Displaying publications 1 - 20 of 1007 in total

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  1. Nordin N, Zaini Ambia NFA, Majid SR, Abu Bakar N
    Carbohydr Polym, 2025 Jan 15;348(Pt A):122830.
    PMID: 39562104 DOI: 10.1016/j.carbpol.2024.122830
    This study investigates the preliminary efficacy of drug encapsulation in chitosan hydrogels by cathodic electrodeposition for the encapsulation of the aromatic dye methyl orange to enhance drug delivery in biological systems. Chitosan, a biocompatible and transparent polymer, is known for its ability to effectively encapsulate and transport therapeutic agents, which is critical for sustained and targeted drug release. Methyl orange was selected as a model drug to study the effects of deposition and immersion times on encapsulation efficiency. The effects of deposition and immersion times on encapsulation efficiency were analyzed by synthesizing multilayer hydrogels via electrochemical oxidation. Characterization techniques, including UV-visible spectroscopy, FTIR, and NMR, were employed; FTIR indicated an effective absorption of 4.34 % for Td50Ti60, while UV-Vis showed 46.41 % at Td60Ti50. NMR analysis revealed effective concentrations of 0.47 mM for Td70Ti60 and 0.38 mM for Td60Ti50, indicating that longer immersion times enhance absorption. These findings provide a foundation for further studies aimed at optimizing drug delivery strategies and improving the therapeutic efficacy of encapsulated agents in biological applications.
    Matched MeSH terms: Spectroscopy, Fourier Transform Infrared/methods
  2. Li J, Rao W, Sun Y, Zhou C, Xia Q, He J, et al.
    Food Res Int, 2024 Dec;197(Pt 1):115271.
    PMID: 39593348 DOI: 10.1016/j.foodres.2024.115271
    This study investigated the effects of plasma-activated water (PAW) generated with argon at discharge times of 0, 4, 8, 12, and 16 min on the gel properties and structures of chicken myofibrillar protein (MP). Under treatments of 8, 12, and 16 min, both the gel strength and water retention capacity of MP significantly improved, with the gel strength (0.53 N) peaking at 16 min and the lowest cooking loss(30.38 %). As the treatment time increased from 0 to 16 min, the storage modulus also gradually increased. Results from low-field nuclear magnetic resonance indicated a slowing of water proton mobility, with the proportion of bound water rising from 0.26 % (0 min) to 0.52 % at 16 min. Fourier transform infrared spectroscopy, endogenous fluorescence spectroscopy and scanning electron microscopy confirmed PAW's alteration of MP's secondary and tertiary structures and gel microstructure. Additionally, this study explored the influence of argon PAW's primary active species on MP from a molecular docking perspective·H2O2 could form hydrogen bonds with MP, while O3 and NO2‾could interact via both hydrogen bonds and electrostatic interactions. Thus, PAW can alter protein structure and enhance MP's functional properties, providing insights for applying cold plasma in processing chicken gel products.
    Matched MeSH terms: Spectroscopy, Fourier Transform Infrared
  3. Nordin N, W M Afifi WAF, Majid SR, Abu Bakar N
    Int J Biol Macromol, 2024 Dec;282(Pt 4):137202.
    PMID: 39489246 DOI: 10.1016/j.ijbiomac.2024.137202
    Frequent droughts significantly affect agricultural productivity and highlight the need for effective solutions to improve water availability for crops. This study investigates the potential of chitosan-based hydrogels, biodegradable biopolymers known for their water-retaining properties, to improve soil moisture and promote plant growth during drought periods. Chitosan hydrogels were synthesized using Pluronic F127 and compared with chitosan and chitosan in combination with sodium alginate (CS/Alg-Na). Comprehensive chemical characterizations were performed by Fourier transform infrared spectroscopy (FTIR), nuclear magnetic resonance (NMR) and field emission scanning electron microscopy (FESEM). The CS/Pl-F127 hydrogels showed high porosity and a water absorption capacity of 81.5 %, while the CS/Alg-Na exhibited a denser network with a capacity of 93.35 % and improved mechanical strength. Plants in the CS/Pl-F127 hydrogel had a shoot elongation rate of 5.9 mm/day on Day 9, which continued until Day 40. In contrast, shoot elongation in the CS/Alg-Na hydrogel peaked at 7.1 mm/day on Day 20 and maintained growth under drought conditions until Day 33. These results show that all chitosan-based hydrogels improve water use efficiency. CS/Alg-Na provides the best support for plant growth under drought conditions, followed by CS/Pl-F127 and pure chitosan.
    Matched MeSH terms: Spectroscopy, Fourier Transform Infrared
  4. Zhang J, Noor ZZ, Baharuddin NH, Setu SA, Hamzah MAAM, Zakaria ZA
    World J Microbiol Biotechnol, 2024 Nov 21;40(12):387.
