Displaying publications 21 - 40 of 504 in total

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  1. Nikmatin S, Hermawan B, Irmansyah I, Indro MN, Kueh ABH, Syafiuddin A
    Materials (Basel), 2018 Dec 22;12(1).
    PMID: 30583516 DOI: 10.3390/ma12010034
    The performance of helmet prototypes fabricated from acrylonitrile butadiene styrene composites filled with oil palm empty fruit bunch fibers was evaluated. The fibers were produced using a milling procedure, while the composites were fabricated using a single-screw extrusion. The physical characteristics of the produced fibers, which are water content, size, and density, were investigated. In addition, the mechanical properties of the produced helmets, including shock absorption, yield stress, frequency, and head injury criterion (HIC), were examined. The impact strength of the produced helmets increases with the rise of filler content. In addition, the helmets were also able to withstand a considerable pressure such that the transmitted pressure was far under the maximum value acceptable by the human skull. The present work also found that HICs exhibited by the investigated helmet prototypes fulfill all the practical guidelines as permitted by the Indonesian government. In terms of novelty, such innovation can be considered the first invention in Indonesia since the endorsement of the use of motorcycle helmets.
  2. Karunarathne VK, Paul SC, Šavija B
    Materials (Basel), 2019 Aug 17;12(16).
    PMID: 31426501 DOI: 10.3390/ma12162622
    In this study, the use of nano-silica (nano-SiO2) and bentonite as mortar additives for combating reinforcement corrosion is reported. More specifically, these materials were used as additives in ordinary Portland cement (OPC)/fly ash blended mortars in different amounts. The effects of nano-silica and bentonite addition on compressive strength of mortars at different ages was tested. Accelerated corrosion testing was used to assess the corrosion resistance of reinforced mortar specimens containing different amounts of nano-silica and bentonite. It was found that the specimens containing nano-SiO2 not only had higher compressive strength, but also showed lower steel mass loss due to corrosion compared to reference specimens. However, this was accompanied by a small reduction in workability (for a constant water to binder ratio). Mortar mixtures with 4% of nano-silica were found to have optimal performance in terms of compressive strength and corrosion resistance. Control specimens (OPC/fly ash mortars without any additives) showed low early age strength and low corrosion resistance compared to specimens containing nano-SiO2 and bentonite. In addition, samples from selected mixtures were analyzed using scanning electron microscopy (SEM) and energy-dispersive X-ray spectroscopy (EDX). Finally, the influence of Ca/Si ratio of the calcium silicate hydrate (C-S-H) in different specimens on the compressive strength is discussed. In general, the study showed that the addition of nano-silica (and to a lesser extent bentonite) can result in higher strength and corrosion resistance compared to control specimens. Furthermore, the addition of nano-SiO2 can be used to offset the negative effect of fly ash on early age strength development.
  3. Zhalehrajabi E, Lau KK, Ku Shaari KZ, Zahraee SM, Seyedin SH, Azeem B, et al.
    Materials (Basel), 2019 Jul 20;12(14).
    PMID: 31330846 DOI: 10.3390/ma12142320
    Granulation is an important step during the production of urea granules. Most of the commercial binders used for granulation are toxic and non-biodegradable. In this study, a fully biodegradable and cost-effective starch-based binder is used for urea granulation in a fluidized bed granulator. The effect of binder properties such as viscosity, surface tension, contact angle, penetration time, and liquid bridge bonding force on granulation performance is studied. In addition, the effect of fluidized bed process parameters such as fluidizing air inlet velocity, air temperature, weight of primary urea particles, binder spray rate, and binder concentration is also evaluated using response surface methodology. Based on the results, binder with higher concentration demonstrates higher viscosity and higher penetration time that potentially enhance the granulation performance. The viscous Stokes number for binder with higher concentration is lower than critical Stokes number that increases coalescence rate. Higher viscosity and lower restitution coefficient of urea particles result in elastic losses and subsequent successful coalescence. Statistical analysis indicate that air velocity, air temperature, and weight of primary urea particles have major effects on granulation performance. Higher air velocity increases probability of collision, whereby lower temperature prevents binder to be dried up prior to collision. Findings of this study can be useful for process scale-up and industrial application.
