goh TH, Puvan IS, Wong WP, Sivanesaratnam V, Sinnathuray TA
    Int. J. Fertil., 1981;26(2):116-9.
    PMID: 6114062
    The menstrual patterns of 281 women undergoing laparoscopic sterilization with silastic rings were studied prospectively. A significant increase in dysmenorrhea and irregular periods was seen soon after sterilization but this was transient, returning to presterilization levels by 12 months. Menorrhagia was not observed and the amount of menstrual blood loss showed a trend towards normal following sterilization. No permanent adverse effects on menstrual patterns were seen in the 1st year after sterilization. It is suggested that factors other than the sterilization procedure may be responsible for the high prevalence of menstrual dysfunction that has been reported following sterilization.
    Matched MeSH terms: Silicone Elastomers*
  4. Zeimaran E, Pourshahrestani S, Djordjevic I, Pingguan-Murphy B, Kadri NA, Towler MR
    Mater Sci Eng C Mater Biol Appl, 2015 Aug;53:175-88.
    PMID: 26042705 DOI: 10.1016/j.msec.2015.04.035
    Biodegradable elastomers have clinical applicability due to their biocompatibility, tunable degradation and elasticity. The addition of bioactive glasses to these elastomers can impart mechanical properties sufficient for hard tissue replacement. Hence, a composite with a biodegradable polymer matrix and a bioglass filler can offer a method of augmenting existing tissue. This article reviews the applications of such composites for skeletal augmentation.
    Matched MeSH terms: Elastomers*
  5. Siti Farhana Hisham, Ishak Ahmad, Rusli Daik, Anita Ramli
    Sains Malaysiana, 2011;40:1179-1186.
    In this study, poly(ethylene terephthalate) (PET) wastes bottle was recycled by glycolysis process using ethylene glycol. The unsaturated polyester resin (UPR) was then prepared by reacting the glycolysed product with maleic anhydride. The blend of UPR based on recycled PET wastes with liquid natural rubber (LNR) was carried out by varying the amount of LNR from 0 to 7.5 wt%. Mechanical tests such as tensile and impact were conducted to investigate the effects of LNR on the mechanical properties. Scanning Electron Microscopy (SEM) was used to analyze the morphology of the breaking area resulted from the tensile tests on the UPR and blend samples. From the results, the blend of 2.5 wt% LNR in UPR based recycled PET wastes achieved the highest strength in the mechanical properties and showed a well dispersed of elastomer particles in the sample morphology compared to other blends concentrations. This blend sample was then compared to the optimum blend of LNR with commercial resin through the glass transition temperature value Tg, mechanical strength and morphology properties. The comparison study showed that the Tg for UPR based recycled PET was higher than the value represented from commercial resin due to the degree of crystalinity in the molecular structure of the materials. LNR was found to be an effective impact modifier which gave a greater improvement in UPR from recycled PET wastes structure but not to the commercial one which needs 5% LNR to achieve the optimum properties. Thus, the compatibility between the UP resin based recycled PET and LNR was much better than with the commercial resin.
    Matched MeSH terms: Elastomers
  6. Okolo C, Rafique R, Iqbal SS, Saharudin MS, Inam F
    Molecules, 2020 Jun 27;25(13).
    PMID: 32605124 DOI: 10.3390/molecules25132960
    Multiwall carbon nanotube (CNT)-filled high density polyethylene (HDPE) nanocomposites were prepared by extrusion and considered for their suitability in the offshore sheathing applications. Transmission electron microscopy was conducted to analyse dispersion after bulk extrusion. Monolithic and nanocomposite samples were subjected to accelerated weathering and photodegradation (carbonyl and vinyl indices) characterisations, which consisted of heat, moisture (seawater) and UV light, intended to imitate the offshore conditions. The effects of accelerated weathering on mechanical properties (tensile strength and elastic modulus) of the nanocomposites were analysed. CNT addition in HDPE produced environmentally resilient nanocomposites with improved mechanical properties. The energy utilised to extrude nanocomposites was also less than the energy used to extrude monolithic HDPE samples. The results support the mass substitution of CNT-filled HDPE nanocomposites in high-end offshore applications.
    Matched MeSH terms: Silicone Elastomers
  7. Saputra R, Walvekar R, Khalid M, Mubarak NM, Sillanpää M
    Chemosphere, 2021 Feb;265:129033.
    PMID: 33250228 DOI: 10.1016/j.chemosphere.2020.129033
    Vulcanized rubber, due to its superior mechanical properties, has long been used in various industries, especially automotive. The rubber industry has evolved and expanded over the years to meet the increasing global demands for tires. Today tires consist of about 19% natural rubber and 24% synthetic rubber, while plastic polymer and metal, filler and additives make up the rest. Over 1.6 billion new tires are produced annually and around 1 billion waste tires are generated. Tires are extensively designed with several complex processes to make them virtually indestructible. Since tire rubber does not decompose easily, their disposal at the end of service life creates a monumental environmental impact. However, waste tire rubber (WTR) consist of valuable rubber hydrocarbon, making its recovery or regeneration highly desirable. The conventional recovery method of WTR tends to produce undesirable products due to the destruction of the polymeric chain and exponentially degenerates the vulcanizates' physical properties. Since then, multiple devulcanization processes were introduced to effectively and selectively cleave vulcanizate's crosslinks while retaining the polymeric networks. Different devulcanization methods such as chemical, mechanical, irradiation, biological and their combinations that have been explored until now are reviewed here. Besides, an overview of the latest development of devulcanization by ionic liquids and deep eutectic solvents are also described. While such devulcanization technique provides new sustainability pathway(s) for WTR, the generated devulcanizate also possesses comparable physical properties to that of virgin products. This further opens the possibility of novel circular economic opportunities worldwide.
    Matched MeSH terms: Elastomers*
  8. Sindi R, Wong YH, Yeong CH, Sun Z
    Quant Imaging Med Surg, 2020 Jun;10(6):1237-1248.
    PMID: 32550133 DOI: 10.21037/qims-20-251
    Background: Despite increasing reports of 3D printing in medical applications, the use of 3D printing in breast imaging is limited, thus, personalized 3D-printed breast model could be a novel approach to overcome current limitations in utilizing breast magnetic resonance imaging (MRI) for quantitative assessment of breast density. The aim of this study is to develop a patient-specific 3D-printed breast phantom and to identify the most appropriate materials for simulating the MR imaging characteristics of fibroglandular and adipose tissues.

