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Fulltext Experimental Investigation and Performance Evaluation of Modified Viscoelastic Surfactant (VES) as a New Thickening Fracturing Fluid

Chieng ZH, Mohyaldinn ME, Hassan AM, Bruining H

Polymers (Basel), 2020 Jun 30;12(7).
PMID: 32629958 DOI: 10.3390/polym12071470

In hydraulic fracturing, fracturing fluids are used to create fractures in a hydrocarbon reservoir throughout transported proppant into the fractures. The application of many fields proves that conventional fracturing fluid has the disadvantages of residue(s), which causes serious clogging of the reservoir's formations and, thus, leads to reduce the permeability in these hydrocarbon reservoirs. The development of clean (and cost-effective) fracturing fluid is a main driver of the hydraulic fracturing process. Presently, viscoelastic surfactant (VES)-fluid is one of the most widely used fracturing fluids in the hydraulic fracturing development of unconventional reservoirs, due to its non-residue(s) characteristics. However, conventional single-chain VES-fluid has a low temperature and shear resistance. In this study, two modified VES-fluid are developed as new thickening fracturing fluids, which consist of more single-chain coupled by hydrotropes (i.e., ionic organic salts) through non-covalent interaction. This new development is achieved by the formulation of mixing long chain cationic surfactant cetyltrimethylammonium bromide (CTAB) with organic acids, which are citric acid (CA) and maleic acid (MA) at a molar ratio of (3:1) and (2:1), respectively. As an innovative approach CTAB and CA are combined to obtain a solution (i.e., CTAB-based VES-fluid) with optimal properties for fracturing and this behaviour of the CTAB-based VES-fluid is experimentally corroborated. A rheometer was used to evaluate the visco-elasticity and shear rate & temperature resistance, while sand-carrying suspension capability was investigated by measuring the settling velocity of the transported proppant in the fluid. Moreover, the gel breaking capability was investigated by determining the viscosity of broken VES-fluid after mixing with ethanol, and the degree of core damage (i.e., permeability performance) caused by VES-fluid was evaluated while using core-flooding test. The experimental results show that, at pH-value ( 6.17 ), 30 (mM) VES-fluid (i.e., CTAB-CA) possesses the highest visco-elasticity as the apparent viscosity at zero shear-rate reached nearly to 10 6 (mPa·s). Moreover, the apparent viscosity of the 30 (mM) CTAB-CA VES-fluid remains 60 (mPa·s) at (90 ∘ C) and 170 (s - 1 ) after shearing for 2-h, indicating that CTAB-CA fluid has excellent temperature and shear resistance. Furthermore, excellent sand suspension and gel breaking ability of 30 (mM) CTAB-CA VES-fluid at 90 ( ∘ C) was shown; as the sand suspension velocity is 1.67 (mm/s) and complete gel breaking was achieved within 2 h after mixing with the ethanol at the ratio of 10:1. The core flooding experiments indicate that the core damage rate caused by the CTAB-CA VES-fluid is ( 7.99 % ), which indicate that it does not cause much damage. Based on the experimental results, it is expected that CTAB-CA VES-fluid under high-temperature will make the proposed new VES-fluid an attractive thickening fracturing fluid.
Fulltext Stability, Rheological Behavior, and pH Responsiveness of CTAB/HCl Acidic Emulsion: Experimental Investigation

Mohyaldinn ME, Alakbari FS, Bin Azman Nor ANA, Hassan AM

ACS Omega, 2023 Jun 27;8(25):22428-22439.
PMID: 37396270 DOI: 10.1021/acsomega.2c08243

Cetyltrimethylammonium bromide (CTAB) surfactant was proven to be a reliable emulsifier for creating stable emulsions used for drilling, well stimulation, and EOR. The presence of acids like HCl during such operations may lead to the formation of acidic emulsions. No previous comprehensive investigations have been done to study the performance of CTAB-based acidic emulsions. This paper, therefore, presents experimental investigations of the stability, rheological behavior, and pH responsiveness of a CTAB/HCl-based acidic emulsion. The effects of temperature, pH, and CTAB concentration on the emulsion stability and rheology have been investigated using a bottle test and a TA Instrument DHR1 rheometer. Viscosity and flow sweep were analyzed for the steady state at a shear range of 2.5-250 s-1. For the dynamic tests, the storage modulus (G') and loss modulus (G″) were observed by applying the oscillation test at the range of shear frequency from 0.1 to 100 rad/s. The results revealed that the emulsion exhibits steady rheological behaviors ranging from Newtonian to shear-dependent (psedosteady), depending on the temperature and CTAB concentration. The tendency of the emulsion to exhibit a solid-like behavior is also dependent on CTAB concentration, temperature, and pH. However, the pH responsiveness of the emulsion is more significantly observed within the acidic range of the pH.
Developing a hierarchical framework for assessing the strategic effectiveness of sustainable waste management in the Somaliland construction industry

