Displaying publications 61 - 80 of 504 in total

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  1. Yasmin F, Tamrin KF, Sheikh NA, Barroy P, Yassin A, Khan AA, et al.
    Materials (Basel), 2021 Mar 09;14(5).
    PMID: 33803364 DOI: 10.3390/ma14051311
    Laser-assisted high speed milling is a subtractive machining method that employs a laser to thermally soften a difficult-to-cut material's surface in order to enhance machinability at a high material removal rate with improved surface finish and tool life. However, this machining with high speed leads to high friction between workpiece and tool, and can result in high temperatures, impairing the surface quality. Use of conventional cutting fluid may not effectively control the heat generation. Besides, vegetable-based cutting fluids are invariably a major source of food insecurity of edible oils which is traditionally used as a staple food in many countries. Thus, the primary objective of this study is to experimentally investigate the effects of water-soluble sago starch-based cutting fluid on surface roughness and tool's flank wear using response surface methodology (RSM) while machining of 316 stainless steel. In order to observe the comparison, the experiments with same machining parameters are conducted with conventional cutting fluid. The prepared water-soluble sago starch based cutting fluid showed excellent cooling and lubricating performance. Therefore, in comparison to the machining using conventional cutting fluid, a decrease of 48.23% in surface roughness and 38.41% in flank wear were noted using presented approach. Furthermore, using the extreme learning machine (ELM), the obtained data is modeled to predict surface roughness and flank wear and showed good agreement between observations and predictions.
  2. Deja M, Zieliński D, Kadir AZA, Humaira SN
    Materials (Basel), 2021 Mar 09;14(5).
    PMID: 33803424 DOI: 10.3390/ma14051318
    High requirements imposed by the competitive industrial environment determine the development directions of applied manufacturing methods. 3D printing technology, also known as additive manufacturing (AM), currently being one of the most dynamically developing production methods, is increasingly used in many different areas of industry. Nowadays, apart from the possibility of making prototypes of future products, AM is also used to produce fully functional machine parts, which is known as Rapid Manufacturing and also Rapid Tooling. Rapid Manufacturing refers to the ability of the software automation to rapidly accelerate the manufacturing process, while Rapid Tooling means that a tool is involved in order to accelerate the process. Abrasive processes are widely used in many industries, especially for machining hard and brittle materials such as advanced ceramics. This paper presents a review on advances and trends in contemporary abrasive machining related to the application of innovative 3D printed abrasive tools. Examples of abrasive tools made with the use of currently leading AM methods and their impact on the obtained machining results were indicated. The analyzed research works indicate the great potential and usefulness of the new constructions of the abrasive tools made by incremental technologies. Furthermore, the potential and limitations of currently used 3D printed abrasive tools, as well as the directions of their further development are indicated.
  3. Huseien GF, Sam ARM, Faridmehr I, Baghban MH
    Materials (Basel), 2021 Mar 06;14(5).
    PMID: 33800835 DOI: 10.3390/ma14051255
    This research investigated the application of epoxy resin polymer as a self-healing strategy for improving the mechanical and durability properties of cement-based mortar. The epoxy resin was added to the concrete mix at various levels (5, 10, 15, and 20% of cement weight), and the effectiveness of healing was evaluated by microstructural analysis, compressive strength, and non-destructive (ultrasonic pulse velocity) tests. Dry and wet-dry conditions were considered for curing, and for generating artificial cracks, specimens at different curing ages (1 and 6 months) were subjected to compressive testing (50 and 80% of specimen's ultimate compressive strength). The results indicated that the mechanical properties in the specimen prepared by 10% epoxy resin and cured under wet-dry conditions was higher compared to other specimens. The degree of damage and healing efficiency index of this particular mix design were significantly affected by the healing duration and cracking age. An optimized artificial neural network (ANN) combined with a firefly algorithm was developed to estimate these indexes over the self-healing process. Overall, it was concluded that the epoxy resin polymer has high potential as a mechanical properties self-healing agent in cement-based mortar.
  4. Lin PC, Fang JC, Lin JW, Tran XV, Ching YC
    Materials (Basel), 2020 Sep 19;13(18).