    Methods: A patient-specific 3D-printed breast model was generated using 3D-printing techniques for the construction of the hollow skin and fibroglandular region shells. Then, the T1 relaxation times of the five selected materials (agarose gel, silicone rubber with/without fish oil, silicone oil, and peanut oil) were measured on a 3T MRI system to determine the appropriate ones to represent the MR imaging characteristics of fibroglandular and adipose tissues. Results were then compared to the reference values of T1 relaxation times of the corresponding tissues: 1,324.42±167.63 and 449.27±26.09 ms, respectively. Finally, the materials that matched the T1 relaxation times of the respective tissues were used to fill the 3D-printed hollow breast shells.

    Results: The silicone and peanut oils were found to closely resemble the T1 relaxation times and imaging characteristics of these two tissues, which are 1,515.8±105.5 and 405.4±15.1 ms, respectively. The agarose gel with different concentrations, ranging from 0.5 to 2.5 wt%, was found to have the longest T1 relaxation times.

    Conclusions: A patient-specific 3D-printed breast phantom was successfully designed and constructed using silicone and peanut oils to simulate the MR imaging characteristics of fibroglandular and adipose tissues. The phantom can be used to investigate different MR breast imaging protocols for the quantitative assessment of breast density.

    Matched MeSH terms: Silicone Elastomers
  9. Chieh, C.W., Asmawi Sanuddin, Reza Afshar, Aidy Ali
    MyJurnal
    The paper presents a simulation work conducted on the elastomer subjected to cyclic loads. A 3D finite element model of elastomer specimen, in accordance to ASTM D412, was developed using CATIA and ANSYS commercial finite element (FEM) packages. Fatigue life predicted from the simulation was compared with well-documented published data and it showed an acceptable agreement. Meanwhile, the simulated strain-life results are slightly lower than the experimental data. Several factors which potentially influenced the variations of the results were noted. Finally, some recommendations are offered at the end of this study to further improve the simulation
    Matched MeSH terms: Elastomers
  10. Balaji AB, Ratnam CT, Khalid M, Walvekar R
    J Biomater Appl, 2018 03;32(8):1049-1062.
    PMID: 29298552 DOI: 10.1177/0885328217750476
    The effect of electron beam radiation on ethylene-propylene diene terpolymer/polypropylene blends is studied as an attempt to develop radiation sterilizable polypropylene/ethylene-propylene diene terpolymer blends suitable for medical devices. The polypropylene/ethylene-propylene diene terpolymer blends with mixing ratios of 80/20, 50/50, 20/80 were prepared in an internal mixer at 165°C and a rotor speed of 50 rpm/min followed by compression molding. The blends and the individual components were radiated using 3.0 MeV electron beam accelerator at doses ranging from 0 to 100 kGy in air and room temperature. All the samples were tested for tensile strength, elongation at break, hardness, impact strength, and morphological properties. After exposing to 25 and 100 kGy radiation doses, 50% PP blend was selected for in vivo studies. Results revealed that radiation-induced crosslinking is dominating in EPDM dominant blends, while radiation-induced degradation is prevailing in PP dominant blends. The 20% PP blend was found to be most compatible for 20-60 kGy radiation sterilization. The retention in impact strength with enhanced tensile strength of 20% PP blend at 20-60 kGy believed to be associated with increased compatibility between PP and EPDM along with the radiation-induced crosslinking. The scanning electron micrographs of the fracture surfaces of the PP/EPDM blends showed evidences consistent with the above contentation. The in vivo studies provide an instinct that the radiated blends are safe to be used for healthcare devices.
    Matched MeSH terms: Elastomers/administration & dosage; Elastomers/chemistry*
  11. Rahman AM, Jamayet NB, Nizami MMUI, Johari Y, Husein A, Alam MK
    J Prosthodont, 2019 Jan;28(1):36-48.
    PMID: 30043482 DOI: 10.1111/jopr.12950
    PURPOSE: This systematic review aims to identify and interpret results of studies that evaluated the changes in the physical properties of maxillofacial prosthetic materials (1) without aging, (2) after natural or artificial accelerated aging, and (3) after outdoor weathering.

