Displaying publications 61 - 80 of 84 in total

  1. Tan Sian Hui Abdullah HS, Aqlili Riana Mohd Asseri SN, Khursyiah Wan Mohamad WN, Kan SY, Azmi AA, Yong Julius FS, et al.
    Environ Pollut, 2021 Feb 15;271:116295.
    PMID: 33383429 DOI: 10.1016/j.envpol.2020.116295
    This manuscript describes the reuse of biowaste for the biosynthesis of silver nanoparticles (AgNPs) and their applications. In particular, we hypothesized that the phytochemicals in the onion peels could act as reductant for silver nanoparticles syntheses. AgNO3 solution (1 mmol) was added dropwise to an aqueous solution of onion peel extract in 3:7 ratio. The reaction mixture was subjected to heating at 90 °C for about 30 min. During the synthesis of the AgNPs, the change of the colour of solution was observed. The AgNPs solution was centrifuged to obtain the two layers, which consists of clear solution and solid layers at 12000 rpm for 30 min. The precipitate was filtered and was re-dispersed in deionised water (25 mL). The solution was centrifuged again to obtain the purified AgNPs. Subsequently, this solution was freeze dried for 48 h to afford the powdered AgNPs. In this work, the structure of the AgNPs were synthesized in spherical shape, with an average size of 12.5 nm observed in the Transmission electron microscopy (TEM) analysis. For catalytic application, the synthesized AgNPs could be applied as green catalyst to promote Knoevenagel and Hantzsch reactions. In most cases, the desired products were obtained in satisfactory yields. In addition, the AgNPs were found to be recyclable for the subsequent reactions. After five successive runs, the average isolated yields for both transformations were recorded to be 91% (Knoevenagel condensation) and 94% (Hantzsch reaction), which indicated that the existing AgNPs could apply as green catalyst in the field of organic synthesis. Furthermore, the AgNPs also showed satisfactory result in antioxidant activity. The current results indicate that the AgNPs can act as alternative antioxidant agent and green catalyst in mediating organic transformations.
  2. Arku RE, Brauer M, Ahmed SH, AlHabib KF, Avezum Á, Bo J, et al.
    Environ Pollut, 2020 Jul;262:114197.
    PMID: 32146361 DOI: 10.1016/j.envpol.2020.114197
    Exposure to air pollution has been linked to elevated blood pressure (BP) and hypertension, but most research has focused on short-term (hours, days, or months) exposures at relatively low concentrations. We examined the associations between long-term (3-year average) concentrations of outdoor PM2.5 and household air pollution (HAP) from cooking with solid fuels with BP and hypertension in the Prospective Urban and Rural Epidemiology (PURE) study. Outdoor PM2.5 exposures were estimated at year of enrollment for 137,809 adults aged 35-70 years from 640 urban and rural communities in 21 countries using satellite and ground-based methods. Primary use of solid fuel for cooking was used as an indicator of HAP exposure, with analyses restricted to rural participants (n = 43,313) in 27 study centers in 10 countries. BP was measured following a standardized procedure and associations with air pollution examined with mixed-effect regression models, after adjustment for a comprehensive set of potential confounding factors. Baseline outdoor PM2.5 exposure ranged from 3 to 97 μg/m3 across study communities and was associated with an increased odds ratio (OR) of 1.04 (95% CI: 1.01, 1.07) for hypertension, per 10 μg/m3 increase in concentration. This association demonstrated non-linearity and was strongest for the fourth (PM2.5 > 62 μg/m3) compared to the first (PM2.5 
  3. Aziz FFA, Jalil AA, Hassan NS, Fauzi AA, Azami MS
    Environ Pollut, 2021 Sep 15;285:117490.