  4. Al-Nabulsi M, Daud A, Yiu C, Omar H, Sauro S, Fawzy A, et al.
    Materials (Basel), 2019 Aug 07;12(16).
    PMID: 31394743 DOI: 10.3390/ma12162504
    Objective: To evaluate the effect of a new application method of bulk-fill flowable composite resin material on bond-strength, nanoleakage, and mechanical properties of dentine bonding agents.

    MATERIALS AND METHODS: Sound extracted human molars were randomly divided into: manufacturer's instructions (MI), manual blend 2 mm (MB2), and manual blend 4 mm (MB4). Occlusal enamel was removed and flattened, dentin surfaces were bonded by Prime & Bond universal (Dentsply and Optibond FL, Kerr). For the MI group, adhesives were applied following the manufacturer's instructions then light-cured. For MB groups, SDR flow+ bulk-fill flowable composite resin was applied in 2- or 4-mm increment then manually rubbed by a micro brush for 15 s with uncured dentine bonding agents and the mixture was light-cured. Composite buildup was fabricated incrementally using Ceram.X One, Dentsply nanohybrid composite resin restorative material. After 24-h water storage, the teeth were sectioned to obtain beams of about 0.8 mm2 for 24-h and thermocycled micro-tensile bond strength at 0.5 mm/min crosshead speed. Degree of conversion was evaluated with micro-Raman spectroscopy. Contraction gaps at 24 h after polymerization were evaluated and atomic force microscopy (AFM) nano-indentation processes were undertaken for measuring the hardness across the interface. Depth of resin penetration was studied using a scanning electron microscope (SEM). Bond strength data was expressed using two-way ANOVA followed by Tukey's test. Nanoindentation hardness was separately analyzed using one-way ANOVA.

    RESULTS: Factors "storage F = 6.3" and "application F = 30.11" significantly affected the bond strength to dentine. For Optibond FL, no significant difference in nanoleakage was found in MI/MB4 groups between baseline and aged specimens; significant difference in nanoleakage score was observed in MB2 groups. Confocal microscopy analysis showed MB2 Optibond FL and Prime & Bond universal specimens diffusing within the dentine. Contraction gap was significantly reduced in MB2 specimens in both adhesive systems. Degree of conversion (DC) of the MB2 specimens were numerically more compared to MS1 in both adhesive systems.

    CONCLUSION: Present study suggests that the new co-blend technique might have a positive effect on bond strengths of etch-and-rinse adhesives to dentine.

  5. Mohajerani A, Hui SQ, Mirzababaei M, Arulrajah A, Horpibulsuk S, Abdul Kadir A, et al.
    Materials (Basel), 2019 Aug 07;12(16).
    PMID: 31394815 DOI: 10.3390/ma12162513
    Fibres have been used in construction materials for a very long time. Through previous research and investigations, the use of natural and synthetic fibres have shown promising results, as their presence has demonstrated significant benefits in terms of the overall physical and mechanical properties of the composite material. When comparing fibre reinforcement to traditional reinforcement, the ratio of fibre required is significantly less, making fibre reinforcement both energy and economically efficient. More recently, waste fibres have been studied for their potential as reinforcement in construction materials. The build-up of waste materials all around the world is a known issue, as landfill space is limited, and the incineration process requires considerable energy and produces unwanted emissions. The utilisation of waste fibres in construction materials can alleviate these issues and promote environmentally friendly and sustainable solutions that work in the industry. This study reviews the types, properties, and applications of different fibres used in a wide range of materials in the construction industry, including concrete, asphalt concrete, soil, earth materials, blocks and bricks, composites, and other applications.
  6. Ikramullah, Rizal S, Nakai Y, Shiozawa D, Khalil HPSA, Huzni S, et al.
    Materials (Basel), 2019 Jul 10;12(14).
