Displaying publications 21 - 40 of 705 in total

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  1. Azmi NA, Idris A, Yusof NSM
    Ultrason Sonochem, 2018 Oct;47:99-107.
    PMID: 29908610 DOI: 10.1016/j.ultsonch.2018.04.016
    Feather keratin is a biomass generated in excess from various livestock industries. With appropriate processing, it holds potential as a green source for degradable biopolymer that could potentially replace current fossil fuel based materials. Several processing methods have been developed, but the use of ultrasonication has not been explored. In this study, we focus on (i) comparing and optimizing the dissolution process of turkey feather keratin through sonication and conventional processes, and (ii) generating a biodegradable polymer material, as a value added product, from the dissolved keratin that could be used in packaging and other applications. Sonication of feather keratin in pure ionic liquids (ILs) and a mixture containing ILs and different co-solvents was conducted under different applied acoustic power levels. It was found that ultrasonic irradiation significantly improved the rate of dissolution of feather keratin as compared to the conventional method, from about 2 h to less than 20 min. The amount of ILs needed was also reduced by introducing a suitable co-solvent. The keratin was then regenerated, analyzed and characterized using various methods. This material holds the potential to be reused in various appliances.
    Matched MeSH terms: Biomass
  2. Rawindran H, Arif Bin Hut N, Vrasna DK, Goh PS, Lim JW, Liew CS, et al.
    Chemosphere, 2024 Jan;346:140591.
    PMID: 37918531 DOI: 10.1016/j.chemosphere.2023.140591
    Current study had made a significant progress in microalgal wastewater treatment through the implementation of an economically viable polyethylene terephthalate (PET) membrane derived from plastic bottle waste. The membrane exhibited an exceptional pure water flux of 156.5 ± 0.25 L/m2h and a wastewater flux of 15.37 ± 0.02 L/m2h. Moreover, the membrane demonstrated remarkable efficiency in selectively removing a wide range of residual parameters, achieving rejection rates up to 99%. The reutilization of treated wastewater to grow microalgae had resulted in a marginal decrease in microalgal density, from 10.01 ± 0.48 to 9.26 ± 0.66 g/g. However, this decline was overshadowed by a notable enhancement in lipid production with level rising from 181.35 ± 0.42 to 225.01 ± 0.11 mg/g. These findings signified the membrane's capacity to preserve nutrients availability within the wastewater; thus, positively influencing the lipid synthesis and accumulation within microalgal cells. Moreover, the membrane's comprehensive analysis of cross-sectional and surface topographies revealed the presence of macropores with a highly interconnected framework, significantly amplifying the available surface area for fluid flow. This exceptional structural attribute had substantially contributed to the membrane's efficacy by facilitating superior filtration and separation process. Additionally, the identified functional groups within the membrane aligned consistently with those commonly found in PET polymer, confirming the membrane's compatibility and efficacy in microalgal wastewater treatment.
    Matched MeSH terms: Biomass
  3. Chin DWK, Lim S, Pang YL, Lim CH, Lee KM
    Bioresour Technol, 2019 Nov;292:121967.
    PMID: 31450064 DOI: 10.1016/j.biortech.2019.121967
    Ethylene glycol in the presence of sodium hydroxide was utilised as pretreatment for effective delignification and reduced the recalcitrance of lignocellulosic biomass which ramified the exposure of cellulose. Two-staged acid hydrolysis was also investigated which demonstrated its synergistic efficiency by minimising the deficiency of single stage acid hydrolysis. The operating parameters including acid concentration, temperature, residence time and cellulose loading for two-staged acid hydrolysis were studied by using ethylene glycol delignified degraded oil palm empty fruit bunch (DEFB) to recover the sugar based substrates for potential biofuels and other bio-chemicals production. In this study, stage I 45 wt% acid at 65 °C for 30 min coupled with high cellulose loading 21.25 w/v% and 12 wt% acid at 100 °C for 120 min was able to release a total of 89.8% optimum sugar yield with minimal formation of degradation products including 0.058 g/L furfural, 0.0251 g/L hydroxymethylfurfural and 0.200 g/L phenolic compounds.
    Matched MeSH terms: Biomass
  4. Manikan V, Nazir Y, Hamid AA
    Heliyon, 2021 Jan;7(1):e06085.