    PMID: 32961763 DOI: 10.3390/ma13184170
    Effects of processing parameters on preheated (heat-assisted) clinching process to join aluminum alloy 5052-H32 (AA5052) and thermoplastic carbon-fiber-reinforced-plastic (TP-CFRP) sheets for cross-tension (CT) specimens were first studied. Preheating was critical since brittle TP-CFRP could be softened to avoid fracturing or cracking during clinching process. Four processing parameters, including punching force, die depth, heating mode, and heating temperature, were considered. Quasi-static tests and microscope observations were taken to evaluate AA5052/TP-CFRP clinch joints in CT specimens and determine appropriate processing parameters for fatigue tests. Finally, fatigue data and failure mode of clinch joints in CT specimens were obtained and discussed.
  5. Fediuk R, Mugahed Amran YH, Mosaberpanah MA, Danish A, El-Zeadani M, Klyuev SV, et al.
    Materials (Basel), 2020 Oct 22;13(21).
    PMID: 33105753 DOI: 10.3390/ma13214712
    The incessant demand for concrete is predicted to increase due to the fast construction developments worldwide. This demand requires a huge volume of cement production that could cause an ecological issue such as increasing the rates of CO2 emissions in the atmosphere. This motivated several scholars to search for various alternatives for cement and one of such alternatives is called sulfur-based concrete. This concrete composite contributes to reduce the amount of cement required to make conventional concrete. Sulfur can be used as a partial-alternate binder to Ordinary Portland Cement (OPC) to produce sulfur-based concrete, which is a composite matrix of construction materials collected mostly from aggregates and sulfur. Sulfur modified concrete outperforms conventional concrete in terms of rapid gain of early strength, low shrinkage, low thermal conductivity, high durability resistance and excellent adhesion. On the basis of mentioned superior characteristics of sulfur-based concrete, it can be applied as a leading construction material for underground utility systems, dams and offshore structures. Therefore, this study reviews the sources, emissions from construction enterprises and compositions of sulfur; describes the production techniques and properties of sulfur; and highlights related literature to generate comprehensive insights into the potential applications of sulfur-based concrete in the construction industry today.
  6. Rafiq W, Bin Napiah M, Hartadi Sutanto M, Salah Alaloul W, Nadia Binti Zabri Z, Imran Khan M, et al.
    Materials (Basel), 2020 Oct 22;13(21).
    PMID: 33105633 DOI: 10.3390/ma13214704
    Moisture damage in hot mix asphalt pavements is a periodic but persistent problem nowadays, even though laboratory testing is performed to identify different moisture-susceptible mixtures. In this study, a Hamburg Wheel Tracking device (HWTD) was used for rutting tests which were conducted on control and a high percentage of recycled asphalt pavement (RAP), i.e., 30%, 50% and 100% of virgin mixtures, under air dry and water-immersed conditions. Similarly, the extracted bitumen from RAP was tested for binder physical properties. Results showed that the asphalt mixtures containing RAP have less rut depth as compared to the control mix both in air dry and immersion conditions and hence showed better anti-rutting properties and moisture stability. Stripping performance of control and RAP containing mixtures was also checked, concluding that the RAP mixture was greatly dependent on the interaction between the binder (virgin plus aged) and aggregates.
  7. M Nofal M, Aziz SB, Hadi JM, Abdulwahid RT, Dannoun EMA, Marif AS, et al.
    Materials (Basel), 2020 Oct 30;13(21).
    PMID: 33143345 DOI: 10.3390/ma13214890
    In this study, porous cationic hydrogen (H+) conducting polymer blend electrolytes with an amorphous structure were prepared using a casting technique. Poly(vinyl alcohol) (PVA), chitosan (CS), and NH4SCN were used as raw materials. The peak broadening and drop in intensity of the X-ray diffraction (XRD) pattern of the electrolyte systems established the growth of the amorphous phase. The porous structure is associated with the amorphous nature, which was visualized through the field-emission scanning electron microscope (FESEM) images. The enhancement of DC ionic conductivity with increasing salt content was observed up to 40 wt.% of the added salt. The dielectric and electric modulus results were helpful in understanding the ionic conductivity behavior. The transfer number measurement (TNM) technique was used to determine the ion (tion) and electron (telec) transference numbers. The high electrochemical stability up to 2.25 V was recorded using the linear sweep voltammetry (LSV) technique.
  8. Borhan A, Yusuf S
    Materials (Basel), 2020 Nov 04;13(21).