    PMID: 34091265 DOI: 10.1016/j.envpol.2021.117490
    The co-existence of heavy metals and organic compounds including Cr(VI) and p-cresol (pC) in water environment becoming a challenge in the treatment processes. Herein, the synchronous photocatalytic reduction of Cr(VI) and oxidation of pC by silver oxide decorated on fibrous silica zirconia (AgO/FSZr) was reported. In this study, the catalysts were successfully developed using microemulsion and electrochemical techniques with various AgO loading (1, 5 and 10 wt%) and presented as 1, 5 and 10-AgO/FSZr. Catalytic activity was tested towards simultaneous photoredox of hexavalent chromium and p-cresol (Cr(VI)/pC) and was ranked as followed: 5-AgO/FSZr (96/78%) > 10-AgO/FSZr (87/61%) > 1-AgO/FSZr (47/24%) > FSZr (34/20%). The highest photocatalytic activity of 5-AgO/FSZr was established due to the strong interaction between FSZr and AgO and the lowest band gap energy, which resulted in less electron-hole recombination and further enhanced the photoredox activity. Cr(VI) ions act as a bridge between the positive charge of catalyst and cationic pC in pH 1 solution which can improve the photocatalytic reduction and oxidation of Cr(VI) and pC, respectively. The scavenger experiments further confirmed that the photogenerated electrons (e-) act as the main species for Cr(VI) to be reduced to Cr(III) while holes (h+) and hydroxyl radicals are domain for photooxidation of pC. The 5-AgO/FSZr was stable after 5 cycles of reaction, suggesting its potential for removal of Cr(VI) and pC simultaneously in the chemical industries.
  4. Sarlaki E, Kermani AM, Kianmehr MH, Asefpour Vakilian K, Hosseinzadeh-Bandbafha H, Ma NL, et al.
    Environ Pollut, 2021 Sep 15;285:117412.
    PMID: 34051566 DOI: 10.1016/j.envpol.2021.117412
    The use of agro-biowaste compost fertilizers in agriculture is beneficial from technical, financial, and environmental perspectives. Nevertheless, the physical, mechanical, and agronomical attributes of agro-biowaste compost fertilizers should be engineered to reduce their storage, handling, and utilization costs and environmental impacts. Pelletizing and drying are promising techniques to achieve these goals. In the present work, the effects of process parameters, including compost particle size/moisture content, pelletizing compression ratio, and drying air temperature/velocity, were investigated on the density, specific crushing energy, and moisture diffusion of agro-biowaste compost pellet. The Taguchi technique was applied to understand the effects of independent parameters on the output responses, while the optimal pellet properties were found using the iterative thresholding method. The soil and plant (sweet basil) response to the optimal biocompost pellet was experimentally evaluated. The farm application of the optimal pellet was also compared with the untreated agro-biowaste compost using the life cycle assessment approach to investigate the potential environmental impact mitigation of the pelletizing and drying processes. Generally, the compost moisture content was the most influential factor on the density and specific crushing energy of the dried pellet, while the moisture diffusion of the wet pellet during the drying process was significantly influenced by the pelletizing compression ratio. The density, specific crushing energy, and moisture diffusion of agro-biowaste compost pellet at the optimal conditions were 1242.49 kg/m3, 0.5054 MJ/t, and 8.2 × 10-8 m2/s, respectively. The optimal biocompost pellet could release 80% of its nitrogen content evenly over 98 days, while this value was 28 days for the chemical urea fertilizer. Besides, the optimal pellet could significantly improve the agronomical attributes of the sweet basil plant compared with the untreated biocompost. The applied strategy could collectively mitigate the weighted environmental impact of farm application of the agro-biowaste compost by more than 63%. This reduction could be attributed to the fact that the pelletizing-drying processes could avoid methane emissions from the untreated agro-biowaste compost during the farm application. Overall, pelletizing-drying of the agro-biowaste compost could be regarded as a promising strategy to improve the environmental and agronomical performance of farm application of organic biofertilizers.
  5. Chen WH, Lo HJ, Yu KL, Ong HC, Sheen HK
    Environ Pollut, 2021 Sep 15;285:117196.