    PMID: 39567441 DOI: 10.1007/s11274-024-04194-6
    This study highlights the biosorption capacity for Cd (II), Cu (II) and Pb (II) by a locally isolated Pseudomonas aeruginosa DR7. At initial concentrations of 150 mg L-1 and 240 min of contact time, P. aeruginosa DR7 showed a 62.56 mg/g removal capacity for Cd (II) at an optimum pH of 6.0, 72.49 mg/g for Cu (II) at an optimum pH of 6.0, and 94.2 mg/g for Pb (II) at an optimum pH of 7.0. The experimental data of Cd (II), Cu (II), and Pb (II) adsorbed by the pseudo-second-order kinetic model correlates well with P. aeruginosa DR7, with R2 all above 0.99, showing that the fitting effect was satisfactory. The isothermal adsorption processes of Cd (II) (0.980) and Cu (II) (0.986) were more consistent with the Freundlich model, whereas Pb (II) was more consistent with the Langmuir model (0.978). FTIR analysis suggested the involvement of hydroxyl, carbonyl, carboxyl, and amine groups present in the inner regions of P. aeruginosa cells during the biosorption process. SEM-EDS analysis revealed that after contact with metals, there were slight changes in the surface appearance of the cells, which confirmed the deposition of metals on the bacterial surface. There was also the possibility of the metals being translocated into the bacterial inner regions by the appearance of electron-dense particles, as observed using TEM. As a conclusion, the removal of metals from solutions using P. aeruginosa DR7 was a plausible alternative as a safe, cheap, and easily used biosorbent.
    Matched MeSH terms: Spectroscopy, Fourier Transform Infrared
  5. Thakur S, Hosny KM, Alissa M, Bairwan RD, Yahya EB, Sabri M, et al.
    Int J Biol Macromol, 2024 Nov;281(Pt 3):136297.
    PMID: 39482132 DOI: 10.1016/j.ijbiomac.2024.136297
    Current alcohol-based sanitizers present safety concerns and are not suitable for all applications. To address the issue, biopolymer hydrogels offer a safer, sustainable alternative due to biocompatibility, biodegradability, and customizable properties. In present study, carboxymethyl cellulose (CMC) was prepared from Durian fruit rind, a tropical fruit byproduct rich in polysaccharides and combined with the synthetic polymer Carbopol to form a hydrogel with homogenization technique. Rambutan (Nephelium lappaceum) leaf extract (RLE) as an antibacterial agent was analyzed for functional, morphological, antibacterial, and structural properties. Phytochemical analysis of RLE confirmed the presence of antibacterial compounds, while Minimum Inhibitory Concentrations (MIC) were 33.3 μg/mL for Escherichia coli and 28.5 μg/mL for Staphylococcus aureus. Additionally, Scanning Electron Microscopy showed significant disruptions in bacterial cell walls. Hydrogel incorporated RLE was produced with improved properties confirmed through viscosity, FT-IR, Disc-diffusion assay and spread plate method analysis. In general, Rambutan leaf extract significantly improves the antibacterial properties of biopolymer-based hydrogels, hence offering a promising, eco-friendly alternative to alcohol-based sanitizers.
    Matched MeSH terms: Spectroscopy, Fourier Transform Infrared
  6. Anwar A, Fatima I, Khan KM, Daalah M, Alawfi BS, Khan NA, et al.
    Exp Parasitol, 2024 Oct;265:108827.
    PMID: 39147119 DOI: 10.1016/j.exppara.2024.108827
    Tetrazoles are five-membered ring aromatic heterocyclic molecules that consist of one carbon and four nitrogen atoms. Several tetrazole-based drugs have shown promising activities against bacteria, fungi, asthma, cancer, hypertension etc. The overall aim of this study was to determine anti-Acanthamoebic properties of tetrazoles and tetrazole-conjugated silver nanoparticles. Tetrazole-conjugated silver nanoparticles were synthesized and confirmed using ultraviolet-visible spectrometry, Dynamic light scattering, and Fourier-transform infrared spectroscopy. Using amoebicidal, encystment, and excystment assays, the findings revealed that tetrazoles exhibited antiamoebic properties and these effects were enhanced when conjugated with silver nanoparticles. Importantly, conjugation with silver nanoparticles inhibited parasite-mediated human cell death in vitro, as measured by lactate dehydrogenase release, but it reduced toxic effects of drugs alone on human cells. Overall, these results showed clearly that tetrazoles exhibit potent antiamoebic properties which can be enhanced by conjugation with silver nanoparticles and these potential in the rational development of therapeutic interventions against parasitic infections such as keratitis and granulomatous amoebic encephalitis due to pathogenic Acanthamoeba.
    Matched MeSH terms: Spectroscopy, Fourier Transform Infrared
  7. Taharuddin NH, Jumaidin R, Mansor MR, Hazrati KZ, Hafila KZ, Md Yusof FA
    Int J Biol Macromol, 2024 Oct;277(Pt 1):133852.