    PMID: 33158295 DOI: 10.3390/ma13214970
    Carbon dioxide (CO2) has been deemed a significant contributor to the climate crisis and has an impact on environmental systems. Adsorption is widely used among other technologies for carbon capture because of its many benefits. As a starting material for the production of activated carbon (AC) by chemical activation using malic acid due to its biodegradable and non-toxic properties, rubber seed shell (RSS) was used as agricultural waste from rubber farming. Sample A6, which was carbonized for 120 min at a temperature of 600 °C and impregnated at a ratio of 1:2, was identified to achieve the highest surface area of 938.61 m2/g with micropore diameter of 1.368 nm, respectively. Using the fixed volumetric approach measured at 25, 50, and 100 °C, the maximum CO2 adsorption capability reported is 59.73 cm3/g of adsorbent. Using the pseudo-first order of Lagergren, the pseudo-second order and the Elovich model, experimental data is modeled. It appears that, based on the correlation coefficient, the pseudo-first order model is aligned with the experimental findings. Furthermore, the activation energy of under 40 kJ/mol indicated a physical adsorption occurs, indicating that the RSS chemically activated with malic acid is a fascinating source of CO2 removal requirements.
  9. Aziz SB, Brevik I, Brza MA, Asnawi ASFM, Dannoun EMA, Yusof YM, et al.
    Materials (Basel), 2020 Nov 07;13(21).
    PMID: 33171877 DOI: 10.3390/ma13215030
    In this study, structural characterization, electrical properties and energy storage performance of plasticized polymer electrolytes based on polyvinyl alcohol/methylcellulose/ammonium thiocyanate (PVA/MC-NH4SCN) were carried out. An X-ray diffraction (XRD) study displayed that the plasticized electrolyte system with the uppermost value of direct current (DC) ionic conductivity was the most amorphous system. The electrolyte in the present work realized an ionic conductivity of 2.903 × 10-3 Scm-1 at room temperature. The main charge carrier in the electrolyte was found to be the ions with the ionic transference number (tion) of 0.912, compared to only 0.088 for the electronic transference number (telec). The electrochemical stability potential window of the electrolyte is 2.1 V. The specific capacitance was found to reduce from 102.88 F/g to 28.58 F/g as the scan rate increased in cyclic voltammetry (CV) analysis. The fabricated electrochemical double layer capacitor (EDLC) was stable up to 200 cycles with high efficiency. The specific capacitance obtained for the EDLC by using charge-discharge analysis was 132.7 F/g at the first cycle, which is slightly higher compared to the CV plot. The equivalent series resistance (ESR) increased from 58 to 171 Ω throughout the cycles, which indicates a good electrolyte/electrode contact. Ions in the electrolyte were considered to have almost the same amount of energy during the conduction process as the energy density is approximately at 14.0 Wh/kg throughout the 200 cycles. The power density is stabilized at the range of 1444.3 to 467.6 W/kg as the EDLC completed the cycles.
  10. Umair M, Azis N, Halis R, Jasni J
    Materials (Basel), 2020 Nov 06;13(21).
    PMID: 33171971 DOI: 10.3390/ma13215002
    This paper presents an investigation on the physio-mechanical properties and AC breakdown voltage of the Kenaf paper in the presence of Polyvinyl Alcohol (PVA) for transformers application. Kenaf bast fibers were used in order to produce the paper through the soda pulping process. The pulps were subjected to beating up to 12,000 revolutions, whereby the PVA was added to the pulps at a different weight percentage concentration up to 12%. Morphological study was carried out on the Kenaf paper based on Scanning Electron Microscopy (SEM). The apparent density, Tensile Index (TI), Burst Index (BI), Tear Index (TeI), and AC breakdown voltage of the Kenaf paper were measured. It is found that the TI and BI of Kenaf paper can be slightly improved through the introduction of PVA. On other hand, the TeI of the Kenaf paper decreases with the increment of the PVA. The AC breakdown voltage of the Kenaf paper slightly increases with the increment of PVA weight percentage concentration.
  11. Ncube LK, Ude AU, Ogunmuyiwa EN, Zulkifli R, Beas IN
    Materials (Basel), 2020 Nov 06;13(21).
    PMID: 33171895 DOI: 10.3390/ma13214994
    Plastics have remained the material of choice, and after serving their intended purpose, a large proportion ends up in the environment where they persist for centuries. The packaging industry is the largest and growing consumer of synthetic plastics derived from fossil fuels. Food packaging plastics account for the bulk of plastic waste that are polluting the environment. Additionally, given the fact that petroleum reserves are finite and facing depletion, there is a need for the development of alternative materials that can serve the same purpose as conventional plastics. This paper reviews the function of packaging materials and highlights the future potential of the adoption of green materials. Biopolymers have emerged as promising green materials although they still have very low market uptake. Polylactic acid (PLA) has emerged as the most favoured bioplastic. However, it is limited by its high cost and some performance drawbacks. Blending with agricultural waste and natural fillers can result in green composites at low cost, low greenhouse gas emissions, and with improved performance for food packaging applications. The continent of Africa is proposed as a rich source of fibres and fillers that can be sustainably exploited to fabricate green composites in a bid to achieve a circular economy.