    PMID: 33962308 DOI: 10.1016/j.envpol.2021.117196
    This research aims to study the wet torrefaction (WT) and saccharification of sorghum distillery residue (SDR) towards hydrochar and bioethanol production. The experiments are designed by Box-Behnken design from response surface methodology where the operating conditions include sulfuric acid concentration (0, 0.01, and 0.02 M), amyloglucosidase concentration (36, 51, and 66 IU), and saccharification time (120, 180, and 240 min). Compared to conventional dry torrefaction, the hydrochar yield is between 13.24 and 14.73%, which is much lower than dry torrefaction biochar (yield >50%). The calorific value of the raw SDR is 17.15 MJ/kg, which is significantly enhanced to 22.36-23.37 MJ/kg after WT. When the sulfuric acid concentration increases from 0 to 0.02 M, the glucose concentration in the product increases from 5.59 g/L to 13.05 g/L. The prediction of analysis of variance suggests that the best combination to maximum glucose production is 0.02 M H2SO4, 66 IU enzyme concentration, and 120 min saccharification time, and the glucose concentration is 30.85 g/L. The maximum bioethanol concentration of 19.21 g/L is obtained, which is higher than those from wheat straw (18.1 g/L) and sweet sorghum residue (16.2 g/L). A large amount of SDR is generated in the kaoliang liquor production process, which may cause environmental problems if it is not appropriately treated. This study fulfills SDR valorization for hydrochar and bioenergy to lower environmental pollution and even achieve a circular economy.
  6. Lee KT, Du JT, Chen WH, Ubando AT, Lee KT
    Environ Pollut, 2021 Sep 15;285:117244.
    PMID: 33965857 DOI: 10.1016/j.envpol.2021.117244
    A green approach using hydrogen peroxide (H2O2) to intensify the fuel properties of spent coffee grounds (SCGs) through torrefaction is developed in this study to minimize environmental pollution. Meanwhile, a neural network (NN) is used to minimize bulk density at different combinations of operating conditions to show the accurate and reliable model of NN (R2 = 0.9994). The biochar produced from SCGs torrefied at temperatures of 200-300 °C, duration of 30-60 min, and H2O2 concentrations of 0-100 wt% is examined. The results reveal that the higher heating value (HHV) of biochar increases with rising temperature, duration, or H2O2 concentration, whereas the bulk density has an opposite trend. The HHV, ignition temperature, and bulk density of biochar from torrefaction at 230 °C for 30 min with a 100 wt% H2O2 solution (230-100%-TSCG) are 27.00 MJ∙kg-1, 292 °C, and 120 kg∙m-3, respectively. This HHV accounts for a 29% improvement compared to that of untorrefied SCG. The contact angle (126°), water activity (0.51 aw), and moisture content (7.69%) of the optimized biochar indicate that it has higher resistance against biodegradation, and thereby can be stored longer. Overall, H2O2 is a green treatment additive for SCGs solid fuel. This study has successfully produced biochar with greater HHV and low bulk density at low temperatures. The green additive development can effectively reduce environmental pollutants and upgrade wastes into resources, and achieve "3E", namely, environmental (non-polluting green additives), energy (biofuel), and circular economy (waste upgrade). In addition, the produced biochar has great potential in the fields of bioadsorbents and soil amendments.
  7. Ma NL, Lam SD, Che Lah WA, Ahmad A, Rinklebe J, Sonne C, et al.
    Environ Pollut, 2021 Oct 01;286:117214.
    PMID: 33971466 DOI: 10.1016/j.envpol.2021.117214
    Salinisation of soil is associated with urban pollution, industrial development and rising sea level. Understanding how high salinity is managed at the plant cellular level is vital to increase sustainable farming output. Previous studies focus on plant stress responses under salinity tolerance. Yet, there is limited knowledge about the mechanisms involved from stress state until the recovery state; our research aims to close this gap. By using the most tolerance genotype (SS1-14) and the most susceptible genotype (SS2-18), comparative physiological, metabolome and post-harvest assessments were performed to identify the underlying mechanisms for salinity stress recovery in plant cells. The up-regulation of glutamine, asparagine and malonic acid were found in recovered-tolerant genotype, suggesting a role in the regulation of panicle branching and spikelet formation for survival. Rice could survive up to 150 mM NaCl (∼15 ds/m) with declined of production rate 5-20% ranged from tolerance to susceptible genotype. This show that rice farming may still be viable on the high saline affected area with the right selection of salt-tolerant species, including glycophytes. The salt recovery biomarkers identified in this study and the adaption underlined could be empowered to address salinity problem in rice field.
  8. Arya S, Patel A, Kumar S, Pau-Loke S
    Environ Pollut, 2021 Aug 15;283:117033.