    PMID: 31295885 DOI: 10.3390/ma12142225
    The aim of this paper is to evaluate the Mode II interfacial fracture toughness and interfacial shear strength of Typha spp. fiber/PLLA and Typha spp. fiber/epoxy composite by using a double shear stress method with 3 fibers model composite. The surface condition of the fiber and crack propagation at the interface between the fiber and the matrix are observed by scanning electron microscope (SEM). Alkali treatment on Typha spp. fiber can make the fiber surface coarser, thus increasing the value of interfacial fracture toughness and interfacial shear strength. Typha spp. fiber/epoxy has a higher interfacial fracture value than that of Typha spp. fiber/PLLA. Interfacial fracture toughness on Typha spp. fiber/PLLA and Typha spp. fiber/epoxy composite model specimens were influenced by the matrix length, fiber spacing, fiber diameter and bonding area. Furthermore, the interfacial fracture toughness and the interfacial fracture shear stress of the composite model increased with the increasing duration of the surface treatment.
  7. Shafiq N, Kumar R, Zahid M, Tufail RF
    Materials (Basel), 2019 Jul 17;12(14).
    PMID: 31319615 DOI: 10.3390/ma12142291
    This paper discussed the effects of modified metakaolin (MK) with nano-silica (NS) on the mechanical properties and durability of concrete. In the first phase, trial mixes of concrete were prepared for achieving the desired value of the 28 days compressive strength, and the charge passed in rapid chloride permeability test (RCPT). In the second phase, statistical analysis was performed on the experimental results using the response surface method (RSM). The RSM was applied for optimizing the mix proportions for the required performance by exploiting the relationship between the mix characteristics and the corresponding test results. A blend of 10% MK + 1% NS as part of cement replacement exhibited the highest mechanical properties and durability characteristics of concrete; concrete mix showed that the 28-days compressive strength (CS) was 103 MPa, which was 15% greater than the CS of the control mix without MK or NS. The same mix showed more than 40% higher flexural and split-tensile strength than the control mix; also it resulted in a reduction of 73% in the rapid chloride permeability value. ANOVA technique was used for optimizing the nano-silica and metakaolin content for achieving maximum compressive strength and minimum RCPT value. Statistical analysis using ANOVA technique showed that the maximum compressive strength and lowest RCPT value could be achieved with a blend of 10% MK and 1.55% NS.
  8. Khan MJ, Kumari S, Shameli K, Selamat J, Sazili AQ
    Materials (Basel), 2019 Jul 26;12(15).
    PMID: 31357398 DOI: 10.3390/ma12152382
    Nanoparticles (NPs) are, frequently, being utilized in multi-dimensional enterprises. Silver nanoparticles (AgNPs) have attracted researchers in the last decade due to their exceptional efficacy at very low volume and stability at higher temperatures. Due to certain limitations of the chemical method of synthesis, AgNPs can be obtained by physical methods including sun rays, microwaves and ultraviolet (UV) radiation. In the current study, the synthesis of pullulan mediated silver nanoparticles (P-AgNPs) was achieved through ultraviolet (UV) irradiation, with a wavelength of 365 nm, for 96 h. P-AgNPs were formed after 24 h of UV-irradiation time and expressed spectra maxima as 415 nm, after 96 h, in UV-vis spectroscopy. The crystallographic structure was "face centered cubic (fcc)" as confirmed by powder X-ray diffraction (PXRD). Furthermore, high resolution transmission electron microscopy (HRTEM) proved that P-AgNPs were covered with a thin layer of pullulan, with a mean crystalline size of 6.02 ± 2.37. The average lattice fringe spacing of nanoparticles was confirmed as 0.235 nm with quasi-spherical characteristics, by selected area electron diffraction (SAED) analysis. These green synthesized P-AgNPs can be utilized efficiently, as an active food and meat preservative, when incorporated into the edible films.
  9. Arab A, Sktani ZDI, Zhou Q, Ahmad ZA, Chen P
    Materials (Basel), 2019 Jul 31;12(15).