  12. Alabduljabbar H, Huseien GF, Sam ARM, Alyouef R, Algaifi HA, Alaskar A
    Materials (Basel), 2020 Dec 02;13(23).
    PMID: 33276508 DOI: 10.3390/ma13235490
    Alkali activated concretes have emerged as a prospective alternative to conventional concrete wherein diverse waste materials have been converted as valuable spin-offs. This paper presents a wide experimental study on the sustainability of employing waste sawdust as a fine/coarse aggregate replacement incorporating fly ash (FA) and granulated blast furnace slag (GBFS) to make high-performance cement-free lightweight concretes. Waste sawdust was replaced with aggregate at 0, 25, 50, 75, and 100 vol% incorporating alkali binder, including 70% FA and 30% GBFS. The blend was activated using a low sodium hydroxide concentration (2 M). The acoustic, thermal, and predicted engineering properties of concretes were evaluated, and the life cycle of various mixtures were calculated to investigate the sustainability of concrete. Besides this, by using the available experimental test database, an optimized Artificial Neural Network (ANN) was developed to estimate the mechanical properties of the designed alkali-activated mortar mixes depending on each sawdust volume percentage. Based on the findings, it was found that the sound absorption and reduction in thermal conductivity were enhanced with increasing sawdust contents. The compressive strengths of the specimens were found to be influenced by the sawdust content and the strength dropped from 65 to 48 MPa with the corresponding increase in the sawdust levels from 0% up to 100%. The results also showed that the emissions of carbon dioxide, energy utilization, and outlay tended to drop with an increase in the amount of sawdust and show more the lightweight concrete to be more sustainable for construction applications.
  13. Zeng H, Wu M, Wang HQ, Zheng JC, Kang J
    Materials (Basel), 2020 Dec 12;13(24).
    PMID: 33322841 DOI: 10.3390/ma13245686
    The magnetic and electronic properties of boron-doped SrTiO3 have been studied by first-principles calculations. We found that the magnetic ground states of B-doped SrTiO3 strongly depended on the dopant-dopant separation distance. As the dopant-dopant distance varied, the magnetic ground states of B-doped SrTiO3 can have nonmagnetic, ferromagnetic or antiferromagnetic alignment. The structure with the smallest dopant-dopant separation exhibited the lowest total energy among all configurations considered and was characterized by dimer pairs due to strong attraction. Ferromagnetic coupling was observed to be stronger when the two adjacent B atoms aligned linearly along the B-Ti-B axis, which could be associated with their local bonding structures. Therefore, the symmetry of the local structure made an important contribution to the generation of a magnetic moment. Our study also demonstrated that the O-Ti-O unit was easier than the Ti-B-Ti unit to deform. The electronic properties of boron-doped SrTiO3 tended to show semiconducting or insulating features when the dopant-dopant distance was less than 5 Å, which changed to metallic properties when the dopant-dopant distance was beyond 5 Å. Our calculated results indicated that it is possible to manipulate the magnetism and band gap via different dopant-dopant separations.
  14. Murali G, Amran M, Fediuk R, Vatin N, Raman SN, Maithreyi G, et al.
    Materials (Basel), 2020 Dec 11;13(24).
    PMID: 33322254 DOI: 10.3390/ma13245648
    Ferrocement panels, while offering various benefits, do not cover instances of low and moderated velocity impact. To address this problem and to enhance the impact strength against low-velocity impact, a fibrous ferrocement panel is proposed and investigated. This study aims to assess the flexural and low-velocity impact response of simply supported ferrocement panels reinforced with expanded wire mesh (EWM) and steel fibers. The experimental program covered 12 different ferrocement panel prototypes and was tested against a three-point flexural load and falling mass impact test. The ferrocement panel system comprises mortar reinforced with 1% and 2% dosage of steel fibers and an EWM arranged in 1, 2, and 3 layers. For mortar preparation, a water-cement (w/c) ratio of 0.4 was maintained and all panels were cured in water for 28 days. The primary endpoints of the investigation are first crack and ultimate load capacity, deflection corresponding to first crack and ultimate load, ductility index, flexural strength, crack width at ultimate load, a number of impacts needed to induce crack commencement and failure, ductility ratio, and failure mode. The finding revealed that the three-layers of EWM inclusion and steel fibers resulted in an additional impact resistance improvement at cracking and failure stages of ferrocement panels. With superior ultimate load capacity, flexural strength, crack resistance, impact resistance, and ductile response, as witnessed in the experiment program, ferrocement panel can be a positive choice for many construction applications subjected to repeated low-velocity impacts.