    PMID: 33553753 DOI: 10.1016/j.heliyon.2021.e06085
    Thraustochytrids are getting increasingly popular due to their high potential role as alternative producers of the high-valued ω-3 polyunsaturated fatty acids (PUFA), docosahexaenoic acid (DHA). While most thraustochytrids prefer glucose as the major carbon source, few strains have been reported to prefer fructose. One such strain is Aurantiochytrium sp. SW1. In this study, the effect of fructose on DHA accumulation by SW1 was investigated using a two-level full factorial design. Besides, biomass, lipid and DHA accumulation profiles of SW1 cultivated in fructose and glucose media were compared. Results revealed that fructose has a very significant positive effect on the volumetric DHA content. Meanwhile, its involvement in affecting DHA biosynthetic capacity, though significant, is not very profound. It was also found that when cultivated in fructose medium, SW1 had a less steep log phase compared to that of glucose medium. However, after 48h of cultivation, biomass and lipid accumulation in fructose medium outweighed the other. Volumetric DHA content in fructose medium at 96h was 11% higher than that of glucose medium. Overall, fructose was found to be a more suitable substrate for biomass, lipid and DHA accumulation in SW1 compared to the conventional source, glucose.
    Matched MeSH terms: Biomass
  5. Rahman MM, Islam AM, Azirun SM, Boyce AN
    ScientificWorldJournal, 2014;2014:490841.
    PMID: 24971378 DOI: 10.1155/2014/490841
    Bush bean, long bean, mung bean, and winged bean plants were grown with N fertilizer at rates of 0, 2, 4, and 6 g N m(-2) preceding rice planting. Concurrently, rice was grown with N fertilizer at rates of 0, 4, 8, and 12 g N m(-2). No chemical fertilizer was used in the 2nd year of crop to estimate the nitrogen agronomic efficiency (NAE), nitrogen recovery efficiency (NRE), N uptake, and rice yield when legume crops were grown in rotation with rice. Rice after winged bean grown with N at the rate of 4 g N m(-2) achieved significantly higher NRE, NAE, and N uptake in both years. Rice after winged bean grown without N fertilizer produced 13-23% higher grain yield than rice after fallow rotation with 8 g N m(-2). The results revealed that rice after winged bean without fertilizer and rice after long bean with N fertilizer at the rate of 4 g N m(-2) can produce rice yield equivalent to that of rice after fallow with N fertilizer at rates of 8 g N m(-2). The NAE, NRE, and harvest index values for rice after winged bean or other legume crop rotation indicated a positive response for rice production without deteriorating soil fertility.
    Matched MeSH terms: Biomass
  6. Mills MB, Malhi Y, Ewers RM, Kho LK, Teh YA, Both S, et al.
    Proc Natl Acad Sci U S A, 2023 Jan 17;120(3):e2214462120.
    PMID: 36623189 DOI: 10.1073/pnas.2214462120
    Logged and structurally degraded tropical forests are fast becoming one of the most prevalent land-use types throughout the tropics and are routinely assumed to be a net carbon sink because they experience rapid rates of tree regrowth. Yet this assumption is based on forest biomass inventories that record carbon stock recovery but fail to account for the simultaneous losses of carbon from soil and necromass. Here, we used forest plots and an eddy covariance tower to quantify and partition net ecosystem CO2 exchange in Malaysian Borneo, a region that is a hot spot for deforestation and forest degradation. Our data represent the complete carbon budget for tropical forests measured throughout a logging event and subsequent recovery and found that they constitute a substantial and persistent net carbon source. Consistent with existing literature, our study showed a significantly greater woody biomass gain across moderately and heavily logged forests compared with unlogged forests, but this was counteracted by much larger carbon losses from soil organic matter and deadwood in logged forests. We estimate an average carbon source of 1.75 ± 0.94 Mg C ha-1 yr-1 within moderately logged plots and 5.23 ± 1.23 Mg C ha-1 yr-1 in unsustainably logged and severely degraded plots, with emissions continuing at these rates for at least one-decade post-logging. Our data directly contradict the default assumption that recovering logged and degraded tropical forests are net carbon sinks, implying the amount of carbon being sequestered across the world's tropical forests may be considerably lower than currently estimated.
    Matched MeSH terms: Biomass
  7. Marcharchand S, Ting ASY
    J Environ Manage, 2017 Dec 01;203(Pt 1):542-549.