    PMID: 39025171 DOI: 10.1016/j.ijbiomac.2024.133852
    The potential of Hylocereus polyrhizus peel (HPP) as a new eco-friendly reinforcement for thermoplastic sago starch/agar composite (TPSS/agar) was investigated. The integration of HPP into TPSS/agar composite aimed to enhance its mechanical and thermal characteristics. The study employed Fourier transform-infrared spectroscopy (FT-IR), Scanning electron microscopy (SEM), Thermogravimetric analysis (TGA), and Differential Scanning Calorimetry (DSC), as well as mechanical, physical properties and soil burial testing to analyse the composites. The results showed a favourable miscibility between the matrix and filler, while at higher concentrations of HPP, the starch granules became more visible. The tensile and impact properties of the composites improved significantly after incorporating HPP at 20 wt%, with values of 12.73 MPa and 1.87 kJ/m2, respectively. The glass transition temperature (Tg) and initial decomposition temperature (Ton) decreased with the addition of HPP. The density of the composites reduced from 1.51 ± 0.01 to 1.26 ± 0.01 g/cm3 as the HPP amount increased. The environmental properties indicated that the composites can be composted, with weight loss accelerating from 35 to 60 % and 61 to 91 % by the addition of HPP in 2- and 4-weeks' time, respectively. The study demonstrates the potential of TPSS/agar/HPP composites as eco-friendly materials for various applications.
    Matched MeSH terms: Spectroscopy, Fourier Transform Infrared
  8. Loke YH, Phang HC, Gobal G, Vijayaraj Kumar P, Kee PE, Widodo RT, et al.
    Drug Dev Ind Pharm, 2024 Oct;50(10):845-855.
    PMID: 39418138 DOI: 10.1080/03639045.2024.2417999
    INTRODUCTION: Fast melt tablets (FMTs) provide a convenient dosage form that rapidly dissolves on the tongue without the need for water. Cocoa butter serves as a suitable matrix system for FMTs formulation, facilitating rapid disintegration at body temperature.

    OBJECTIVES: This study aimed to formulate FMTs using cocoa butter as a base and investigate the effect of various disintegrants and superdisintegrants on their characteristics.

    METHODS: Cocoa butter-based FMTs were prepared via the fusion molding technique. Different disintegrants and superdisintegrants were added at varying concentrations and subjected to characterization. The optimal formulation was selected and incorporated with 10 mg memantine hydrochloride.

    RESULTS: The optimal FMT formulation consisted of 340 mg cocoa butter, 75 mg starch, and 75 mg crospovidone, exhibiting a hardness of 17.12 ± 0.31 N and a disintegration time of 32.67 ± 0.17 s. Furthermore, FMTs demonstrated a faster release profile compared to the commercially available product, Ebixa. SEM micrographs revealed homogenous blending of individual ingredients within the cocoa butter matrix and FT-IR analysis confirmed the chemical stability of memantine hydrochloride in the formulation. The dissolution profile of F17 suggested that the drug in FMTs released faster compared to Ebixia. Memantine hydrochloride achieved 98.07% of drug release in FMTs at 10 min. Moreover, the prepared FMTs exhibited stability for at least 6 months.

    CONCLUSION: The successful development of cocoa butter-based FMTs containing memantine hydrochloride highlights the potential of cocoa butter as viable alternative matrix-forming material for FMTs production. This innovative formulation offers patients a convenient alternative for medication administration.

    Matched MeSH terms: Spectroscopy, Fourier Transform Infrared/methods
  9. Daood U, Ilyas MS, Ashraf M, Akbar M, Asif A, Khan AS, et al.
    J Oral Maxillofac Surg, 2024 Sep;82(9):1147-1162.
    PMID: 38830601 DOI: 10.1016/j.joms.2024.05.004
    BACKGROUND: Treated or coated sutures promise to prevent contamination of wounds.

    PURPOSE: The purpose of the study was to coat surgical sutures with a new quaternary ammonium silane (QAS) antimicrobial compound at two different application temperatures and then to evaluate the resulting structural, physical, mechanical, and biological properties.

    STUDY DESIGN, SETTING, SAMPLE: In vitro and in vivo studies were conducted using male albino Wistar rats approved by the Joint Ethical Committee of IMU and Postgraduate Medical Institute, Lahore. Only suture samples, coated uniformly with verified presence of the compound and of adequate length were used. Samples which were not coated uniformly and with inadequate length or damaged were excluded.

    PREDICTOR VARIABLE: Predictor variables were sutures with and without QAS coatings and different temperatures. Sutures were coated with QAS at 0.5 and 1.0% wt/vol using the dip coating technique and sutures with and without QAS coating were tested at 25 and 40 °C temperatures.

    MAIN OUTCOME VARIABLE(S): Outcome variables of structural and physico-mechanical properties of QAS-coated and non-coated sutures were measured using Fourier transform infrared spectroscopy (for structural changes), confocal laser and scanning electron (for diameter changes), and tensile strength/modulus (for mechanical testing). Biologic outcome variables were tested (bacterial viability); macrophage cultures from Wistar rats were tested (M1/M2 polarization detecting IL-6 and IL-10). Macrophage cells were analyzed with CD80+ (M1) and CD163+ (M2). Chemotaxis index was calculated as a ratio of quantitative fluorescence of cells.