    PMID: 31370216 DOI: 10.3390/ma12152440
    Zirconia toughened alumina (ZTA) is a promising advanced ceramic material for a wide range of applications that are subjected to dynamic loading. Therefore, the investigation of dynamic compressive strength, fracture toughness and hardness is essential for ZTA ceramics. However, the relationship between these mechanical properties in ZTA has not yet been established. An example of this relationship is demonstrated using ZTA samples added with MgO prepared through conventional sintering. The microstructure and mechanical properties of ZTA composites were characterized. The hardness of ZTA composites increased for ≤0.7 wt.% MgO due to the pinning effect of MgO and decrease of the porosity in the microstructure. Oppositely, the fracture toughness of ZTA composites continuously decreased due to the size reduction of Al2O3 grains. This is the main reason of deteriorate of dynamic compressive strength more than 0.2 wt.% of MgO addition. Therefore, the SHPB test shows the improvement of the dynamic compressive strength only up to a tiny amount (0.2 wt.% of MgO addition) into ZTA ceramics.
  10. Lal LPJ, Ramesh S, Parasuraman S, Natarajan E, Elamvazuthi I
    Materials (Basel), 2019 Sep 20;12(19).
    PMID: 31547117 DOI: 10.3390/ma12193057
    Nanosilica particles were utilized as secondary reinforcement to enhance the strength of the epoxy resin matrix. Thin glass fibre reinforced polymer (GFRP) composite laminates of 3 ± 0.25 mm were developed with E-Glass mats of 610 GSM and LY556 epoxy resin. Nanosilica fillers were mixed with epoxy resin in the order of 0.25, 0.5, 0.75 and 1 wt% through mechanical stirring followed by an ultrasonication method. Thereafter, the damage was induced on toughened laminates through low-velocity drop weight impact tests and the induced damage was assessed through an image analysis tool. The residual compression strength of the impacted laminates was assessed through compression after impact (CAI) experiments. Laminates with nanosilica as secondary reinforcement exhibited enhanced compression strength, stiffness, and damage suppression. Results of Fourier-transform infrared spectroscopy revealed that physical toughening mechanisms enhanced the strength of the nanoparticle-reinforced composite. Failure analysis of the damaged area through scanning electron microscopy (SEM) evidenced the presence of key toughening mechanisms like damage containment through micro-cracks, enhanced fiber-matrix bonding, and load transfer.
  11. Mohajerani A, Burnett L, Smith JV, Kurmus H, Milas J, Arulrajah A, et al.
    Materials (Basel), 2019 Sep 20;12(19).
    PMID: 31547011 DOI: 10.3390/ma12193052
    Nanoparticles are defined as ultrafine particles sized between 1 and 100 nanometres in diameter. In recent decades, there has been wide scientific research on the various uses of nanoparticles in construction, electronics, manufacturing, cosmetics, and medicine. The advantages of using nanoparticles in construction are immense, promising extraordinary physical and chemical properties for modified construction materials. Among the many different types of nanoparticles, titanium dioxide, carbon nanotubes, silica, copper, clay, and aluminium oxide are the most widely used nanoparticles in the construction sector. The promise of nanoparticles as observed in construction is reflected in other adoptive industries, driving the growth in demand and production quantity at an exorbitant rate. The objective of this study was to analyse the use of nanoparticles within the construction industry to exemplify the benefits of nanoparticle applications and to address the short-term and long-term effects of nanoparticles on the environment and human health within the microcosm of industry so that the findings may be generalised. The benefits of nanoparticle utilisation are demonstrated through specific applications in common materials, particularly in normal concrete, asphalt concrete, bricks, timber, and steel. In addition, the paper addresses the potential benefits and safety barriers for using nanomaterials, with consideration given to key areas of knowledge associated with exposure to nanoparticles that may have implications for health and environmental safety. The field of nanotechnology is considered rather young compared to established industries, thus limiting the time for research and risk analysis. Nevertheless, it is pertinent that research and regulation precede the widespread adoption of potentially harmful particles to mitigate undue risk.
  12. Tamadon A, Pons DJ, Clucas D, Sued K
    Materials (Basel), 2019 Oct 01;12(19).