    PMID: 28693968 DOI: 10.1016/j.jenvman.2017.06.068
    Trichoderma asperellum (Ta) was first cultured in synthetic medium (Potato Dextrose Broth, PDB) of various concentrations (100, 75, 50, 25%). The biomass was harvested and inoculated into dye solutions (crystal violet, CV; methyl violet, MV; malachite green, MG; and cotton blue, CB). Reduced concentrations (20, 50, 75%) affected growth rate but their decolourization efficacies remained unaffected. This was attributed to similar numbers and types of functional groups (hydroxyl, amine, ester-lipid, alkane groups) found on the surface of fungal biomass, as revealed by the Fourier transformed infrared spectroscopy (FTIR) analysis. Their production of NADH-reductase for degradation, and their biosorption activities were also unaffected. In general, Ta cultured in reduced concentrations (20, 50, 75%) retained the ability to perform biosorption and biodegradation, similar to cultures from control (100% PDB). This suggested that reduced nutrient levels (as a cost-feasible strategy) could be used to cultivate biomass of Ta for dye removal activities.
    Matched MeSH terms: Biomass
  8. Azmi SZ, Latif MT, Ismail AS, Juneng L, Jemain AA
    Air Qual Atmos Health, 2010 Mar;3(1):53-64.
    PMID: 20376168
    Over the last decades, the development of the Klang Valley (Malaysia), as an urban commercial and industrial area, has elevated the risk of atmospheric pollutions. There are several significant sources of air pollutants which vary depending on the background of the location they originate from. The aim of this study is to determine the trend and status of air quality and their correlation with the meteorological factors at different air quality monitoring stations in the Klang Valley. The data of five major air pollutants (PM(10), CO, SO(2), O(3), NO(2)) were recorded at the Alam Sekitar Sdn Bhd (ASMA) monitoring stations in the Klang Valley, namely Petaling Jaya (S1), Shah Alam (S2) and Gombak (S3). The data from these three stations were compared with the data recorded at Jerantut, Pahang (B), a background station established by the Malaysian Department of Environment. Results show that the concentrations of CO, NO(2) and SO(2) are higher at Petaling Jaya (S1) which is due to influence of heavy traffic. The concentrations of PM(10) and O(3,) however, are predominantly related to regional tropical factors, such as the influence of biomass burning and of ultra violet radiation from sunlight. They can, though, also be influenced by local sources. There are relatively stronger inter-pollutant correlations at the stations of Gombak and Shah Alam, and the results also suggest that heavy traffic flow induces high concentrations of PM(10), CO, NO(2) and SO(2) at the three sampling stations. Additionally, meteorological factors, particularly the ambient temperature and wind speed, may influence the concentration of PM(10) in the atmosphere.
    Matched MeSH terms: Biomass
  9. Loo YM, Lim PE, Seng CE
    Environ Technol, 2010 Apr 14;31(5):479-87.
    PMID: 20480823 DOI: 10.1080/09593330903514482
    The objective of this research was to evaluate the treatment ofp-nitrophenol (PNP) as a sole organic carbon source using a sequencing batch reactor (SBR) with the addition of adsorbent. Two types of adsorbents, namely powdered activated carbon (PAC) and pyrolysed rice husk (PRH) were used in this study. Two identical SBRs, each with a working volume of 10 L, were operated with fill, react, settle, draw and idle periods in the ratio of 2:8:1:0.75:0.25 for a cycle time of 12 h. The results showed that, without the addition of adsorbent, increasing the influent PNP concentration to 200 mg/L resulted in the deterioration of chemical oxygen demand (COD) removal efficiency and PNP removal efficiency in the SBRs. Improvement in the performance of the SBR was observed with the addition of PAC. When the dosage of 1.0 g PAC/cycle was applied, COD removal of 95% and almost complete removal of PNP were achieved at the influent PNP concentration of 300 mg/L. The kinetic study showed that the rates of COD and PNP removal can be described by the first-order kinetics. The enhancement of performance in the PAC-supplemented SBR was postulated to be due to the initial adsorption of PNP by the freshly added and the bioregenerated PAC, thus reducing the inhibition on the microorganisms. The PRH was found to be ineffective because of its relatively low adsorption capacity for PNP, compared with that of PAC.
    Matched MeSH terms: Biomass
  10. Lim JX, Vadivelu VM
    J Environ Manage, 2014 Dec 15;146:217-225.