    COVARIATES: Not applicable.

    ANALYSES: Ordinal data among groups were compared using the Wilcoxon Mann-Whitney U test along with the comparison of histological analysis using the Wilcoxon Sign-rank test (P Fourier transform infrared spectroscopy peak at 1490 cm-1 confirmed the presence of QAS on suture's surfaces with a significant increase (P 

    Matched MeSH terms: Spectroscopy, Fourier Transform Infrared
  10. Niazi FH, Luddin N, Alghawazi AM, Al Sebai L, Alqerban A, Alqahtani YM, et al.
    Microsc Res Tech, 2024 Aug;87(8):1955-1964.
    PMID: 38581370 DOI: 10.1002/jemt.24569
    To incorporate different concentrations of Al2O9Zr3 (1%, 5%, and 10%) nanoparticles (NP) into the ER adhesive and subsequently assess the impact of this addition on the degree of conversion, μTBS, and antimicrobial efficacy. The current research involved a wide-ranging examination that merged various investigative techniques, including the application of scanning electron microscopy (SEM) for surface characterization of NP coupled with energy-dispersive x-ray spectroscopy (EDX), Fourier-transform infrared (FTIR) spectroscopy, μTBS testing, and microbial analysis. Teeth were divided into four groups based on the application of modified and unmodified three-step ER adhesive primer. Group 1 (0% Al2O9Zr3 NPs) Control, Group 2 (1% Al2O9Zr3 NPs), Group 3 (5% Al2O9Zr3 NPs), and Group 4 (10% Al2O9Zr3 NPs). EDX analysis of Al2O9Zr3 NPs was performed showing elemental distribution in synthesized NPs. Zirconium (Zr), Aluminum (Al), and Oxides (O2). After primer application, an assessment of the survival rate of Streptococcus mutans was completed. The FTIR spectra were analyzed to observe the characteristic peaks indicating the conversion of double bonds, both before and after the curing process, for the adhesive Etch and rinse containing 1,5,10 wt% Al2O9Zr3 NPs. μTBS and failure mode assessment were performed using a Universal Testing Machine (UTM) and stereomicroscope respectively. The μTBS and S.mutans survival rates comparison among different groups was performed using one-way ANOVA and Tukey post hoc (p = .05). Group 4 (10 wt% Al2O9Zr3 NPs + ER adhesive) specimens exhibited the minimum survival of S.mutans (0.11 ± 0.02 CFU/mL). Nonetheless, Group 1 (0 wt% Al2O9Zr3 NPs + ER adhesive) displayed the maximum surviving S.mutans (0.52 ± 0.08 CFU/mL). Moreover, Group 2 (1 wt% Al2O9Zr3 NPs + ER adhesive) (21.22 ± 0.73 MPa) samples displayed highest μTBS. However, the bond strength was weakest in Group 1 (0 wt% Al2O9Zr3 NPs + ER adhesive) (14.13 ± 0.32 MPa) study samples. The etch-and-rinse adhesive exhibited enhanced antibacterial activity and micro-tensile bond strength (μTBS) when 1% Al2O9Zr3 NPs was incorporated, as opposed to the control group. Nevertheless, the incorporation of Al2O9Zr3 NPs led to a decrease in DC. RESEARCH HIGHLIGHTS: 10 wt% Al2O9Zr3 NPs + ER adhesive specimens exhibited the minimum survival of S.mutans. 1 wt% Al2O9Zr3 NPs + ER adhesive samples displayed the most strong composite/CAD bond. The highest DC was observed in Group 1: 0 wt% Al2O9Zr3 NPs + ER adhesive.
    Matched MeSH terms: Spectroscopy, Fourier Transform Infrared/methods
  11. Suraparaju SK, Aljaerani HA, Samykano M, Kadirgama K, Noor MM, Natarajan SK
    Environ Sci Pollut Res Int, 2024 Aug;31(38):50166-50178.
    PMID: 38625473 DOI: 10.1007/s11356-024-33151-x
    Molten salts are the operational fluid for most concentrated solar power (CSP) systems, which has attracted more attention among the scientific community due to the augmentation of their properties with the doping of nanoparticles. Hexagonal boron nitride (h-BN) nanoparticles were dispersed in HITEC molten salt to create a novel nanofluid and evaluate the h-BN nanoparticles' influence on HITEC thermophysical properties. The influence of nanoparticle concentration (0.1, 0.5, and 1wt.%) of h-BN and HITEC was studied in this research. HITEC and nano-enhanced HITEC molten salt (NEHMS) were characterized using energy-dispersive X-ray spectroscopy (EDX), field emission scanning electron microscopy (FESEM), and Fourier transform infrared spectroscopy (FT-IR). Specific heat capacity, latent heat, and melting temperature were assessed using differential scanning calorimetry (DSC). The maximum working temperature was evaluated with thermogravimetric analysis (TGA). The ideal nanoparticle concentration is 0.1 wt.% h-BN, which results in a 27% increase in heat capacity, a 72% increase in latent heat, and a 7% enhancement in thermal stability. The thermal cycling stability test proved the stability of the enhanced thermophysical properties. The material characterization revealed that the samples with improved thermophysical properties have a homogeneous dispersion of nanoparticles with minor nanoparticle agglomeration. The system advisor model (SAM) simulation comparison of the optimum sample with solar salt and HITEC salt revealed that using the optimum sample increases CSP plant efficiency by 0.4% and reduces power costs by 0.13¢/kWh.