    METHODS: Relevant articles written in English only, before January 15, 2017, were identified using an electronic search in the PubMed, Scopus, and Google Scholar databases. Furthermore, a manual search of the related major journals was also conducted to identify more pertinent articles. The relevancy of the articles was verified by screening the title, abstract, and full text if they met the inclusion criteria. A total of 37 articles satisfied the criteria, from which data were extracted for qualitative synthesis.

    RESULTS: Among the 37 included articles, 14 were without aging, 15 were natural or artificial accelerated aging, 7 were outdoor weathering, and 1 contained both artificial aging and outdoor weathering. Only 4 studies out of the 14 without aging had significant observations; whereas 9 articles with natural or artificial aging published significant results, and 3 out of 7 outdoor weathering articles showed significant changes in the evaluated silicone elastomers.

    CONCLUSIONS: Despite the varying research, it seems that the single "ideal" maxillofacial prosthetic material that can provide sufficient resistance against different aging conditions is yet to be identified. Therefore, it is imperative for standardization organizations, the scientific community, and academia to develop modified prosthetic silicones possessing improved physical properties and color stability, limiting the clinical problems regarding degradation of maxillofacial prostheses.

    Matched MeSH terms: Silicone Elastomers*
  12. M. Hafiz, C.M.Salmi, M.Kamarol, M.Mariatti
    MyJurnal
    Nowadays Silicone Rubber (SiR) is recommended in high voltage cable accessories fabrication as it offers excellent electrical and mechanical properties. Electrical tree is one of the phenomenon which contributes to the main factor of SiR insulation breakdown. Recently, a new approach has been applied in order to enhance the insulation strength properties by introducing nano filler in undoped material. Thus, this paper presents the influence of nano-alumina and halloysite nanoclay on electrical tree growth in SiR at 0, 1 vol%, 2 vol% and 3 vol% concentration. The electrical tree growth was investigated at 8kVrms after tree inception voltage (TIV) within 30 minutes under room temperature. The results show reductions of electrical tree growth speed and accumulate damage (%) up to 2 vol% nano-alumina and up to 3 vol% halloysite nanoclay. Nevertheless the presence of 3 vol% nano-alumina in SiR leads to the faster electrical tree growth rate and the worst accumulate damage within 1 minute of electrical tree growth process.
    Matched MeSH terms: Silicone Elastomers
  13. Gautam Sarkhel, Sanjay Manjhi
    Sains Malaysiana, 2013;42:495-501.
    Industrial pollution issue and dark colour of carbon black, clay based non black filler are getting more importance for reinforcing elastomer. EPDM-Kaolin composites with various maleated EPDM concentration have been prepared by mixing on a two roll mill. The rheometry data showed the optimum cure time increases with increasing compatibilizer concentration without decreasing torque value indicating that acidic functional groups comes from compatibilizer could retard cure rate and increase the optimum cure time rather than change in the ultimate cure state. As the filler
    concentration increases, the edge to edge and face to edge interaction between filler and EPDM increases and the free volume between EPDM molecules is reduced, the storage modulus increases. Moreover, the dynamic mechanical analysis also showed the increase in glass transition temperature with increase in filler concentration due to the inter-tubular diffusion of EPDM inside the clay. It was also observed that with increasing filler concentration, the resistivity and dielectric strength decreases and moreover with increasing compatibilizer concentration the resistivity decreases due to better dispersion of filler helps to build conduction path. The morphological study also revealed that homogeneity of filler dispersion increases with increase in compatibilizer concentration.
    Matched MeSH terms: Elastomers
  14. Rahman AM, Jamayet NB, Nizami MMUI, Johari Y, Husein A, Alam MK
    J Prosthet Dent, 2021 Jan 17.
    PMID: 33472753 DOI: 10.1016/j.prosdent.2020.07.026
    STATEMENT OF PROBLEM: The climate of tropical Southeast Asia includes high humidity and ultraviolet radiation that reduce the lifespan of silicone prostheses by inducing changes in their mechanical properties and color stability. Studies on the surface roughness (SR) and mechanical properties of different silicone elastomers (SEs) subjected to the natural tropical weather of Southeast Asia are lacking.

