A case of signet-ring cell lymphoma diagnosed initially by fine needle aspiration cytology is reported. This rare tumor is a variant of follicular lymphoma, which closely resembles metastatic adenocarcinoma and other tumors which exhibit signet-ring cell appearance. Correct diagnosis can be achieved by careful morphologic analysis together with positive reactivity with lymphoid markers. The cytohistologic, immunohistochemical and electron microscopic features are described, and the differ ential diagnostic considerations are discussed in the report.
Polymer blends of 60/40 NR/HDPE were prepared using Brabender PL2000 Plasticorder with 60g capacity. The blends were added with radiation-sensitive natural rubber (NR)-based compatibilizer, known as LENRA. They were irradiated with electron-beam radiation at various doses. The efficacy of the compatibilizer was monitored by measuring various properties of the blends such as physical and dynamic mechanical properties including morphological studies by electron microscopic technique. Early results show that the addition of LENRA improves the properties of the TPNR blends.
Neutron aperture is one of the collimator components in a neutron radiography facility. The optimum design of neutron aperture is very importance in order to obtain largest L/D ratio with highest thermal neutron flux and low gamma-rays at the image plane. In this study, the optimization of neutron aperture parameters were done using Monte Carlo N-Particle Transport Code, version five (MCNP5). This code has a capability to simulate the neutron, photon, and electron or coupled of neutron/photon/electron transport, including the capability to calculate eigen values for critical system. The aperture parameters concerned in this study are the selection of best aperture material, aperture thickness, aperture position and aperture center hole diameter. In these simulations, vacuum beam port medium was applied.
A laboratory scale test rig to treat simulated flue gas using electron beam technology was installed at the Alurtron EB-Irradiation Center, MINT. The experiment test rig was proposed as a result of feasibility studies conducted jointly by IAEA, MINT and TNB Research in 1997. The test rig system consists of several components, among others, diesel generator sets, pipe ducts, spray cooler, ammonia dosage system, irradiation vessel, bag filter and gas analyzers. The installation was completed and commissioned in October 2001. Results from the commissioning test runs and subsequent experimental work showed that the efficiency of flue gas treatment is high. It was proven that electron beam technology might be applied in the treatment of air pollutants. This paper describes the design and work function of the individual major components as well as the full system function. Results from the initial experimental works are also presented.
Effects of organoclay concentration on the properties of radiation crosslinked natural rubber (NR)/ ethylene vinyl acetate (EVA)/clay nanocomposites were investigated. The NR/EVA blend with a ratio of 40/60 was melt blended with different concentration of either dodecyl ammonium montmorillonite (DDA-MMT) or dimethyl dihydrogenated tallow quarternary ammonium montmorillonite (C20A). Composite of NR/EVA blend with unmodified clay (Na-MMT) was also prepared for comparison purposes. The composites were irradiated with electron beam (EB) at an optimum irradiation dose. The formation of radiation-induced crosslinking depends on the type and concentration of the organoclay used in the preparation of nanocomposites as measured by gel content. Changes in the interlayer distance of the silicate layers with the increase of organoclay concentration were shown by the XRD results. Variation in the tensile properties of the nanocomposites with the increase of organoclay concentration depends on the formation of crosslinking as well as reinforcement effect of the organoclay. Improvement in thermal stability of the NR/EVA blend was also observed with the presence of organoclay.
Space weather forecasting and its importance for the power and communication industry have inspired research related to TEC forecasting lately. Research has attempted to establish an empirical model approach for TEC prediction. In this paper, artificial neural networks (ANNs) have been applied in total electron content using GPS Ionospheric Scintillation and TEC Monitor (GISTM) data from UKM Station. The TEC prediction will be useful in improving the quality of current GNSS applications, such as in automobiles, road mapping, location-based advertising, personal navigation or logistics. Hence, a neural network model was designed with relevant features and customised parameters. Various types of input data and data representations from the ionospheric activity were used for the chosen network structure, which was a three-layer perceptron trained by feed forward back propagation method and tested on the chosen test data. We found that the optimum RMSE occurred with 10 nodes as the best NN for GISTM UKM station for the studied period with RMSE 1.3457 TECU. An analysis was made to compare the TEC from the measured TEC with neural network prediction and from IRI-corr model. The results showed that the NN model forecast the TEC values close to the measured TEC values with 9.96% of relative error. Thus, the forecasting of total electron content has the potential to be implemented successfully with larger data set from multi-centred environment.