    PMID: 25173730 DOI: 10.1016/j.jenvman.2014.07.023
    A sequencing batch reactor (SBR) with a working volume of 8 L and an exchange ratio of 25% was used to enrich biomass for the treatment of the anaerobically treated low pH palm oil mill effluent (POME). The influent concentration was stepwise increased from 5000 ± 500 mg COD/L to 11,500 ± 500 mg COD/L. The performance of the reactor was monitored at different organic loading rates (OLRs). It was found that approximately 90% of the COD content of the POME wastewater was successfully removed regardless of the OLR applied to the SBR. Cycle studies of the SBR show that the oxygen uptake by the biomass while there is no COD reduction may be due to the oxidation of the storage product by the biomass. Further, the growth kinetic parameters of the biomass were determined in batch experiments using respirometer. The maximum specific growth rate (μmax) was estimated to be 1.143 day(-1) while the half saturation constant (Ks) with respect to COD was determined to be 0.429 g COD/L. The decay coefficient (bD) and biomass yield (Y) were found to be 0.131 day(-1) and 0.272 mg biomass/mg COD consumed, respectively.
    Matched MeSH terms: Biomass*
  11. Chin L, Moran JA, Clarke C
    New Phytol, 2010 Apr;186(2):461-70.
    PMID: 20100203 DOI: 10.1111/j.1469-8137.2009.03166.x
    *Three Bornean pitcher plant species, Nepenthes lowii, N. rajah and N. macrophylla, produce modified pitchers that 'capture' tree shrew faeces for nutritional benefit. Tree shrews (Tupaia montana) feed on exudates produced by glands on the inner surfaces of the pitcher lids and defecate into the pitchers. *Here, we tested the hypothesis that pitcher geometry in these species is related to tree shrew body size by comparing the pitcher characteristics with those of five other 'typical' (arthropod-trapping) Nepenthes species. *We found that only pitchers with large orifices and lids that are concave, elongated and oriented approximately at right angles to the orifice capture faeces. The distance from the tree shrews' food source (that is, the lid nectar glands) to the front of the pitcher orifice precisely matches the head plus body length of T. montana in the faeces-trapping species, and is a function of orifice size and the angle of lid reflexion. *Substantial changes to nutrient acquisition strategies in carnivorous plants may occur through simple modifications to trap geometry. This extraordinary plant-animal interaction adds to a growing body of evidence that Nepenthes represents a candidate model for adaptive radiation with regard to nitrogen sequestration strategies.
    Matched MeSH terms: Biomass
  12. Loow YL, Wu TY
    J Environ Manage, 2018 Jun 15;216:192-203.
    PMID: 28545947 DOI: 10.1016/j.jenvman.2017.04.084
    Among the chemical pretreatments available for pretreating biomass, the inorganic salt is considered to be a relatively new but simple reagent that offers comparable pentose (C5) sugar recoveries as the conventional dilute acid hydrolysis. This study investigated the effects of different concentrations (1.5-6.0% (v/v)) of H2O2 or Na2S2O8 in facilitating CuSO4·5H2O pretreatment for improving pentose sugar recovery from oil palm fronds. The best result was observed when 0.2 mol/L of CuSO4·5H2O was integrated with 4.5% (v/v) of Na2S2O8 to recover 8.2 and 0.9 g/L of monomeric xylose and arabinose, respectively in the liquid fraction. On the other hand, an addition of 1.5% (v/v) of H2O2 yielded approximately 74% lesser total pentose sugars as compared to using 4.5% (v/v) Na2S2O8. By using CuSO4·5H2O alone (control), only 0.8 and 1.0 g/L xylose and arabinose, respectively could be achieved. The results mirrored the importance of using chemical additives together with the inorganic salt pretreatment of oil palm fronds. Thus, an addition of 4.5% (v/v) of Na2S2O8 during CuSO4·5H2O pretreatment of oil palm fronds at 120 °C and 30 min was able to attain a total pentose sugar yield up to ∼40%.
    Matched MeSH terms: Biomass
  13. Wan Afifudeen CL, Aziz A, Wong LL, Takahashi K, Toda T, Abd Wahid ME, et al.
    Phytochemistry, 2021 Dec;192:112936.
    PMID: 34509143 DOI: 10.1016/j.phytochem.2021.112936
    The non-model microalga Messastrum gracile SE-MC4 is a potential species for biodiesel production. However, low biomass productivity hinders it from passing the life cycle assessment for biodiesel production. Therefore, the current study was aimed at uncovering the differences in the transcriptome profiles of the microalgae at early exponential and early stationary growth phases and dissecting the roles of specific differential expressed genes (DEGs) involved in cell division during M. gracile cultivation. The transcriptome analysis revealed that the photosynthetic integral membrane protein genes such as photosynthetic antenna protein were severely down-regulated during the stationary growth phase. In addition, the signaling pathways involving transcription, glyoxylate metabolism and carbon metabolism were also down-regulated during stationary growth phase. Current findings suggested that the coordination between photosynthetic integral membrane protein genes, signaling through transcription and carbon metabolism classified as prominent strategies during exponential growth stage. These findings can be applied in genetic improvement of M. gracile for biodiesel application.