    Matched MeSH terms: Spectroscopy, Fourier Transform Infrared
  12. Manojkumar U, Kaliannan D, Balasubramanian B, Kamyab H, Vasseghian Y, Chelliapan S, et al.
    Environ Geochem Health, 2024 Jun 07;46(7):221.
    PMID: 38849635 DOI: 10.1007/s10653-024-02000-8
    This study reported the synthesis and assessment of zinc oxide/iron oxide (ZnO/Fe2O3) nanocomposite as photocatalysts for the degradation of a mixture of methylene red and methylene blue dyes. X-ray diffraction analysis confirms that the crystallite of zinc oxide (ZnO) has a hexagonal wurtzite phase and iron oxide (Fe2O3) has a rhombohedral phase. Fourier Transform Infra-Red spectrum confirms the presence of Zn-O vibration stretching at 428, 480 and 543 cm-1 stretching confirming Fe-O bond formation. Scanning Electron Microscope images exhibited a diverse size and shape of the nanocomposites. The ZnO-90%/Fe2O3-10% and ZnO-10%/Fe2O3-90% nanocomposites reveal good photocatalytic activity with reaction rate constants of 1.5 × 10-2 and 0.66 × 10-2; and 1.3 × 10-2 and 0.60 × 10-2 for methylene blue and methyl red dye respectively. The results revealed that the synthesized ZnO/Fe2O3 nanocomposite is the best catalyst for dye degradation and can be used for industrial applications in future.
    Matched MeSH terms: Spectroscopy, Fourier Transform Infrared
  13. Salimi E, Asim MH, Abidin MNZ
    Sci Rep, 2024 May 11;14(1):10798.
    PMID: 38734777 DOI: 10.1038/s41598-024-61586-2
    The nucleation of carbonate-containing apatite on the biomaterials surface is regarded as a significant stage in bone healing process. In this regard, composites contained hydroxyapatite (Ca10(PO4)6(OH)2, HA), wollastonite (CaSiO3, WS) and polyethersulfone (PES) were synthesized via a simple solvent casting technique. The in-vitro bioactivity of the prepared composite films with different weight ratios of HA and WS was studied by placing the samples in the simulated body fluid (SBF) for 21 days. The results indicated that the the surface of composites containing 2 wt% HA and 4 wt% WS was completely covered by a thick bone-like apatite layer, which was characterized by Grazing incidence X-ray diffraction, attenuated total reflectance-Fourier transform infrared spectrometer, field emission electron microscopy and energy dispersive X-ray analyzer (EDX). The degradation study of the samples showed that the concentration of inorganic particles could not influence the degradability of the polymeric matrix, where all samples expressed similar dexamethasone (DEX) release behavior. Moreover, the in-vitro cytotoxicity results indicated the significant cyto-compatibility of all specimens. Therefore, these findings revealed that the prepared composite films composed of PES, HA, WS and DEX could be regarded as promising bioactive candidates with low degradation rate for bone tissue engineering applications.
    Matched MeSH terms: Spectroscopy, Fourier Transform Infrared
  14. Javaid MA, Cheema SA, Nasir N, Ahmad S, Hussain MT, Tanveer Z, et al.
    Int J Biol Macromol, 2024 May;267(Pt 2):131441.
    PMID: 38583848 DOI: 10.1016/j.ijbiomac.2024.131441
    The thermal stability of polyurethanes, known for its limitations, was addressed in this research by seeking improvement through the introduction of carbohydrate-based chain extenders. In this research paper, we systematically sought to improve the thermal resistance of polyurethanes by incorporating carboxymethyl cellulose and chitosan, representing a pioneering application of the mixture design approach in their preparation. In this synthesis, hydroxyl-terminated polybutadiene and isophorone diisocyanate (IPDI) were reacted to prepare -NCO terminated prepolymer, which was subsequently reacted with varying mole ratios of CMC and CSN to develop a series of five PU samples. The prepared PU samples were characterized using the Fourier-transformed infrared spectroscopic technique. Thermal pyrolysis of PU samples was examined using thermal gravimetric analysis (TGA). It was observed that, among all the samples, PUS-3 showed remarkable thermal stability over a wide temperature range. A comprehensive statistical analysis was conducted to substantiate the experimental findings. It was estimated that CMC and CSN significantly enhance the thermal stability of the samples when involved in an interaction fashion. The ANOVA Table for the mixture design demonstrates that over 90 % of the total variation in thermal stability is explained by the mixture model across a wide temperature range. Moreover, PSU-3 exhibited 4 % more thermal stability over a wide range of temperatures on average, as compared to contemporary samples.