A search for a heavy neutral lepton N of Majorana nature decaying into a W boson and a charged lepton is performed using the CMS detector at the LHC. The targeted signature consists of three prompt charged leptons in any flavor combination of electrons and muons. The data were collected in proton-proton collisions at a center-of-mass energy of 13 TeV, with an integrated luminosity of 35.9 fb^{-1}. The search is performed in the N mass range between 1 GeV and 1.2 TeV. The data are found to be consistent with the expected standard model background. Upper limits are set on the values of |V_{eN}|^{2} and |V_{μN}|^{2}, where V_{ℓN} is the matrix element describing the mixing of N with the standard model neutrino of flavor ℓ. These are the first direct limits for N masses above 500 GeV and the first limits obtained at a hadron collider for N masses below 40 GeV.
The most sensitive part of a metal-oxide-semiconductor (MOS) structure to ionizing radiation is the
oxide insulating layer. When ionizing radiation passes through the oxide, the energy deposited creates
electron/hole pairs. Oxide trapped charge causes a negative shift in capacitance-voltage (C-V)
characteristics. These changes are the results of, firstly, incre using trapped positive charge in the
oxide, which causes a parallel shift of the curve to more negative voltages, and secondly, increasing
interface trap density, which causes the curve to stretch-out.
In this study, a novel glyphosate-degrading shows the ability to reduce molybdenum to
molybdenum blue. The enzyme from this bacterium was partially purified and partially
characterized to ascertain whether the Mo-reducing enzyme from this bacterium shows better or
lower efficiency in reducing molybdenum compared to other Mo-reducing bacterium that only
exhibits a single biotransformation activity. The enzyme was partially purified using ammonium
sulphate fractionation. The Vmax for the electron donating substrate or NADH was at 1.905 nmole
Mo blue/min while the Km was 6.146 mM. The regression coefficient was 0.98. Comparative
assessment with the previously characterized Mo-reducing enzyme from various bacteria showed
that the Mo-reducing enzyme from Burkholderia vietnamiensis strain AQ5-12 showed a lower
enzyme activity.
An electron beam (EB) flue gas test rig and a dielectric barrier discharge (DBD) reactor were tested for the removal of nitric oxide (NO) from gas stream in separate experiments. In both systems, energised electrons were used to produce radicals that reacted with the pollutants. The EB system was a laboratory scale test rig used to treat emission from a diesel run generator. At 1.0 MeV and 10 mA more than 90% NO removal from flue gases flowing at 120 Nm3/h can be achieved. For higher removal percentage, higher beam current was required. In a related effort, a table top, two tubes DBD reactor was used to process bottled gases containing 106 ppm NO. Total removal (>99%) was achieved when the inlet gas contained only NO and N2. Additional SO2 in the in let gas stream lowered the removal rate but was overcame by scaling up the system to 10 DBD tubes. The system was operated with input AC voltage of 35 kV peak to peak. In the EB treatment system, the amount of NO2 increased at high beam current, showing that the NO was also oxidised in the process. Whereas in the DBD reactor, the amount of NO2 remained insignificant throughout the process. This leads to the conclusion that the DBD reactor is capable of producing total removal of NO. This is highly desirable as post treatment will not be necessary.
In this study TiO2 films have been prepared using two different techniques i.e. sol-gel and electron gun evaporation (e-gun) techniques. The films were annealed at 300, 350 and 400oC in air. The microstructure study using field emission scanning electron microscope and x-ray diffractometer showed nanometer grains size and only the film prepared by sol-gel and annealed at 400oC has anatase phase while others are amorphous. To study the effect of the films (as buffer layer) onto the dielectric bolometer Ba0.6Sr 0.4TiO3 as distance sensor, sensors with the configuration of Al/BST/TiO2/RuO2/SiO2/Si were built. Two different measurements i.e. with and without infrared source were carried out to measure the sensitivity and repeatability of the sensors. The sensors which contained sol-gel TiO2 films gave reading for both type of measurements, indicating that the sensor can act as active and passive sensors. However, the sensors which contained e-gun TiO2 films only gave responses when the IR source was used, indicating that they can only act as passive sensors. The most sensitive sensor was TiO2 film prepared by sol gel and annealed at 350oC. In general sensors which contained TiO2 films prepared by sol gel showed good repeatability.