    PMID: 31581446 DOI: 10.3390/ma12193215
    One of the difficulties with bobbin friction stir welding (BFSW) has been the visualisation of microstructure, particularly grain boundaries, and this is especially problematic for materials with fine grain structure, such as AA6082-T6 aluminium as here. Welds of this material were examined using optical microscopy (OM) and electron backscatter diffraction (EBSD). Results show that the grain structures that form depend on a complex set of factors. The motion of the pin and shoulder features transports material around the weld, which induces shear. The shear deformation around the pin is non-uniform with a thermal and strain gradient across the weld, and hence the dynamic recrystallisation (DRX) processes are also variable, giving a range of observed polycrystalline and grain boundary structures. Partial DRX was observed at both hourglass boundaries, and full DRX at mid-stirring zone. The grain boundary mapping showed the formation of low-angle grain boundaries (LAGBs) at regions of high shear as a consequence of thermomechanical nature of the process.
  13. Shaifudin MS, Ghazali MSM, Kamaruzzaman WMIWM, Wan Abdullah WR, Kassim S, Ismail NQA, et al.
    Materials (Basel), 2021 Feb 03;14(4).
    PMID: 33546094 DOI: 10.3390/ma14040702
    This paper investigated the effects of Pr6O11 and Co3O4 on the electrical properties of ZnO-BaTiO3 varistor ceramics. The Pr6O11 doping has a notable influence on the characteristics of the nonlinear coefficient, varistor voltage, and leakage current where the values varied from 2.29 to 2.69, 12.36 to 68.36 V/mm and 599.33 to 548.16 µA/cm2, respectively. The nonlinear varistor coefficient of 5.50 to 7.15 and the varistor voltage of 7.38 to 8.10 V/mm was also influenced by the use of Co3O4 as a dopant. When the amount of Co3O4 was above 0.5 wt.%, the leakage current increased from 202.41 to 302.71 μA/cm2. The varistor ceramics with 1.5 wt.% Pr6O11 shows good nonlinear electrical performance at higher breakdown voltage and reduced the leakage current of the ceramic materials. Besides, the varistor sample that was doped with 0.5 wt.% Co3O4 was able to enhance the nonlinear electrical properties at low breakdown voltage with a smaller value of leakage current.
  14. Ahmad W, Jabbar B, Ahmad I, Mohamed Jan B, Stylianakis MM, Kenanakis G, et al.
    Materials (Basel), 2021 Feb 22;14(4).
    PMID: 33671689 DOI: 10.3390/ma14041037
    Polymer composites are favorite materials for sensing applications due to their low cost and easy fabrication. In the current study, composite nanofibers consisting of polyethylene oxide (PEO), oxidized multi-walled carbon nanotubes (MWCNT) and copper oxide (CuO) nanoparticles with 1% and 3% of fillers (i.e., PEO-CuO-MWCNT: 1%, and PEO-CuO-MWCNT: 3%) were successfully developed through electrospinning for humidity sensing applications. The composite nanofibers were characterized by FTIR, XRD, SEM and EDX analysis. Firstly, they were loaded on an interdigitated electrode (IDE), and then the humidity sensing efficiency was investigated through a digital LCR meter (E4980) at different frequencies (100 Hz-1 MHz), as well as the percentage of relative humidity (RH). The results indicated that the composite nanofibers containing 1% and 3% MWCNT, combined with CuO in PEO polymer matrix, showed potent resistive and capacitive response along with high sensitivity to humidity at room temperature in an RH range of 30-90%. More specifically, the PEO-CuO-MWCNT: 1% nanocomposite displayed a resistive rapid response time within 3 s and a long recovery time of 22 s, while the PEO-CuO-MWCNT: 3% one exhibited 20 s and 11 s between the same RH range, respectively.
  15. Wan Jusoh WN, Matori KA, Mohd Zaid MH, Zainuddin N, Ahmad Khiri MZ, Abdul Rahman NA, et al.
    Materials (Basel), 2021 Feb 18;14(4).