    PURPOSE: The purpose of this in vitro study was to evaluate the SR, tensile strength (TS), and percentage elongation (% E) of different SEs subjected to outdoor weathering in the Malaysian climate.

    MATERIAL AND METHODS: Type-II dumbbell-shaped specimens (N-120) (nonweathered=15, weathered=15) were made from 3 room-temperature vulcanized (A-2000, A-2006, and A-103) and 1 heat-temperature vulcanized (M-511) silicone (Factor II). For 6 months, weathered specimens were subjected to outdoor weathering inside a custom exposure rack. Simultaneously, the nonweathered specimens were kept in a dehumidifier. Subsequently, the SR was measured with a profilometer; TS and % E were measured by using a universal testing machine. Two-way ANOVA was used to compare the means of the tested properties of the nonweathered and weathered specimens, and pairwise comparison was carried out between the silicones (α=.05).

    RESULTS: After outdoor weathering, the SR, TS, and % E were adversely affected by weathering in the Malaysian environment. Among the silicone materials, A-2000 showed the least TS changes (2.51 MPa), while A-2006 demonstrated significant changes in percentage elongation after outdoor weathering (266.5%). M-511 exhibited the highest mean value (2.50 μm) for SR changes. In addition, A-103 SE showed statistically significant differences in most pairwise comparisons for all 3 dependent variables.

    CONCLUSIONS: Based on the evaluation of mechanical properties, A-103 can be suggested as a suitable silicone for maxillofacial prostheses fabricated for tropical climates. However, A-2000 can be a suitable alternative, although significant changes to surface roughness were detected after outdoor weathering.