    Matched MeSH terms: Biomass
  14. Teo HL, Wahab RA
    Int J Biol Macromol, 2020 Oct 15;161:1414-1430.
    PMID: 32791266 DOI: 10.1016/j.ijbiomac.2020.08.076
    There is an array of methodologies to prepare nanocellulose (NC) and its fibrillated form (CNF) with enhanced physicochemical characteristics. However, acids, bases or organosolv treatments on biomass are far from green, and seriously threaten the environment. Current approach to produce NC/CNF from biomass should be revised and embrace the concept of sustainability and green chemistry. Although hydrothermal process, high-pressure homogenization, ball milling technique, deep eutectic solvent treatment, enzymatic hydrolysis etc., are the current techniques for producing NC, the route designs remain imperfect. Herein, this review highlights the latest methodologies in the pre-processing and isolating of NC/CNF from lignocellulose biomass, by largely focusing on related papers published in the past two years till date. This article also explores the latest advancements in environmentally friendly NC extraction techniques that cooperatively use ball milling and enzymatic hydrolytic routes as an eco-efficient way to produce NC/CNF, alongside the potential applications of the nano-sized celluloses.
    Matched MeSH terms: Biomass*
  15. Alsaleh M, Zubair AO, Abdul-Rahim AS
    Environ Sci Pollut Res Int, 2021 Jun;28(23):29831-29844.
    PMID: 33575938 DOI: 10.1007/s11356-021-12769-1
    The objective of this research is to examine the impact of bioenergy usage on health outcomes, especially adult mortality in both developed and underdeveloped countries in the European Union, where the use of solid biomass is growing to generate bioheat, biocool, and biopower. Over the period studied, findings indicate that increased consumption of bioenergy has increased mortality rates in developed and underdeveloped EU28 countries during the period 1990-2018. This feedback proposes, using generalized least squares (GLS), that the resulting death rate from burning biomass-related cases is higher in the EU15 developed countries compared to EU13 underdeveloped countries. There is a need to lower burning biomass in the entire EU15 countries, more importantly its developed region, by critically evaluating the bioenergy production life cycle before it is available for final consumption. However, there is a continuous need to intensify stringent production procedures in the bioenergy industry in EU15 countries, more importantly the imported biomass crops for energy use. There is also a need to be consistent with the campaign on the usage of bioenergy products, i.e., bioheat, bioelectricity, and biofuels, particularly in the rural areas where the use of wood fuels for cooking, heating, and cooling are significant in EU15 developed countries in comparison to EU13 developing countries.
    Matched MeSH terms: Biomass
  16. Uemura Y, Sellappah V, Trinh TH, Hassan S, Tanoue KI
    Bioresour Technol, 2017 Nov;243:107-117.
    PMID: 28810504 DOI: 10.1016/j.biortech.2017.06.057
    Torrefaction of oil palm empty fruit bunches (EFB) under combustion gas atmosphere was conducted in a batch reactor at 473, 523 and 573K in order to investigate the effect of real combustion gas on torrefaction behavior. The solid mass yield of torrefaction in combustion gas was smaller than that of torrefaction in nitrogen. This may be attributed to the decomposition enhancement effect by oxygen and carbon dioxide in combustion gas. Under combustion gas atmosphere, the solid yield for torrefaction of EFB became smaller as the temperature increased. The representative products of combustion gas torrefaction were carbon dioxide and carbon monoxide (gas phase) and water, phenol and acetic acid (liquid phase). By comparing torrefaction in combustion gas with torrefaction in nitrogen gas, it was found that combustion gas can be utilized as torrefaction gas to save energy and inert gas.
    Matched MeSH terms: Biomass*
  17. Iskandar NL, Zainudin NA, Tan SG
    J Environ Sci (China), 2011;23(5):824-30.