The effects of strontium doping on the electrical and magneto-transport properties of magneto resistive La0.7Ca0.28Sr0.02MnO3 at different sintering temperatures have been studied. The samples were prepared by the co-precipitation technique (COP) and sintered at 1120, 1220 and 1320 oC. XRD patterns revealed that the samples have an orthorhombic structure and the diffraction patterns can be indexed with the Pbnm space group. The insulator metal transition, TIM increased linearly from 261 K to 272 K with the increase in sintering temperature. The magnetoresistance (MR) measurements were made in magnetic fields from 0.1 to 1 T at room temperature. The percentage of MR increased with increasing of magnetic field and sintering temperature for all samples. The electrical resistivity data were fitted with several equations in the metallic (ferromagnetic) and insulator (paramagnetic) regime. The density of states at the Fermi level N(EF) and the activation energy (Ea) of electron hopping were estimated by using variable range hopping and small polaron hopping model.
Bottom-contact pentacene OTFTs are fabricated using cross-linked poly(vinyl alcohol) (PVA) insulator and its reliability characteristics are analyzed. The hysteresis of the OTFTs is mainly caused by the electrons that are injected from the gate electrode to the cross-linked PVA insulator. To block the injection of electrons, plasma-enhanced chemical vapor deposition (PECVD) SiO2 layer is inserted between the gate electrode and the cross-linked PVA layer, so that the minimum hysteresis can be obtained. In addition, the effects of the gate bias stress as a function of time is investigated to examine the long-term reliability of the device during the operation.
In the present work, polymer electrolytes of poly(vinylidene fluoride co-hexafluoroproplyne) (PVDF-HFP) and PVDF-HFP/poly(ethyl methacrylate) (PVDF-HFP/PEMA) blend complexed with different concentrations of ammonium triflate (NH4CF3SO3) were prepared and characterized. The structural and thermal properties of the electrolytes were studied by XRD and DSC while the electrical properties were investigated by impedance spectroscopy. Ionic transference number measurements were done by D.C polarization technique. The results of these study showed that the PVDF-HFP/PEMA based electrolytes exhibit higher ionic conductivity as compared to PVDF-HFP based electrolytes. This could be attributed to the higher degree of amorphicity in the PVDF-HFP/PEMA based electrolytes. The results of ionic transference number measurements showed that the charge transport in these electrolytes was mainly due to ions and only negligible contribution comes from electrons.
Aryl diazonium salts are coupling agents that assist in molecules attachment to interfaces for sensing purposes. Despite
not being fully explored and not yet widely applicable for cell-based sensors, the high stability of aryl diazonium salt
formed sensing system is highly favorable in biological applications. Carbon-based electrodes are the most commonly
used in aryl diazonium modification due to its post grafting stable C-C bond formation. Here, salt bridge based microbial
fuel cells (MFCs) were used to study on the effect of aryl diazonium modification on the anode graphite fibre brush. Aryl
diazonium salts were in situ generated by the diazonation of p-phenylenediamine with NaNO2 in HCl solution. The
electrochemical performance of the aryl diazonium modified graphite brush MFC was measured and compared with the
unmodified graphite brush MFC. The power output of the modified graphite brush bioanode was higher (8.33 W/m3
)
than the unmodified graphite brush (7.60 W/m3
) after 20 days of operation with ferricyanide as the catholyte. After 70
days of operation using phosphate buffer solution as the catholyte, the Pmax of modified brush was three times higher
(0.06 W/m3
) than of the unmodified brush (0.02 W/m3
), which indicates an enhanced binding towards the substrate that
facilitates a better electron transfer between the microbial and electrode surface.