    Matched MeSH terms: Silicone Elastomers
  15. Ch'ng SY, Andriyana A, Tee YL, Verron E
    Materials (Basel), 2015 Mar 02;8(3):884-898.
    PMID: 28787977 DOI: 10.3390/ma8030884
    The effect of carbon black on the mechanical properties of elastomers is of great interest, because the filler is one of principal ingredients for the manufacturing of rubber products. While fillers can be used to enhance the properties of elastomers, including stress-free swelling resistance in solvent, it is widely known that the introduction of fillers yields significant inelastic responses of elastomers under cyclic mechanical loading, such as stress-softening, hysteresis and permanent set. When a filled elastomer is under mechanical deformation, the filler acts as a strain amplifier in the rubber matrix. Since the matrix local strain has a profound effect on the material's ability to absorb solvent, the study of the effect of carbon black content on the swelling characteristics of elastomeric components exposed to solvent in the presence of mechanical deformation is a prerequisite for durability analysis. The aim of this study is to investigate the effect of carbon black content on the swelling of elastomers in solvent in the presence of static mechanical strains: simple extension and simple torsion. Three different types of elastomers are considered: unfilled, filled with 33 phr (parts per hundred) and 66 phr of carbon black. The peculiar role of carbon black on the swelling characteristics of elastomers in solvent in the presence of mechanical strain is explored.
    Matched MeSH terms: Elastomers
  16. Pourshahrestani S, Zeimaran E, Kadri NA, Gargiulo N, Jindal HM, Hasikin K, et al.
    Mater Sci Eng C Mater Biol Appl, 2019 May;98:1022-1033.
    PMID: 30812986 DOI: 10.1016/j.msec.2019.01.022
    A novel series of silver-doped mesoporous bioactive glass/poly(1,8-octanediol citrate) (AgMBG/POC) elastomeric biocomposite scaffolds were successfully constructed by a salt-leaching technique for the first time and the effect of inclusion of different AgMBG contents (5, 10, and 20 wt%) on physicochemical and biological properties of pure POC elastomer was evaluated. Results indicated that AgMBG particles were uniformly dispersed in the POC matrix and increasing the AgMBG concentration into POC matrix up to 20 wt% enhanced thermal behaviour, mechanical properties and water uptake ability of the composite scaffolds compared to those from POC. The 20%AgMBG/POC additionally showed higher degradation rate in Tris(hydroxymethyl)-aminomethane-HCl (Tris-HCl) compared with pure POC and lost about 26% of its initial weight after soaking for 28 days. The AgMBG phase incorporation also significantly endowed the resulting composite scaffolds with efficient antibacterial properties against Escherichia coli and Staphylococcus aureus bacteria while preserving their favorable biocompatibility with soft tissue cells (i.e., human dermal fibroblast cells). Taken together, our results suggest that the synergistic effect of both AgMBG and POC make these newly designed AgMBG/POC composite scaffold an attractive candidate for soft tissue engineering applications.
    Matched MeSH terms: Elastomers/chemistry*
  17. Ataollahi F, Pramanik S, Moradi A, Dalilottojari A, Pingguan-Murphy B, Wan Abas WA, et al.
    J Biomed Mater Res A, 2015 Jul;103(7):2203-13.
    PMID: 24733741 DOI: 10.1002/jbm.a.35186
    Extracellular environments can regulate cell behavior because cells can actively sense their mechanical environments. This study evaluated the adhesion, proliferation and morphology of endothelial cells on polydimethylsiloxane (PDMS)/alumina (Al2 O3 ) composites and pure PDMS. The substrates were prepared from pure PDMS and its composites with 2.5, 5, 7.5, and 10 wt % Al2 O3 at a curing temperature of 50°C for 4 h. The substrates were then characterized by mechanical, structural, and morphological analyses. The cell adhesion, proliferation, and morphology of cultured bovine aortic endothelial (BAEC) cells on substrate materials were evaluated by using resazurin assay and 1,1'-dioctadecyl-1,3,3,3',3'-tetramethylindocarbocyanine perchlorate-acetylated LDL (Dil-Ac-LDL) cell staining, respectively. The composites (PDMS/2.5, 5, 7.5, and 10 wt % Al2 O3 ) exhibited higher stiffness than the pure PDMS substrate. The results also revealed that stiffer substrates promoted endothelial cell adhesion and proliferation and also induced spread morphology in the endothelial cells compared with lesser stiff substrates. Statistical analysis showed that the effect of time on cell proliferation depended on stiffness. Therefore, this study concludes that the addition of different Al2 O3 percentages to PDMS elevated substrate stiffness which in turn increased endothelial cell adhesion and proliferation significantly and induced spindle shape morphology in endothelial cells.
    Matched MeSH terms: Elastomers/chemistry*
  18. Khairi MHA, Fatah AYA, Mazlan SA, Ubaidillah U, Nordin NA, Ismail NIN, et al.
    Int J Mol Sci, 2019 Aug 21;20(17).
    PMID: 31438576 DOI: 10.3390/ijms20174085