Negash YT, Hassan AM, Tseng ML, Ali MH, Lim MK

Environ Sci Pollut Res Int, 2023 May;30(25):67303-67325.
PMID: 37103710 DOI: 10.1007/s11356-023-27060-8

This study contributes to develop a hierarchical framework for assessing the strategic effectiveness of waste management in the construction industry. This study identifies a valid set of strategic effectiveness attributes of sustainable waste management (SWM) in construction. Prior studies have neglected to develop a strategic effectiveness assessment framework for SWM to identify reduce, reuse, and recycle policy initiatives that ensure waste minimization and resource recovery programs. This study utilizes the fuzzy Delphi method to screen out nonessential attributes in qualitative information. This study initially proposes a set of 75 criteria; after two rounds of assessment, consensus regarding 28 criteria is achieved among experts, and the 28 criteria are validated. Fuzzy interpretive structural modeling divides the attributes into various elements. The modeling constructs a six-level model that depicts the interrelationships among the 28 validated criteria as a hierarchical framework, and it finds and ranks the optimal drivers for practical improvement. This study integrates the best-worst method to measure the weights of different criteria in the hierarchical strategic effectiveness framework. The findings reveal that waste management operational strategy, construction site waste management performance, and the mutual coordination level are the top aspects for assessing strategic effectiveness in the hierarchical framework. In practice, the waste reduction rate, the recycling rate, water and land usage, the reuse rate, and noise and air pollution levels are identified to assist policymakers in evaluation. The theoretical and managerial implications are discussed.
Fulltext A practical green synthesis method of Ag NPs using rosy periwinkle plant leaves for solar panel coating

Palanichamy P, Krishnasamy R, Meenakshi Sundaram U, Thiagamani SMK, Ilyas RA, Hassan AM

Heliyon, 2023 Dec;9(12):e22893.
PMID: 38125411 DOI: 10.1016/j.heliyon.2023.e22893

Coated silver nanoparticles (Ag NPs) are currently receiving interest because of their numerous uses in various fields of electronics, antimicrobials, manufacturing sectors, optical science, and pharmaceuticals. Among others, it gained significant attention in the power electronic system. The goal of the proposed study is to use a cost-effective coating material for solar panels; to accomplish this, silver nanoparticles were synthesized from the leaves of the Rosy Periwinkle plants. Green synthesis and characterization, such as Ultraviolet Visible Spectrometer (UV-Vis) analysis, Scanning Electron Microscopy (SEM), Energy Dispersive X-ray Spectroscopy (EDX), and Fourier Transform Infrared Spectroscopy (FTIR), were carried out after the silver nanoparticles have been collected prior coating. As a consequence, the effectiveness is determined based on the conductivity test, and the resulting Ag NPs are then applied to the c-si layer of the solar panel. Additionally, a modelling and experimental analysis are performed in this study to ascertain the suggested framework's ability to measure energy before and after coating panels with Ag NPs. Specifically, the Voltage Current (VI) and Power Voltage (PV) characteristics were validated in this study for analyzing the effectiveness and the obtained results revealed that the coating of green synthesized Ag NPs generated 2 % more power than the reference solar panel under the same conditions. Further, hardware testing and simulation were both used to confirm the outcomes and effectiveness of the suggested method. The open circuit voltage (Voc), short circuit current (Isc), maximum peak voltage (Vmp), maximum peak current (Imp), and efficiency are taken into account when assessing how well the suggested system performs at tracking. Moreover, the current density characteristics were evaluated with respect to various irradiation conditions for both the typical solar as well as Ag NPs coated panels. From the observation, it is noted that the efficiency level of coated panel was improved up to 19.20 %, 18 %, and 17.20 % for the irradiations of 200 W/m2, 500 W/m2, and 1000 W/m2 respectively.
New effective 3-aminopropyltrimethoxysilane functionalized magnetic sporopollenin-based silica coated graphene oxide adsorbent for removal of Pb(II) from aqueous environment

Hassan AM, Wan Ibrahim WA, Bakar MB, Sanagi MM, Sutirman ZA, Nodeh HR, et al.