    PMID: 33670465 DOI: 10.3390/ma14040954
    Glass ionomer cement (GIC) is a well-known restorative material applied in dentistry. The present work aims to study the effect of hydroxyapatite (HA) addition into GIC based on physical, mechanical and structural properties. The utilization of waste materials namely clam shell (CS) and soda lime silica (SLS) glass as replacements for the respective CaO and SiO2 sources in the fabrication of alumino-silicate-fluoride (ASF) glass ceramics powder. GIC was formulated based on ASF glass ceramics, polyacrylic acid (PAA) and deionized water, while 1 wt.% of HA powder was added to enhance the properties of the cement samples. The cement samples were subjected to four different ageing times before being analyzed. In this study, the addition of HA caused an increment in density and compressive strength results along with ageing time. Besides, X-ray Diffraction (XRD) revealed the formation of fluorohydroxyapatite (FHA) phase in HA-added GIC samples and it was confirmed by Fourier Transform Infrared (FTIR) analysis which detected OH‒F vibration mode. In addition, needle-like and agglomeration of spherical shapes owned by apatite crystals were observed from Field Emission Scanning Electron Microscopy (FESEM). Based on Energy Dispersive X-ray (EDX) analysis, the detection of chemical elements in the cement samples were originated from chemical compounds used in the preparation of glass ceramics powder and also the polyacid utilized in initiating the reaction of GIC.
  16. Eliaslankaran Z, Daud NNN, Yusoff ZM, Rostami V
    Materials (Basel), 2021 Feb 28;14(5).
    PMID: 33670914 DOI: 10.3390/ma14051140
    Coastal accretion and erosion are unavoidable processes as some coastal sediments undergo modification and stabilization. This study was conducted to investigate the geotechnical behavior of soil collected from Bagan Lalang coast and treated with lime, cement, and rice husk ash (RHA) to design a low-cost alternative mixture with environmentally friendly characteristics. Laboratory tests were carried out to analyze the physical properties of the soil (Atterberg limits and compaction properties), together with mechanical characteristics (direct shear and unconfined compressive strength (UCS) tests) to determine the effect of different ratios of stabilizer/pozzolan on the coastal soil and the optimum conditions for each mixture. Part of the purpose of this study was also to analyze the shear behavior of the coastal soil and monitor the maximum axial compressive stress that the treated specimens can bear under zero confining pressure. Compared to the natural soil, the soil treated with lime and rice husk ash (LRHA) in the ratio of 1:2 (8% lime content) showed a tremendous increase in shear stress under the normal stress of 200 kPa. The strength parameters such as the cohesion (c) and internal friction angle (ϕ) values showed a significant increase. Cohesion values increased considerably in samples cured for 90 days compared to specimens cured for 7 days with additional LRHA in the ratio of 1:2 (28%).
  17. Ahmad R, Abdullah MMAB, Ibrahim WMW, Hussin K, Ahmad Zaidi FH, Chaiprapa J, et al.
    Materials (Basel), 2021 Feb 25;14(5).
    PMID: 33669116 DOI: 10.3390/ma14051077
    The primary motivation of developing ceramic materials using geopolymer method is to minimize the reliance on high sintering temperatures. The ultra-high molecular weight polyethylene (UHMWPE) was added as binder and reinforces the nepheline ceramics based geopolymer. The samples were sintered at 900 °C, 1000 °C, 1100 °C, and 1200 °C to elucidate the influence of sintering on the physical and microstructural properties. The results indicated that a maximum flexural strength of 92 MPa is attainable once the samples are used to be sintered at 1200 °C. It was also determined that the density, porosity, volumetric shrinkage, and water absorption of the samples also affected by the sintering due to the change of microstructure and crystallinity. The IR spectra reveal that the band at around 1400 cm-1 becomes weak, indicating that sodium carbonate decomposed and began to react with the silica and alumina released from gels to form nepheline phases. The sintering process influence in the development of the final microstructure thus improving the properties of the ceramic materials.
  18. Soomro IA, Pedapati SR, Awang M
    Materials (Basel), 2021 Feb 08;14(4).