    The existing mold concept of fabricating magnetorheological elastomer (MRE) tends to encounter several flux issues due to magnetic flux losses inside the chamber. Therefore, this paper presents a new approach for enhancing particle alignment through MRE fabrication as a means to provide better rheological properties. A closed-loop mold, which is essentially a fully guided magnetic field inside the chamber, was designed in order to strengthen the magnetic flux during the curing process with the help of silicone oil (SO) plasticizers. The oil serves the purpose of softening the matrix. Scanning electron microscopy (SEM) was used to observe the surface morphology of the fabricated MRE samples. The field-dependent dynamic properties of the MREs were measured several ways using a rheometer, namely, strain sweep, frequency sweep, and magnetic field sweep. The analysis implied that the effectiveness of the MRE was associated with the use of the SO, and the closed-loop mold helped enhance the absolute modulus up to 0.8 MPa. The relative magnetorheological (MR) effects exhibited high values up to 646%. The high modulus properties offered by the MRE with SO are believed to be potentially useful in industry applications, particularly as vibration absorbers, which require a high range of stiffness.
    Matched MeSH terms: Elastomers/chemistry*
  19. Abdul Aziz SA, Mazlan SA, Ubaidillah U, Shabdin MK, Yunus NA, Nordin NA, et al.
    Materials (Basel), 2019 Oct 28;12(21).
    PMID: 31661837 DOI: 10.3390/ma12213531
    Carbon-based particles, such as graphite and graphene, have been widely used as a filler in magnetorheological elastomer (MRE) fabrication in order to obtain electrical properties of the material. However, these kinds of fillers normally require a very high concentration of particles to enhance the conductivity property. Therefore, in this study, the nanosized Ni-Mg cobalt ferrite is introduced as a filler to soften MRE and, at the same time, improve magnetic, rheological, and conductivity properties. Three types of MRE samples without and with different compositions of Mg, namely Co0.5Ni0.2Mg0.3Fe2O4 (A1) and Co0.5Ni0.1Mg0.4Fe2O4 (A2), are fabricated. The characterization related to the micrograph, magnetic, and rheological properties of the MRE samples are analyzed using scanning electron microscopy (SEM), vibrating sample magnetometer (VSM), and the rheometer. Meanwhile, the effect of the nanosized Ni-Mg cobalt ferrites on the electrical resistance property is investigated and compared with the different Mg compositions. It is shown that the storage modulus of the MRE sample with the nanosized Ni-Mg cobalt ferrites is 43% higher than that of the MRE sample without the nanomaterials. In addition, it is demonstrated that MREs with the nanosized Ni-Mg cobalt ferrites exhibit relatively low electrical resistance at the on-state as compared to the off-state condition, because MRE with a higher Mg composition shows lower electrical resistance when higher current flow occurs through the materials. This salient property of the proposed MRE can be effectively and potentially used as an actuator to control the viscoelastic property of the magnetic field or sensors to measure the strain of the flexible structures by the electrical resistance signal.
    Matched MeSH terms: Elastomers
  20. Perkins AN, Inayat-Hussain SH, Deziel NC, Johnson CH, Ferguson SS, Garcia-Milian R, et al.
    Environ Res, 2019 02;169:163-172.
    PMID: 30458352 DOI: 10.1016/j.envres.2018.10.018
    Currently, there are >11,000 synthetic turf athletic fields in the United States and >13,000 in Europe. Concerns have been raised about exposure to carcinogenic chemicals resulting from contact with synthetic turf fields, particularly the infill material ("crumb rubber"), which is commonly fabricated from recycled tires. However, exposure data are scant, and the limited existing exposure studies have focused on a small subset of crumb rubber components. Our objective was to evaluate the carcinogenic potential of a broad range of chemical components of crumb rubber infill using computational toxicology and regulatory agency classifications from the United States Environmental Protection Agency (US EPA) and European Chemicals Agency (ECHA) to inform future exposure studies and risk analyses. Through a literature review, we identified 306 chemical constituents of crumb rubber infill from 20 publications. Utilizing ADMET Predictor™, a computational program to predict carcinogenicity and genotoxicity, 197 of the identified 306 chemicals met our a priori carcinogenicity criteria. Of these, 52 chemicals were also classified as known, presumed or suspected carcinogens by the US EPA and ECHA. Of the remaining 109 chemicals which were not predicted to be carcinogenic by our computational toxicology analysis, only 6 chemicals were classified as presumed or suspected human carcinogens by US EPA or ECHA. Importantly, the majority of crumb rubber constituents were not listed in the US EPA (n = 207) and ECHA (n = 262) databases, likely due to an absence of evaluation or insufficient information for a reliable carcinogenicity classification. By employing a cancer hazard scoring system to the chemicals which were predicted and classified by the computational analysis and government databases, several high priority carcinogens were identified, including benzene, benzidine, benzo(a)pyrene, trichloroethylene and vinyl chloride. Our findings demonstrate that computational toxicology assessment in conjunction with government classifications can be used to prioritize hazardous chemicals for future exposure monitoring studies for users of synthetic turf fields. This approach could be extended to other compounds or toxicity endpoints.
    Matched MeSH terms: Elastomers
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