  15. Tan PS, Akhavan Farid A, Karimzadeh A, Rahimian Koloor SS, Petrů M
    Materials (Basel), 2020 Sep 21;13(18).
    PMID: 32967330 DOI: 10.3390/ma13184199
    The curvature correction factor is an important parameter in the stress calculation formulation of a helical extension spring, which describes the effect of spring wire curvature on the stress increase towards its inner radius. In this study, the parameters affecting the curvature correction factor were investigated through theoretical and numerical methods. Several finite element (FE) models of an extension spring were generated to obtain the distribution of the tensile stress in the spring. In this investigation, the hook orientation and the number of coils of the extension spring showed significant effects on the curvature correction factor. These parameters were not considered in the theoretical model for the calculation of the curvature correction factor, causing a deviation between the results of the FE model and the theoretical approach. A set of equations is proposed for the curvature correction factor, which relates both the spring index and the number of coils. These equations can be applied directly to the design of extension springs with a higher safety factor.
  16. Nizamuddin S, Qureshi SS, Baloch HA, Siddiqui MTH, Takkalkar P, Mubarak NM, et al.
    Materials (Basel), 2019 Jan 28;12(3).
    PMID: 30696042 DOI: 10.3390/ma12030403
    The process parameters of microwave-induced hydrothermal carbonization (MIHTC) play an important role on the hydrothermal chars (hydrochar) yield. The effect of reaction temperature, reaction time, particle size and biomass to water ratio was optimized for hydrochar yield by modeling using the central composite design (CCD). Further, the rice straw and hydrochar at optimum conditions have been characterized for energy, chemical, structural and thermal properties. The optimum condition for hydrochar synthesis was found to be at a 180 °C reaction temperature, a 20 min reaction time, a 1:15 weight per volume (w/v) biomass to water ratio and a 3 mm particle size, yielding 57.9% of hydrochar. The higher heating value (HHV), carbon content and fixed carbon values increased from 12.3 MJ/kg, 37.19% and 14.37% for rice straw to 17.6 MJ/kg, 48.8% and 35.4% for hydrochar. The porosity, crystallinity and thermal stability of the hydrochar were improved remarkably compared to rice straw after MIHTC. Two characteristic peaks from XRD were observed at 2θ of 15° and 26°, whereas DTG peaks were observed at 50⁻150 °C and 300⁻350 °C for both the materials. Based on the results, it can be suggested that the hydrochar could be potentially used for adsorption, carbon sequestration, energy and agriculture applications.
  17. Nguyen HN, Nguyen TY, Tran KV, Tran TT, Nguyen TT, Phan VD, et al.
    Materials (Basel), 2019 Feb 16;12(4).
    PMID: 30781542 DOI: 10.3390/ma12040598
    Triple-layered composite plates are created by joining three composite layers using shear connectors. These layers, which are assumed to be always in contact and able to move relatively to each other during deformation, could be the same or different in geometric dimensions and material. They are applied in various engineering fields such as ship-building, aircraft wing manufacturing, etc. However, there are only a few publications regarding the calculation of this kind of plate. This paper proposes novel equations, which utilize Mindlin's theory and finite element modelling to simulate the forced vibration of triple-layered composite plates with layers connected by shear connectors subjected to a moving load. Moreover, a Matlab computation program is introduced to verify the reliability of the proposed equations, as well as the influence of some parameters, such as boundary conditions, the rigidity of the shear connector, thickness-to-length ratio, and the moving load velocity on the dynamic response of the composite plate.
  18. Makmud MZH, Illias HA, Chee CY, Dabbak SZA
    Materials (Basel), 2019 Mar 11;12(5).