    PMID: 33887669 DOI: 10.1016/j.envpol.2021.117033
    Waste residues and acidic effluents (post-processing of E-waste) released into the local surroundings cause perilous environmental threats and potential risks to human health. Only limited research and information are available toward the sustainable management of waste residues generated post resource recovery of E-waste components. In the present study, the manual processing of obsolete computer (keyboard, monitor, CPU, and mouse) and chemical leaching of waste printed circuit boards (WPCBs) (motherboard, hard drive, DVD drive, and power supply) were performed for urban mining. The toxicity characteristics of typical pollutants in the residues of the WPCBs (post chemical leaching) were studied by toxicity characteristics leaching procedure (TCLP) test. Manual dismantling techniques resulted in an efficient urban mining concept with an overall average profit estimation of INR 2513.73/US$ 34.59. The chemical leaching of WPCBs showed a high concentration of metal leaching like Cu (229662 ± 575.3 mg/kg) and Pb (36785.67 ± 13.07 mg/kg) in the motherboard after stripping epoxy coating. The toxicity test revealed that the concentration of Cu (245.746 ± 0.016 mg/l) in the treated waste residue and Cu (430.746 ± 0.0015 mg/l) and Pb (182.09 ± 0.0035 mg/l) in the non-treated waste residue exceeded the threshold limit. The concentrations of other elements As, Cd, Co, Cr, Ag, Mn, Zn, Ni, Fe, Se, and In were within the permissible limit. Hence, the waste residue stands non-hazardous except Cu and Pb. Stripping out the epoxy coating of WPCBs enhances the metal leaching concentrations. The study highlighted that efficient and appropriate E-waste urban mining has immense potential in tracing the waste scrap into secondary resources. This study also emphasized that the final processed waste residue (left unattended or discarded due to lack of appropriate skill and technology) can be taken into consideration and exploited for value-added materials.
  9. Mehdizadeh H, Jia X, Mo KH, Ling TC
    Environ Pollut, 2021 Jul 01;280:116914.
    PMID: 33774540 DOI: 10.1016/j.envpol.2021.116914
    Recently, the use of accelerated carbonation curing has attracted wide attention as a promising method to reduce carbon dioxide (CO2) emission and improve the mechanical properties of cement-based materials. However, the diffusion mechanism of CO2 in the matrix and the content of hydration products are the key factors that restrict the carbonation reaction rate. To understand the combined behavior of hydration and carbonation reactions, this paper investigates the influence of cement hydration induced by water-to-cement ratio (w/c) (ranging from 0.25 to 0.45) on microstructure and microhardness properties of cement paste. The experimental results demonstrated that carbonation only occurred at the surface layer of cement paste samples and carbonation efficiency was significantly influenced by greater hydration due to higher w/c. The carbonation depth of the sample with 0.45 w/c was about 6 times higher than that of sample with 0.25 w/c after 28 days of CO2 curing. XRD results revealed that calcite-type calcium carbonate is the main carbonation product and consumption of clinker phases (C2S and C3S) during the hydration enhanced the calcite precipitation in the pores of the surface layer. According to FTIR, with increasing w/c, the position of Si-O-Si stretching bond of the carbonated surface changed from Q2 to Q3, confirming the formation of amorphous silica-rich gel, along with the appearance of CO32- bonds related to calcite. In overall, the micro-mechanical analysis in this study showed that the carbonation significantly improved the surface microhardness of cement paste samples, while the refinement of capillary pores due to carbonation also decreased the negative impact of large pores formed in the matrix of cement paste prepared with high w/c.
  10. Alahmad B, Al-Hemoud A, Kang CM, Almarri F, Kommula V, Wolfson JM, et al.
    Environ Pollut, 2021 Aug 01;282:117016.
    PMID: 33848912 DOI: 10.1016/j.envpol.2021.117016
    BACKGROUND: Kuwait and the Gulf region have a desert, hyper-arid and hot climate that makes outdoor air sampling challenging. The region is also affected by intense dust storms. Monitoring challenges from the harsh climate have limited data needed to inform appropriate regulatory actions to address air pollution in the region.