A measurement is reported of the jet mass distribution in hadronic decays of boosted top quarks produced in pp collisions at sqrt[s]=13 TeV. The data were collected with the CMS detector at the LHC and correspond to an integrated luminosity of 35.9 fb^{-1}. The measurement is performed in the lepton+jets channel of tt[over ¯] events, where the lepton is an electron or muon. The products of the hadronic top quark decay t→bW→bqq[over ¯]^{'} are reconstructed as a single jet with transverse momentum larger than 400 GeV. The tt[over ¯] cross section as a function of the jet mass is unfolded at the particle level and used to extract a value of the top quark mass of 172.6±2.5 GeV. A novel jet reconstruction technique is used for the first time at the LHC, which improves the precision by a factor of 3 relative to an earlier measurement. This highlights the potential of measurements using boosted top quarks, where the new technique will enable future precision measurements.
A search for charged Higgs bosons produced via vector boson fusion and decaying into W and Z bosons using proton-proton collisions at sqrt[s]=13 TeV is presented. The data sample corresponds to an integrated luminosity of 15.2 fb^{-1} collected with the CMS detector in 2015 and 2016. The event selection requires three leptons (electrons or muons), two jets with large pseudorapidity separation and high dijet mass, and missing transverse momentum. The observation agrees with the standard model prediction. Limits on the vector boson fusion production cross section times branching fraction for new charged physical states are reported as a function of mass from 200 to 2000 GeV and interpreted in the context of Higgs triplet models.
Photosynthetic microbial fuel cells (PMFCs) are novel bioelectrochemical transducers that employ microalgae to generate oxygen, organic metabolites and electrons. Conventional PMFCs employ non-eco-friendly membranes, catalysts and phosphate buffer solution. Eliminating the membrane, buffer and catalyst can make the MFC a practical possibility. Therefore, single chambered (SPMFC) were constructed and operated at different recirculation flow rates (0, 40 and 240 ml/min) under bufferless conditions. Furthermore, maximum power density of 4.06 mW/m2, current density of 46.34 mA/m2 and open circuit potential of 0.43 V and low internal resistance of 611.8 Ω were obtained at 40 ml/min. Based on the results it was decided that SPMFC was better for operation at 40 ml/min. Therefore, these findings provided progressive insights for future pilot and industrial scale studies of PMFCs.
The first observation of top quark production in proton-nucleus collisions is reported using proton-lead data collected by the CMS experiment at the CERN LHC at a nucleon-nucleon center-of-mass energy of sqrt[s_{NN}]=8.16 TeV. The measurement is performed using events with exactly one isolated electron or muon candidate and at least four jets. The data sample corresponds to an integrated luminosity of 174 nb^{-1}. The significance of the tt[over ¯] signal against the background-only hypothesis is above 5 standard deviations. The measured cross section is σ_{tt[over ¯]}=45±8 nb, consistent with predictions from perturbative quantum chromodynamics.
Herein, we report a detailed study on creating heterojunction between graphitic carbon nitride (g-C3N4) and bismuth phosphate (BiPO4), enhancing the unpaired free electron mobility. This leads to an accelerated photocatalysis of 2,4-dichlorophenols (2,4-DCPs) under sunlight irradiation. The heterojunction formation was efficaciously conducted via a modest thermal deposition technique. The function of g-C3N4 plays a significant role in generating free electrons under sunlight irradiation. Together, the generated electrons at the g-C3N4 conduction band (CB) are transferred and trapped by the BiPO4 to form active superoxide anion radicals (•O2-). These active radicals will be accountable for the photodegradation of 2,4-DCPs. The synthesized composite characteristics were methodically examined through several chemical and physical studies. Due to the inimitable features of both g-C3N4 and BiPO4, its heterojunction formation, 2.5wt% BiPO4/g-C3N4 achieved complete 2,4-DCP removal (100%) in 90 min under sunlight irradiation. This is due to the presence of g-C3N4 that enhanced electron mobility through the formation of heterojunctions that lengthens the electron-hole pairs' lifetime and maximizes the entire solar spectrum absorption to generate active electrons at the g-C3N4 conduction band. Thus, this formation significantly draws the attention for future environmental remediation, especially in enhancing the entire solar spectrum's harvesting.