J Environ Manage, 2020 Jan 01;253:109658.
PMID: 31666209 DOI: 10.1016/j.jenvman.2019.109658

A new effective adsorbent, 3-aminopropyltrimethoxysilane functionalized magnetic sporopollenin (MSp@SiO2NH2) based silica-coated graphene oxide (GO), (GO@SiO2-MSp@SiO2NH2) was successfully synthesized and applied for the first time in the removal of hazardous Pb(II) ions from aqueous solution. The properties of the composite were characterized using Fourier-transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), field emission scanning electron microscopy (FESEM), energy-dispersive X-ray spectroscopy (EDX) and vibrating-sample magnetometery (VSM). Evaluation of GO@SiO2-MSp@SiO2NH2 adsorption performance at optimum conditions revealed that the adsorbent has a maximum adsorption capacity of 323.5 mg/g for Pb(II) using 50-200 mg/L initial Pb(II) ions concentrations. Initial and final concentrations of Pb(II) ions in aqueous solution were analyzed using graphite furnace atomic absorption spectroscopy (GF-ASS). The adsorption behavior of Pb(II) ions onto GO@SiO2-MSp@SiO2NH2 was studied using Langmuir, Freundlich and Temkin isotherms models. The values of coefficient of determination showed that the adsorption best fitted the Langmuir model (R2 = 0.9994). Kinetic studies suggested that the adsorption of Pb(II) ion followed a pseudo-second-order rate model (R2 = 1.00) and thermodynamic studies revealed that the adsorption process is endothermic and spontaneous. The effect of co-existing ions on Pb(II) ion adsorption were also studied and found to have considerable effects only at higher matrix concentration. The adsorbent can be reused up to ten times and retain its good adsorption capacity. In addition, GO@SiO2-MSp@SiO2NH2 showed great potential for Pb(II)removal from industrial wastewater samples.
Fulltext Heat and mass transfer analysis of assisting and opposing radiative flow conveying ternary hybrid nanofluid over an exponentially stretching surface

Nagaraja KV, Khan U, Madhukesh JK, Hassan AM, Prasannakumara BC, Ben Kahla N, et al.

Sci Rep, 2023 Sep 08;13(1):14795.
PMID: 37684341 DOI: 10.1038/s41598-023-41916-6

Access to dependable and environmentally friendly energy sources is critical to a country's economic growth and long-term development. As countries seek greener energy alternatives, the interaction of environmental elements, temperature, and sunlight becomes more critical in utilizing renewable energy sources such as wind and bioenergy. Solar power has received much attention due to extraordinary efficiency advances. under this context, the present work focus on solar radiation and chemical processes in the presence of modified ternary hybrid nanofluids (THNFs) circulating over an exponentially stretched surface in both aiding flow (A-F) and opposing flow (O-F) circumstances. The primary objective of this investigation is to dive into the complicated dynamics of these structures, which are distinguished by complex interactions involving radiation, chemical reactions, and the movement of fluids. We construct reduced ordinary differential equations from the governing equations using suitable similarity transformations, which allows for a more in-depth examination of the liquid's behavior. Numerical simulations using the Runge-Kutta Fehlberg (RKF) approach and shooting techniques are used to understand the underlying difficulties of these reduced equations. The results show that thermal radiation improves heat transmission substantially under O-F circumstances in contrast to A-F conditions. Furthermore, the reaction rate parameter has an exciting connection with concentration levels, with greater rates corresponding to lower concentrations. Furthermore, compared to the O-F scenario, the A-F scenario promotes higher heat transfer in the context of a modified nanofluid. Rising reaction rate and solid fraction volume enhanced mass transfer rate. The rate of thermal distribution in THNFs improves from 0.13 to 20.4% in A-F and 0.16 to 15.06% in O-F case when compared to HNFs. This study has real-world implications in several fields, including developing more efficient solar water heaters, solar thermal generating plants, and energy-saving air conditioners.
Fulltext Predicting compressive strength of eco-friendly plastic sand paver blocks using gene expression and artificial intelligence programming

Iftikhar B, Alih SC, Vafaei M, Javed MF, Rehman MF, Abdullaev SS, et al.

Sci Rep, 2023 Jul 27;13(1):12149.
PMID: 37500697 DOI: 10.1038/s41598-023-39349-2

Plastic sand paver blocks provide a sustainable alternative by using plastic waste and reducing the need for cement. This innovative approach leads to a more sustainable construction sector by promoting environmental preservation. No model or Equation has been devised that can predict the compressive strength of these blocks. This study utilized gene expression programming (GEP) and multi-expression programming (MEP) to develop empirical models to forecast the compressive strength of plastic sand paver blocks (PSPB) comprised of plastic, sand, and fibre in an effort to advance the field. The database contains 135 results for compressive strength with seven input parameters. The R2 values of 0.87 for GEP and 0.91 for MEP for compressive strength reveal a relatively significant relationship between predicted and actual values. MEP outperformed GEP by displaying a higher R2 and lower values for statistical evaluations. In addition, a sensitivity analysis was conducted, which revealed that the sand grain size and percentage of fibres play an essential part in compressive strength. It was estimated that they contributed almost 50% of the total. The outcomes of this research have the potential to promote the reuse of PSPB in the building of green environments, hence boosting environmental protection and economic advantage.
Numerical analysis of magnetohydrodynamics in an Eyring-Powell hybrid nanofluid flow on wall jet heat and mass transfer

Yaseen M, Rawat SK, Khan U, Sarris IE, Khan H, Negi AS, et al.