    OBJECTIVES: To compare gravimetric measurements with existing networks that rely on beta-attenuation measurements in a desert climate; determine the annual levels of PM2.5 and PM10 over a two-year period in Kuwait; assess compliance with air quality standards; and identify and quantify PM2.5 sources.

    METHODS: We custom-designed particle samplers that can withstand large quantities of dust without their inlet becoming overloaded. The samplers were placed in two populated residential locations, one in Kuwait City and another near industrial and petrochemical facilities in Ali Sabah Al-Salem (ASAS) to collect PM2.5 and PM10 samples for mass and elemental analysis. We used positive matrix factorization to identify PM2.5 sources and apportion their contributions.

    RESULTS: We collected 2339 samples during the period October 2017 through October 2019. The beta-attenuation method in measuring PM2.5 consistently exceeded gravimetric measurements, especially during dust events. The annual levels for PM2.5 in Kuwait City and ASAS were 41.6 ± 29.0 and 47.5 ± 27.6 μg/m3, respectively. Annual PM2.5 levels in Kuwait were nearly four times higher than the U.S. National Ambient Air Quality Standard. Regional pollution was a major contributor to PM2.5 levels in both locations accounting for 44% in Kuwait City and 46% in ASAS. Dust storms and re-suspended road dust were the second and third largest contributors to PM2.5, respectively.

    CONCLUSIONS: The premise that frequent and extreme dust storms make air quality regulation futile is dubious. In this comprehensive particulate pollution analysis, we show that the sizeable regional anthropogenic particulate sources warrant national and regional mitigation strategies to ensure compliance with air quality standards.

  11. Lim HR, Khoo KS, Chew KW, Chang CK, Munawaroh HSH, Kumar PS, et al.
    Environ Pollut, 2021 Sep 01;284:117492.
    PMID: 34261213 DOI: 10.1016/j.envpol.2021.117492
    Spirulina biomass accounts for 30% of the total algae biomass production globally. In conventional process of Spirulina biomass production, cultivation using chemical-based culture medium contributes 35% of the total production cost. Moreover, the environmental impact of cultivation stage is the highest among all the production stages which resulted from the extensive usage of chemicals and nutrients. Thus, various types of culture medium such as chemical-based, modified, and alternative culture medium with highlights on wastewater medium is reviewed on the recent advances of culture media for Spirulina cultivation. Further study is needed in modifying or exploring alternative culture media utilising waste, wastewater, or by-products from industrial processes to ensure the sustainability of environment and nutrients source for cultivation in the long term. Moreover, the current development of utilising wastewater medium only support the growth of Spirulina however it cannot eliminate the negative impacts of wastewater. In fact, the recent developments in coupling with wastewater treatment technology can eradicate the negative impacts of wastewater while supporting the growth of Spirulina. The application of Spirulina cultivation in wastewater able to resolve the global environmental pollution issues, produce value added product and even generate green electricity. This would benefit the society, business, and environment in achieving a sustainable circular bioeconomy.
  12. Hassan Shah MU, Bhaskar Reddy AV, Yusup S, Goto M, Moniruzzaman M
    Environ Pollut, 2021 Sep 01;284:117119.
    PMID: 33906032 DOI: 10.1016/j.envpol.2021.117119
    The well-known toxicity of conventional chemical oil spill dispersants demands the development of alternative and environmentally friendly dispersant formulations. Therefore, in the present study we have developed a pair of less toxic and green dispersants by combining lactonic sophorolipid (LS) biosurfactant individually with choline myristate and choline oleate ionic liquid surfactants. The aggregation behavior of resulted surfactant blends and their dispersion effectiveness was investigated using the baffled flask test. The introduction of long hydrophobic alkyl chain with unsaturation (attached to choline cation) provided synergistic interactions between the binary surfactant mixtures. The maximum dispersion effectiveness was found to be 78.23% for 80:20 (w/w) lactonic sophorolipid-choline myristate blends, and 81.15% for 70:30 (w/w) lactonic sophorolipid-choline oleate blends at the dispersant-to-oil ratio of 1:25 (v/v). The high dispersion effectiveness of lactonic sophorolipid-choline oleate between two developed blends is attributed to the stronger synergistic interactions between surfactants and slower desorption rate of blend from oil-water interface. The distribution of dispersed oil droplets at several DOR were evaluated and it was observed that oil droplets become smaller with increasing DOR. In addition, the acute toxicity analysis of developed formulations against zebra fish (Danio rerio) confirmed their non-toxic behavior with LC50 values higher than 400 ppm after 96 h. Overall, the proposed new blends/formulations could effectively substitute the toxic and unsafe chemical dispersants.