    PMID: 33567606 DOI: 10.3390/ma14040802
    Resistance spot welding (RSW) of dual phase (DP) steels is a challenging task due to formation of brittle martensitic structure in the fusion zone (FZ), resulting in a low energy capacity of the joint during high-rate loading. In the present study, in situ postweld heat treatment (PWHT) was carried out by employing a double pulse welding scheme with the aim of improving the mechanical performance of DP590 steel resistance spot weld joint. Taguchi method was used to optimize in situ PWHT parameters to obtain maximum peak load and failure energy. Experiments were designed based on orthogonal array (OA) L16. Mechanical performance was evaluated in terms of peak load and failure energy after performing low dynamic tensile shear (TS) test. Microstructural characterization was carried out using a scanning electron microscope (SEM). The results show that improvements of 17 and 86% in peak load and failure energy, respectively, were achieved in double-pulse welding (DPW) at optimum conditions compared to traditional single-pulse welding (SPW). The improvement in mechanical performance resulted from (i) enlargement of the FZ and (ii) improved weld toughness due to tempering of martensite in the FZ and subcritical heat affected zone (SCHAZ). These factors are influenced by heat input, which in turn depends upon in situ PWHT parameters.
  19. Hashim AN, Salleh MAAM, Sandu AV, Ramli MM, Yee KC, Mohd Mokhtar NZ, et al.
    Materials (Basel), 2021 Feb 05;14(4).
    PMID: 33562471 DOI: 10.3390/ma14040738
    The evolution of internal compressive stress from the intermetallic compound (IMC) Cu6Sn5 growth is commonly acknowledged as the key inducement initiating the nucleation and growth of tin (Sn) whisker. This study investigates the effect of Sn-0.7Cu-0.05Ni on the nucleation and growth of Sn whisker under continuous mechanical stress induced. The Sn-0.7Cu-0.05Ni solder joint has a noticeable effect of suppression by diminishing the susceptibility of nucleation and growth of Sn whisker. By using a synchrotron micro X-ray fluorescence (µ-XRF) spectroscopy, it was found that a small amount of Ni alters the microstructure of Cu6Sn5 to form a (Cu,Ni)6Sn5 intermetallic layer. The morphology structure of the (Cu,Ni)6Sn5 interfacial intermetallic layer and Sn whisker growth were investigated by scanning electron microscope (SEM) in secondary and backscattered electron imaging mode, which showed that there is a strong correlation between the formation of Sn whisker and the composition of solder alloy. The thickness of the (Cu,Ni)6Sn5 IMC interfacial layer was relatively thinner and more refined, with a continuous fine scallop-shaped IMC interfacial layer, and consequently enhanced a greater incubation period for the nucleation and growth of the Sn whisker. These verification outcomes proposes a scientifically foundation to mitigate Sn whisker growth in lead-free solder joint.
  20. Zaimi NSM, Salleh MAAM, Sandu AV, Abdullah MMAB, Saud N, Rahim SZA, et al.
    Materials (Basel), 2021 Feb 07;14(4).
    PMID: 33562200 DOI: 10.3390/ma14040776
    This paper elucidates the effect of isothermal ageing at temperature of 85 °C, 125 °C and 150 °C for 100, 500 and 1000 h on Sn-3.0Ag-0.5Cu (SAC305) lead-free solder with the addition of 1 wt% kaolin geopolymer ceramic (KGC) reinforcement particles. SAC305-KGC composite solders were fabricated through powder metallurgy using a hybrid microwave sintering method and reflowed on copper substrate printed circuit board with an organic solderability preservative surface finish. The results revealed that, the addition of KGC was beneficial in improving the total thickness of interfacial intermetallic compound (IMC) layer. At higher isothermal ageing of 150 °C and 1000 h, the IMC layer in SAC305-KGC composite solder was towards a planar-type morphology. Moreover, the growth of total interfacial IMC layer and Cu3Sn layer during isothermal ageing was found to be controlled by bulk diffusion and grain-boundary process, respectively. The activation energy possessed by SAC305-KGC composite solder for total interfacial IMC layer and Cu3Sn IMC was 74 kJ/mol and 104 kJ/mol, respectively. Based on a lap shear test, the shear strength of SAC305-KGC composite solder exhibited higher shear strength than non-reinforced SAC305 solder. Meanwhile, the solder joints failure mode after shear testing was a combination of brittle and ductile modes at higher ageing temperature and time for SAC305-KGC composite solder.
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