    Matched MeSH terms: Spectroscopy, Fourier Transform Infrared
  15. Fayyaz Z, Farrukh MA, Ul-Hamid A, Chong KK
    Microsc Res Tech, 2024 May;87(5):957-976.
    PMID: 38174385 DOI: 10.1002/jemt.24487
    The present exploration demonstrates the efficient, sustainable, cost-effective, and environment-friendly green approach for the synthesis of silver (Ag)-doped copper oxide (CuO) embedded with reduced graphene oxide (rGO) nanocomposite using the green one-pot method and the green deposition method. Leaf extracts of Ficus carica and Azadirachta indica were used for both methods as reducing and capping agents. The effect of methodology and plant extract was analyzed through different characterization techniques such as UV-visible spectroscopy, Fourier transform infrared (FT-IR) spectroscopy, thermogravimetric analysis (TGA), x-ray diffraction (XRD) analysis, scanning electron microscopy (SEM), high-resolution transmission electron microscopy (HRTEM). The lowest band gap of 3.0 eV was observed for the Ag/CuO/rGO prepared by the green one-pot method using F. carica. The reduction of graphene oxide (GO) and the formation of metal oxide was confirmed through functional group detection using FT-IR. Calculation of thermodynamic parameters showed that all reactions involved were nonspontaneous and endothermic which shows the stability of nanocomposites. XRD studies revealed the crystallinity, phase purity and small average crystallite size of 32.67 nm. SEM images disclosed that the morphology of the nanocomposites was spherical with agglomeration and rough texture. The particle size of the nanocomposites calculated through HRTEM was found in agreement with the XRD results. The numerous properties of the synthesized nanocomposites enhanced their potential against the degradation of methylene blue, rhodamine B, and ciprofloxacin. The highest percentage degradation of Ag/CuO/rGO was found to be 97%, synthesized using the green one-pot method with F. carica against ciprofloxacin, which might be due to the lowest band gap, delayed electron-hole pair recombination, and large surface area available. The nanocomposites were also tested against the Gram-positive and Gram-negative bacteria. RESEARCH HIGHLIGHTS: Facile synthesis of Ag/CuO/rGO nanocomposite using a green one-pot method and the green deposition method. The lowest band gap of 3.0 eV was observed for nanocomposite prepared by a green one-pot method using Ficus carica. Least average crystallite size of 32.67 nm was found for nanocomposite prepared by a green one-pot method using F. carica. Highest antibacterial and catalytic activity (97%) was obtained against ciprofloxacin with nanocomposite prepared through green one-pot method using F. carica. A mechanism of green synthesis is proposed.
    Matched MeSH terms: Spectroscopy, Fourier Transform Infrared
  16. Azadi S, Azizipour E, Amani AM, Vaez A, Zareshahrabadi Z, Abbaspour A, et al.
    Sci Rep, 2024 Mar 11;14(1):5855.
    PMID: 38467729 DOI: 10.1038/s41598-024-56512-5
    The antifungal efficacy and cytotoxicity of a novel nano-antifungal agent, the Fe3O4@SiO2/Schiff-base complex of Cu(II) magnetic nanoparticles (MNPs), have been assessed for targeting drug-resistant Candida species. Due to the rising issue of fungal infections, especially candidiasis, and resistance to traditional antifungals, there is an urgent need for new therapeutic strategies. Utilizing Schiff-base ligands known for their broad-spectrum antimicrobial activity, the Fe3O4@SiO2/Schiff-base/Cu(II) MNPs have been synthesized. The Fe3O4@SiO2/Schiff-base/Cu(II) MNPs was characterized by Fourier Transform-Infrared Spectroscopy (FT-IR), X-ray Diffraction (XRD), Transmission Electron Microscopy (TEM), Scanning Electron Microscopy (SEM), Dynamic Light Scattering (DLS), Energy-dispersive X-ray (EDX), Vibrating Sample Magnetometer (VSM), and Thermogravimetric analysis (TGA), demonstrating successful synthesis. The antifungal potential was evaluated against six Candida species (C. dubliniensis, C. krusei, C. tropicalis, C. parapsilosis, C. glabrata, and C. albicans) using the broth microdilution method. The results indicated strong antifungal activity in the range of 8-64 μg/mL with the lowest MIC (8 μg/mL) observed against C. parapsilosis. The result showed the MIC of 32 μg/mL against C. albicans as the most common infection source. The antifungal mechanism is likely due to the disruption of the fungal cell wall and membrane, along with increased reactive oxygen species (ROS) generation leading to cell death. The MTT (3-[4,5-dimethylthiazol-2-yl]-2,5-diphenyltetrazolium bromide) assay for cytotoxicity on mouse L929 fibroblastic cells suggested low toxicity and even enhanced cell proliferation at certain concentrations. This study demonstrates the promise of Fe3O4@SiO2/Schiff-base/Cu(II) MNPs as a potent antifungal agent with potential applications in the treatment of life-threatening fungal infections, healthcare-associated infections, and beyond.