  13. Mahpudz A, Lim SL, Inokawa H, Kusakabe K, Tomoshige R
    Environ Pollut, 2021 Aug 24;290:117990.
    PMID: 34523515 DOI: 10.1016/j.envpol.2021.117990
    Catalytic hydrolysis of sodium borohydride (NaBH4) is a promising method to provide clean hydrogen (H2) energy for portable devices. Therefore, designing a non-noble metal catalyst that performs well in this hydrolysis is essential. Cobalt-nanoparticles (Co-NPs) supported on magnesium-aluminium layered double hydroxide (LDH) with various mean diameter were synthesized by changing concentration of cobalt-citrate anion (Co-citrate) precursor used for ion exchange with the LDH host. Then the Co-citrate intercalated LDHs were reduced with NaBH4 to form Co-NPs. Evidence of successful intercalation was shown by X-ray diffraction (XRD) and Fourier-Transform Infrared spectroscopy (FT-IR). Transmission Electron Microscope (TEM) and Scanning TEM (STEM) observations revealed that Co-NPs were in metallic state and their mean diameter increased with the concentration of Co-citrate solution. Nitrogen physisorption isotherms showed that the surface structure of LDHs transformed from non-porous to mesoporous after chemical reduction, which indicated that the Co-NPs were formed in the interlayer of LDHs. Catalytic hydrolysis of NaBH4 at 25 °C clarified that the catalyst synthesized from 6 mM Co-citrate solution showed the highest H2 generation rate of 4520 ± 251 mL min-1·gCo-1, indicating the catalyst had the optimum size of Co-NP. This activity could be considered relatively higher compared to unsupported cobalt and many other supported cobalt-base catalysts previously reported. It was also clearly shown that size of Co-NPs supported on LDH could be a significant parameter as it allowed better accessibility of reactants to the active catalyst surface to obtain maximum activity. For this optimum catalyst, the activation energy was evaluated to be 56.9 kJ mol-1. Although the catalyst was able to achieve almost the same conversion when the catalyst was repeatedly tested five times under the same condition, the catalytic activity decreased gradually. Overall, it could be revealed that Co-NPs supported on LDHs have a huge potential to be used for H2 energy production.
  14. Dayana Priyadharshini S, Suresh Babu P, Manikandan S, Subbaiya R, Govarthanan M, Karmegam N
    Environ Pollut, 2021 Aug 17;290:117989.
    PMID: 34433126 DOI: 10.1016/j.envpol.2021.117989
    Surface and water bodies in many parts of the world are affected due to eutrophication, contamination and depletion. The approach of wastewater treatment using algae for eliminating nutrients and other pollutants from domestic wastewater is growing interest among the researchers. However, sustainable treatment of the wastewater is considered to be important in establishing more effective nutrient and pollutant reduction using algal systems. In comparison to the conventional method of remediation, there are opportunities to commercially viable businesses interest with phycoremediation, thus by achieving cost reductions and renewable bioenergy options. Phycoremediation is an intriguing stage for treating wastewater since it provides tertiary bio-treatment while producing potentially valuable biomass that may be used for a variety of applications. Furthermore, the phycoremediation provides the ability to remove heavy metals as well as harmful organic substances, without producing secondary contamination. In this review, the role of microalgae in treating different wastewaters and the process parameters affecting the treatment and future scope of research have been discussed. Though several algae are employed for wastewater treatment, species of the genera Chlamydomonas, Chlorella, and Scenedesmus are extensively utilized. Interestingly, there is a vast scope for employing algal species with high flocculation capacity and adsorption mechanisms for the elimination of microplastics. In addition, the algal biomass generated during phycoremediation has been found to possess high protein and lipid contents, promising their exploitation in biofuel, food and animal feed industries.