    PMID: 30861988 DOI: 10.3390/ma12050816
    This study provides a thorough investigation of partial discharge (PD) activities in nanofluid insulation material consisting of different types of nanoparticles, which are conductive and semiconductive when subjected to high voltage stress is presented. Nanofluids have become a topic of interest because they can be an alternative to liquid insulation in electrical apparatus due to their promising dielectric strength and cooling ability. However, during in-service operation, PDs can occur between conductors in the insulation system. Therefore, this study presents the behavior of PDs within nanofluid dielectric materials consisting of conductive and semiconductive nanoparticles. The results show that there is an improvement in the PD resistance and a reduction in the tan delta of nanofluids at power frequency after the incorporation of conductive or semiconductive nanoparticles in the nanofluid oil. However, the most suitable concentration of conductive and semiconductive nanoparticles in the base fluid was found to be, respectively, 0.01 g/L and 1.0 g/L at PD inception and PD steady-state conditions. The clustering of nanoparticles in a nanofluid suspension due to PD activities is also discussed in this study.
  19. Al Balawi AN, Yusof NA, Kamaruzaman S, Mohammad F, Wasoh H, Al-Lohedan HA
    Materials (Basel), 2019 Apr 11;12(7).
    PMID: 30978916 DOI: 10.3390/ma12071178
    The present study deals with the synthesis, characterization, and DNA extraction of poly(4,4'-cyclohexylidene bisphenol oxalate)/silica (Si) nanocomposites (NCs). The effects of varying the monomer/Si (3.7%, 7%, and 13%) ratio towards the size and morphology of the resulting NC and its DNA extraction capabilities have also been studied. For the NC synthesis, two different methods were followed, including the direct mixing of poly(4,4'-cyclohexylidene bisphenol oxalate) with fumed Si, and in situ polymerization of the 4,4'-cyclohexylidene bisphenol monomer in the presence of fumed silica (11 nm). The formed NCs were thoroughly investigated by using different techniques such as scanning electron microscopy (SEM), fourier transform infrared (FTIR) spectroscopy, differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), powdered X-ray diffraction (XRD), and Brunauer-Emmett-Teller (BET) analysis where the results supported that there was the successful formation of poly(4,4'-cyclohexylidene bisphenol oxalate)/Si NC. Within the three different NC samples, the one with 13% Si was found to maintain a very high surface area of 12.237 m²/g, as compared to the other two samples consisting of 7% Si (3.362 m²/g) and 3.7% Si (1.788 m²/g). Further, the solid phase DNA extraction studies indicated that the efficiency is strongly influenced by the amount of polymer (0.2 g > 0.1 g > 0.02 g) and the type of binding buffer. Among the three binding buffers tested, the guanidine hydrochloride/EtOH buffer produced the most satisfactory results in terms of yield (1,348,000 ng) and extraction efficiency (3370 ng/mL) as compared to the other two buffers of NaCl (2 M) and phosphate buffered silane. Based on our results, it can be indicated that the developed poly(4,4'-cyclohexylidene bisphenol oxalate)/Si NC can serve as one of the suitable candidates for the extraction of DNA in high amounts as compared to other traditional solid phase approaches.
  20. Aziz SB, Nofal MM, Kadir MFZ, Dannoun EMA, Brza MA, Hadi JM, et al.
    Materials (Basel), 2021 Apr 16;14(8).
    PMID: 33923484 DOI: 10.3390/ma14081994
    This report shows a simple solution cast methodology to prepare plasticized polyvinyl alcohol (PVA)/methylcellulose (MC)-ammonium iodide (NH4I) electrolyte at room temperature. The maximum conducting membrane has a conductivity of 3.21 × 10-3 S/cm. It is shown that the number density, mobility and diffusion coefficient of ions are enhanced by increasing the glycerol. A number of electric and electrochemical properties of the electrolyte-impedance, dielectric properties, transference numbers, potential window, energy density, specific capacitance (Cs) and power density-were determined. From the determined electric and electrochemical properties, it is shown that PVA: MC-NH4I proton conducting polymer electrolyte (PE) is adequate for utilization in energy storage device (ESD). The decrease of charge transfer resistance with increasing plasticizer was observed from Bode plot. The analysis of dielectric properties has indicated that the plasticizer is a novel approach to increase the number of charge carriers. The electron and ion transference numbers were found. From the linear sweep voltammetry (LSV) response, the breakdown voltage of the electrolyte is determined. From Galvanostatic charge-discharge (GCD) measurement, the calculated Cs values are found to drop with increasing the number of cycles. The increment of internal resistance is shown by equivalent series resistance (ESR) plot. The energy and power density were studied over 250 cycles that results to the value of 5.38-3.59 Wh/kg and 757.58-347.22 W/kg, respectively.
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