    PMID: 21790056
    Filamentous fungi are able to accumulate significant amount of metals from their environment. The potential of fungal biomass as agents for biosorption of heavy metals from contaminated sediments is currently receiving attention. In the present study, a total of 41 isolates of filamentous fungi obtained from the sediment of the Langat River, Selangor, Malaysia were screened for their tolerance and uptake capability of copper (Cu) and lead (Pb). The isolates were identified as Aspergillus niger, A. fumigatus, Trichoderma asperellum, Penicillium simplicissimum and P. janthinellum. A. niger and P. simplicissimum, were able to survive at 1000 mg/L of Cu(II) concentration on Potato Dextrose Agar (PDA) while for Pb, only A. niger survived at 5000 mg/L concentration. The results showed that A. niger, P. simplicissimum and T. asperellum have a better uptake capacity for Pb compared to Cu and the findings indicated promising biosorption of Cu and Pb by these filamentous fungi from aqueous solution. The present study was also determined the maximum removal of Cu(II) and Pb(II) that was performed by A. niger. The metal removal which occurred at Cu(II) 200 mg/L was (20.910 +/- 0.581) mg/g and at 250 mg/L of Pb(II) was (54.046 +/- 0.328) mg/g.
    Matched MeSH terms: Biomass
  18. Hena S, Fatihah N, Tabassum S, Ismail N
    Water Res, 2015 Sep 1;80:346-56.
    PMID: 26043271 DOI: 10.1016/j.watres.2015.05.001
    Reserve lipids of microalgae are promising for biodiesel production. However, economically feasible and sustainable energy production from microalgae requires optimization of cultivation conditions for both biomass yield and lipid production of microalgae. Biomass yield and lipid production in microalgae are a contradictory problem because required conditions for both targets are different. Simultaneously, the mass cultivation of microalgae for biofuel production also depends extremely on the performance of the microalgae strains used. In this study a green unicellular microalgae Chlorella sorokiniana (DS6) isolated from the holding tanks of farm wastewater treatment plant using multi-step screening and acclimation procedures was found high-lipid producing facultative heterotrophic microalgae strain capable of growing on dairy farm effluent (DFE) for biodiesel feedstock and wastewater treatment. Morphological features and the phylogenetic analysis for the 18S rRNA identified the isolated strains. A novel three stage cultivation process of facultative strain of C. sorokiniana was examined for lipid production.
    Matched MeSH terms: Biomass
  19. Razak NN, Annuar MS
    Appl Biochem Biotechnol, 2014 Mar;172(6):2932-44.
    PMID: 24464534 DOI: 10.1007/s12010-014-0731-7
    Free laccase and fungal biomass from white-rot fungi were compared in the thermokinetics study of the laccase-catalyzed decolorization of an azo dye, i.e., Trypan Blue. The decolorization in both systems followed a first-order kinetics. The apparent first-order rate constant, k1', value increases with temperature. Apparent activation energy of decolorization was similar for both systems at ∼ 22 kJ mol(-1), while energy for laccase inactivation was 18 kJ mol(-1). Although both systems were endothermic, fungal biomass showed higher enthalpy, entropy, and Gibbs free energy changes for the decolorization compared to free laccase. On the other hand, free laccase showed reaction spontaneity over a wider range of temperature (ΔT = 40 K) as opposed to fungal biomass (ΔT = 15 K). Comparison of entropy change (ΔS) values indicated metabolism of the dye by the biomass.
    Matched MeSH terms: Biomass
  20. Loy ACM, Gan DKW, Yusup S, Chin BLF, Lam MK, Shahbaz M, et al.
    Bioresour Technol, 2018 Aug;261:213-222.
    PMID: 29665455 DOI: 10.1016/j.biortech.2018.04.020
    The thermal degradation behaviour and kinetic parameter of non-catalytic and catalytic pyrolysis of rice husk (RH) using rice hull ash (RHA) as catalyst were investigated using thermogravimetric analysis at four different heating rates of 10, 20, 50 and 100 K/min. Four different iso conversional kinetic models such as Kissinger, Friedman, Kissinger-Akahira-Sunose (KAS) and Ozawa-Flynn-Wall (OFW) were applied in this study to calculate the activation energy (EA) and pre-exponential value (A) of the system. The EA of non-catalytic and catalytic pyrolysis was found to be in the range of 152-190 kJ/mol and 146-153 kJ/mol, respectively. The results showed that the catalytic pyrolysis of RH had resulted in a lower EA as compared to non-catalytic pyrolysis of RH and other biomass in literature. Furthermore, the high Gibb's free energy obtained in RH implied that it has the potential to serve as a source of bioenergy production.
    Matched MeSH terms: Biomass
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