  15. Chen HL, Gibbins CN, Selvam SB, Ting KN
    Environ Pollut, 2021 Nov 15;289:117895.
    PMID: 34364115 DOI: 10.1016/j.envpol.2021.117895
    Microplastic pollution is widely recognised as a global issue, posing risks to natural ecosystems and human health. The combination of rapid industrial and urban development and relatively limited environmental regulation in many tropical countries may increase the amount of microplastic entering rivers, but basic data on contamination levels are lacking. This is especially the case in tropical South East Asian countries. In this paper, the abundance, composition and spatio-temporal variation of microplastic in the Langat River, Malaysia, were assessed, and the relationship between microplastic concentration and river discharge was investigated. Water samples were collected over a 12-month period from 8 sampling sites on the Langat, extending from forested to heavily urbanised and industrial areas. All 508 water samples collected over this period contained microplastic; mean concentration across all sites and times was 4.39 particles/L but extended up to 90.00 particles/L in some urban tributaries. Most microplastics were secondary in origin, and dominated by fibres. Microplastic counts correlated directly with river discharge, and counts increased and decreased in response to changes in flow. A time-integrated assessment of the microplastic load conveyed by the Langat suggested that the river is typically (50 % of the time) delivering around 5 billion particles per day to the ocean. The positive correlation between the concentration of microplastics and suspended sediments in the Langat suggested that continuously logging turbidity sensors could be used to provide better estimates of microplastic loads and improve assessment of human and ecological health risks.
  16. Lin S, Ng SF, Ong WJ
    Environ Pollut, 2021 Nov 01;288:117677.
    PMID: 34273765 DOI: 10.1016/j.envpol.2021.117677
    This study aimed to analyze the environmental impacts of the oxidative desulfurization (ODS) process catalyzed by metal-free reduced graphene oxide (rGO) through life cycle assessment (LCA). The environmental impacts study containing the rGO production process, the ODS process, the comparison of different oxidants and solvents was developed. This study was performed by using ReCiPe 2016 V1.03 Hierarchist midpoint as well as endpoint approach and SimaPro software. For the production of 1 kg rGO, the results showed that hydrochloric acid (washing), sulfuric acid (mixing), hydrazine (reduction) and electricity were four main contributors in this process, and this process showed a significant impact on human health 14.21 Pt followed by ecosystem 0.845 Pt and resources 0.164 Pt. For the production of 1 kg desulfurized oil (400 ppm), main environmental impacts were terrestrial ecotoxicity (43.256 kg 1,4-DCB), global warming (41.058 kg CO2), human non-carcinogenic toxicity (19.570 kg 1,4-DCB) and fossil resource scarcity (13.178 kg oil), and the main contributors were electricity, diesel oil and acetonitrile. The whole ODS process also showed a greatest effect on human health. For two common oxidants hydrogen peroxide and oxygen used in ODS, hydrogen peroxide showed a greater impact than oxygen. On the other hand, for three common solvents employed in ODS, N-methyl-2-pyrrolidone had a more serious impact on human health followed by acetonitrile and N,N-dimethylformamide. As such, LCA results demonstrated the detailed environmental impacts originated from the catalytic ODS, hence elucidating systematic guidance for its future development toward practicality.
  17. Curren E, Kuwahara VS, Yoshida T, Leong SCY
    Environ Pollut, 2021 Nov 01;288:117776.
    PMID: 34280748 DOI: 10.1016/j.envpol.2021.117776
    Microplastic pollution is a prevalent and serious problem in marine environments. These particles have a detrimental impact on marine ecosystems. They are harmful to marine organisms and are known to be a habitat for toxic microorganisms. Marine microplastics have been identified in beach sand, the seafloor and also in marine biota. Although research investigating the presence of microplastics in various marine environments have increased across the years, studies in Southeast Asia are still relatively limited. In this paper, 36 studies on marine microplastic pollution in Southeast Asia were reviewed and discussed, focusing on microplastics in beach and benthic sediments, seawater and marine organisms. These studies have shown that the presence of fishing harbours, aquaculture farms, and tourism result in an increased abundance of microplastics. The illegal and improper disposal of waste from village settlements and factories also contribute to the high abundance of microplastics observed. Hence, it is crucial to identify the hotspots of microplastic pollution, for assessment and mitigation purposes. Future studies should aim to standardize protocols and quantification, to allow for better quantification and assessment of the levels of microplastic contamination for monitoring purposes.