    Matched MeSH terms: Spectroscopy, Fourier Transform Infrared
  17. Jamion NA, Lee KE, Mokhtar M, Goh TL
    Environ Sci Pollut Res Int, 2024 Mar;31(11):16291-16308.
    PMID: 38315340 DOI: 10.1007/s11356-024-32140-4
    Ex-mining lake-converted constructed wetlands play a significant role in the carbon cycle, offering a great potential to sequester carbon and mitigate climate change and global warming. Investigating the quantity of carbon storage capacity of ex-mining lake-converted constructed wetlands provides information and justification for restoration and conservation efforts. The present study aims to quantify the carbon pool of the ex-mining lake-converted constructed wetlands and characterise the physicochemical properties of the soil and sediment. Pearson's correlation and a one-way ANOVA were performed to compare the different sampling stations at Paya Indah Wetland, Selangor, Malaysia. An analysis of 23 years of ex-mining lake-converted constructed wetlands of Paya Indah Wetlands, Selangor, Malaysia, revealed that the estimated total carbon pool in soil and sediment accumulated to 1553.11 Mg C ha-1 (equivalent to 5700 Mg CO2 ha-1), which translates to an annual carbon sink capacity of around 67.5 Mg C ha-1 year-1. The characterisation showed that the texture of all soil samples was dominated by silt, whereas sediments exhibited texture heterogeneity. Although the pH of the soil and sediment was both acidic, the bulk density was still optimal for plant growth and did not affect root growth. FT-IR and WDXRF results supported that besides the accumulation and degradation of organic substances, which increase the soil and sediment carbon content, mineral carbonation is a mechanism by which soil and sediment can store carbon. Therefore, this study indicates that the ex-mining lake-converted constructed wetlands of Paya Indah Wetlands, Selangor, Malaysia have a significant carbon storage potential.
    Matched MeSH terms: Spectroscopy, Fourier Transform Infrared
  18. Zakaria DS, Rozi SKM, Halim HNA, Mohamad S, Zheng GK
    Environ Sci Pollut Res Int, 2024 Mar;31(11):16309-16327.
    PMID: 38315341 DOI: 10.1007/s11356-024-32285-2
    Climate change caused by the greenhouse gases CO2 remains a topic of global concern. To mitigate the excessive levels of anthrophonic CO2 in the atmosphere, CO2 capture methods have been developed and among these, adsorption is an especially promising method. This paper presents a series of amine functionalized biochar obtained from desiccated coconut waste (amine-biochar@DCW) for use as CO2 adsorbent. They are ethylenediamine-functionalized biochar@DCW (EDA-biochar@DCW), diethylenetriamine-functionalized biochar@DCW (DETA-biochar@DCW), triethylenetetramine-functionalized biochar@DCW (TETA-biochar@DCW), tetraethylenepentamine-functionalized biochar@DCW (TEPA-biochar@DCW), and pentaethylenehexamine-functionalized biochar@DCW (PEHA-biochar@DCW). The adsorbents were obtained through amine functionalization of biochar and they are characterized using Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), energy dispersive X-ray (EDX) spectroscopy, Brunauer-Emmett-Teller (BET), and thermogravimetric analysis (TGA). The CO2 adsorption study was conducted isothermally and using a thermogravimetric analyzer. From the results of the characterization analyses, a series of amine-biochar@DCW adsorbents had larger specific surface area in the range of 16.2 m2/g-37.1 m2/g as compare to surface area of pristine DCW (1.34 m2/g). Furthermore, the results showed an increase in C and N contents as well as the appearance of NH stretching, NH bending, CN stretching, and CN bending, suggesting the presence of amine on the surface of biochar@DCW. The CO2 adsorption experiment shows that among the amine modified biochar adsorbents, TETA-biochar@DCW has the highest CO2 adsorption capacity (61.78 mg/g) when using a mass ratio (m:m) of biochar@DCW:TETA (1:2). The adsorption kinetics on the TETA-biochar@DCW was best fitted by the pseudo-second model (R2 = 0.9998), suggesting the adsorption process occurs through chemisorption. Additionally, TETA-biochar@DCW was found to have high selectivity toward CO2 gas and good reusability even after five CO2 adsorption-desorption cycles. The results demonstrate the potential of novel CO2 adsorbents based on amine functionalized on desiccated coconut waste biochar.
    Matched MeSH terms: Spectroscopy, Fourier Transform Infrared
  19. Kadir NHA, Murugan N, Khan AA, Sandrasegaran A, Khan AU, Alam M
    Microsc Res Tech, 2024 Mar;87(3):602-615.