  18. Yusuf A, Sodiq A, Giwa A, Eke J, Pikuda O, Eniola JO, et al.
    Environ Pollut, 2022 Jan 01;292(Pt B):118421.
    PMID: 34756874 DOI: 10.1016/j.envpol.2021.118421
    The gravity of the impending threats posed by microplastics (MPs) pollution in the environment cannot be over-emphasized. Several research studies continue to stress how important it is to curb the proliferation of these small plastic particles with different physical and chemical properties, especially in aquatic environments. While several works on how to monitor, detect and remove MPs from the aquatic environment have been published, there is still a lack of explicit regulatory framework for mitigation of MPs globally. A critical review that summarizes recent advances in MPs research and emphasizes the need for regulatory frameworks devoted to MPs is presented in this paper. These frameworks suggested in this paper may be useful for reducing the proliferation of MPs in the environment. Based on all reviewed studies related to MPs research, we discussed the occurrence of MPs by identifying the major types and sources of MPs in water bodies; examined the recent ways of detecting, monitoring, and measuring MPs routinely to minimize projected risks; and proposed recommendations for consensus regulatory actions that will be effective for MPs mitigation.
  19. Ratnasari A, Syafiuddin A, Zaidi NS, Hong Kueh AB, Hadibarata T, Prastyo DD, et al.
    Environ Pollut, 2022 Jan 01;292(Pt B):118474.
    PMID: 34763013 DOI: 10.1016/j.envpol.2021.118474
    The emergence and continual accumulation of industrial micropollutants such as dyes, heavy metals, organic matters, and pharmaceutical active compounds (PhACs) in the ecosystem pose an alarming hazard to human health and the general wellbeing of global flora and fauna. To offer eco-friendly solutions, living and non-living algae have lately been identified and broadly practiced as promising agents in the bioremediation of micropollutants. The approach is promoted by recent findings seeing better removal performance, higher efficiency, surface area, and binding affinity of algae in various remediation events compared to bacteria and fungi. To give a proper and significant insight into this technology, this paper comprehensively reviews its current applications, removal mechanisms, comparative efficacies, as well as future outlooks and recommendations. In conducting the review, the secondary data of micropollutants removal have been gathered from numerous sources, from which their removal performances are analyzed and presented in terms of strengths, weaknesses, opportunities, and threats (SWOT), to specifically examine their suitability for selected micropollutants remediation. Based on kinetic, isotherm, thermodynamic, and SWOT analysis, non-living algae are generally more suitable for dyes and heavy metals removal, meanwhile living algae are appropriate for removal of organic matters and PhACs. Moreover, parametric effects on micropollutants removal are evaluated, highlighting that pH is critical for biodegradation activity. For selective pollutants, living and non-living algae show recommendable prospects as agents for the efficient cleaning of industrial wastewaters while awaiting further supporting discoveries in encouraging technology assurance and extensive applications.
  20. Rajendran S, Hoang TKA, Trudeau ML, Jalil AA, Naushad M, Awual MR
    Environ Pollut, 2022 Jan 01;292(Pt B):118375.
    PMID: 34656681 DOI: 10.1016/j.envpol.2021.118375
    Recently, hetero junction materials (p-n-p and n-p-n) have been developed for uplifting the visible light activity to destroy the harmful pollutants in wastewater. This manuscript presents a vivid description of novel n-p-n junction materials namely CeO2-PPy-ZnO. This novel n-p-n junction was applied as the photocatalyst in drifting the mobility of charge carriers and hence obtaining the better photocatalytic activity when compared with p-n and pure system. Such catalyst's syntheses were successful via the copolymerization method. The structural, morphological and optical characterization techniques were applied to identify the physio-chemical properties of the prepared materials. Additionally, the superior performance of this n-p-n nanostructured material was demonstrated in the destruction of micro organic (chlorophenol) toxic wastes under visible light. The accomplished ability of the prepared catalysts (up to 92% degradation of chlorophenol after 180 min of irradiation) and their profound degradation mechanism was explained in detail.
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