    PMID: 38018343 DOI: 10.1002/jemt.24437
    This study aimed to investigate the characterization of zinc oxide nanoparticles (ZnONPs) produced from Cucurbita pepo L. (pumpkin seeds) and their selective cytotoxic effectiveness on human colon cancer cells (HCT 116) and African Green Monkey Kidney, Vero cells. The study also investigated the antioxidant activity of ZnONPs. The study also examined ZnONPs' antioxidant properties. This was motivated by the limited research on the comparative cytotoxic effects of ZnO NPs on normal and HCT116 cells. The ZnO NPs were characterized using Fourier-transform infrared spectroscopy (FTIR), Thermogravimetric Analysis (TGA), Transmission Electron Microscope/Selected Area Electron Diffraction (TEM/SAED), and Scanning Electron Microscope-Energy Dispersive X-ray (SEM-EDX) for determination of chemical fingerprinting, heat stability, size, and morphology of the elements, respectively. Based on the results, ZnO NPs from pumpkins were found to be less than 5 μm and agglomerates in nature. Furthermore, the ZnO NPs fingerprinting and SEM-EDX element analysis were similar to previous literature, suggesting the sample was proven as ZnO NPs. The ZnO NPs also stable at a temperature of 380°C indicating that the green material is quite robust at 60-400°C. The cell viability of Vero cells and HCT 116 cell line were measured at two different time points (24 and 48 h) to assess the cytotoxicity effects of ZnO NP on these cells using AlamarBlue assay. Cytotoxic results have shown that ZnO NPs did not inhibit Vero cells but were slightly toxic to cancer cells, with a dose-response curve IC50 = ~409.7 μg/mL. This green synthesis of ZnO NPs was found to be non-toxic to normal cells but has a slight cytotoxicity effect on HCT 116 cells. A theoretical study used molecular docking to investigate nanoparticle interaction with cyclin-dependent kinase 2 (CDK2), exploring its mechanism in inhibiting CDK2's role in cancer. Further study should be carried out to determine suitable concentrations for cytotoxicity studies. Additionally, DPPH has a significant antioxidant capacity, with an IC50 of 142.857 μg/mL. RESEARCH HIGHLIGHTS: Pumpkin seed extracts facilitated a rapid, high-yielding, and environmentally friendly synthesis of ZnO nanoparticles. Spectrophotometric analysis was used to investigate the optical properties, scalability, size, shape, dispersity, and stability of ZnO NPs. The cytotoxicity of ZnO NPs on Vero and HCT 116 cells was assessed, showing no inhibition of Vero cells and cytotoxicity of cancer cells. The DPPH assay was also used to investigate the antioxidant potential of biogenic nanoparticles. A molecular docking study was performed to investigate the interaction of ZnO NPs with CDK2 and to explore the mechanism by which they inhibit CDK2's role in cancer.
    Matched MeSH terms: Spectroscopy, Fourier Transform Infrared
  20. Amjad M, Mohyuddin A, Ulfat W, Goh HH, Dzarfan Othman MH, Kurniawan TA
    J Environ Manage, 2024 Feb 27;353:120287.
    PMID: 38335595 DOI: 10.1016/j.jenvman.2024.120287
    Textile wastewater laden with dyes has emerged as a source of water pollution. This possesses a challenge in its effective treatment using a single functional material. In respond to this technological constraint, this work presents multifunctional cotton fabrics (CFs) within a single, streamlined preparation process. This approach utilizes the adherence of Ag NPs (nanoparticles) using Si binder on the surface of CFs, resulting in Ag-coated CFs through a pad dry method. The prepared samples were characterized using scanning electron microscope-energy dispersive X-ray electroscopy (SEM-EDS), thermal gravimetric analysis (TGA), Fourier transformation infrared (FT-IR). It was found that the FT-IR spectra of Ag NPs-coated CFs had peaks appear at 3400, 2900, and 1200 cm-1, implying the stretching vibrations of O-H, C-H, and C-O, respectively. Based on the EDX analysis, the presence of C, O, and Ag related to the coated CFs were detected. After coating the CFs with varying concentrations of Ag NPs (1%, 2% and 3% (w/w)), they were used to remove dyes. Under the same concentration of 10 mg/L and optimized pH 7.5 and 2 h of reaction time, 3% (w/w) Ag-coated CFs exhibited a substantial MB degradation of 98 %, while removing 95% of methyl orange, 85% of rhodamine B, and 96% of Congo red, respectively, following 2 h of Vis exposure. Ag NPs had a strong absorption at 420 nm with 2.51 eV of energy band gap. Under UV irradiation, electrons excited and produced free radicals that promoted dyes photodegradation. The oxidation by-products included p-dihydroxybenzene and succinic acid. Spent Ag-coated CFs attained 98% of regeneration efficiency. The utilization of Ag-coated CFs as a photocatalyst facilitated treated effluents to meet the required discharge standard of lower than 1 mg/L mandated by national legislation. The integration of multifunctional CFs in the treatment system presents a new option for tackling water pollution due to dyes.
    Matched MeSH terms: Spectroscopy, Fourier Transform Infrared
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