Nanotechnology, 2023 Sep 14;34(48).
PMID: 37625394 DOI: 10.1088/1361-6528/acf3f6

The customization of hybrid nanofluids to achieve a particular and controlled growth rate of thermal transport is done to meet the needs of applications in heating and cooling systems, aerospace and automotive industries, etc. Due to the extensive applications, the aim of the current paper is to derive a numerical solution to a wall jet flow problem through a stretching surface. To study the flow problem, authors have considered a non-Newtonian Eyring-Powell hybrid nanofluid with water and CoFe2O4and TiO2nanoparticles. Furthermore, the impact of a magnetic field and irregular heat sink/source are studied. To comply with the applications of the wall jet flow, the authors have presented the numerical solution for two cases; with and without a magnetic field. The numerical solution is derived with a similarity transformation and MATLAB-based bvp4c solver. The value of skin friction for wall jet flow at the surface decreases by more than 50% when the magnetic fieldMA=0.2is present. The stream function value is higher for the wall jet flow without the magnetic field. The temperature of the flow rises with the dominant strength of the heat source parameters. The results of this investigation will be beneficial to various applications that utilize the applications of a wall jet, such as in car defrosters, spray paint drying for vehicles or houses, cooling structures for the CPU of high-processor laptops, sluice gate flows, and cooling jets over turbo-machinery components, etc.
Fulltext The Global, Regional, and National Burden of Adult Lip, Oral, and Pharyngeal Cancer in 204 Countries and Territories: A Systematic Analysis for the Global Burden of Disease Study 2019

GBD 2019 Lip, Oral, and Pharyngeal Cancer Collaborators, Cunha ARD, Compton K, Xu R, Mishra R, Drangsholt MT, et al.

JAMA Oncol, 2023 Oct 01;9(10):1401-1416.
PMID: 37676656 DOI: 10.1001/jamaoncol.2023.2960

IMPORTANCE: Lip, oral, and pharyngeal cancers are important contributors to cancer burden worldwide, and a comprehensive evaluation of their burden globally, regionally, and nationally is crucial for effective policy planning.
OBJECTIVE: To analyze the total and risk-attributable burden of lip and oral cavity cancer (LOC) and other pharyngeal cancer (OPC) for 204 countries and territories and by Socio-demographic Index (SDI) using 2019 Global Burden of Diseases, Injuries, and Risk Factors (GBD) Study estimates.
EVIDENCE REVIEW: The incidence, mortality, and disability-adjusted life years (DALYs) due to LOC and OPC from 1990 to 2019 were estimated using GBD 2019 methods. The GBD 2019 comparative risk assessment framework was used to estimate the proportion of deaths and DALYs for LOC and OPC attributable to smoking, tobacco, and alcohol consumption in 2019.
FINDINGS: In 2019, 370 000 (95% uncertainty interval [UI], 338 000-401 000) cases and 199 000 (95% UI, 181 000-217 000) deaths for LOC and 167 000 (95% UI, 153 000-180 000) cases and 114 000 (95% UI, 103 000-126 000) deaths for OPC were estimated to occur globally, contributing 5.5 million (95% UI, 5.0-6.0 million) and 3.2 million (95% UI, 2.9-3.6 million) DALYs, respectively. From 1990 to 2019, low-middle and low SDI regions consistently showed the highest age-standardized mortality rates due to LOC and OPC, while the high SDI strata exhibited age-standardized incidence rates decreasing for LOC and increasing for OPC. Globally in 2019, smoking had the greatest contribution to risk-attributable OPC deaths for both sexes (55.8% [95% UI, 49.2%-62.0%] of all OPC deaths in male individuals and 17.4% [95% UI, 13.8%-21.2%] of all OPC deaths in female individuals). Smoking and alcohol both contributed to substantial LOC deaths globally among male individuals (42.3% [95% UI, 35.2%-48.6%] and 40.2% [95% UI, 33.3%-46.8%] of all risk-attributable cancer deaths, respectively), while chewing tobacco contributed to the greatest attributable LOC deaths among female individuals (27.6% [95% UI, 21.5%-33.8%]), driven by high risk-attributable burden in South and Southeast Asia.
CONCLUSIONS AND RELEVANCE: In this systematic analysis, disparities in LOC and OPC burden existed across the SDI spectrum, and a considerable percentage of burden was attributable to tobacco and alcohol use. These estimates can contribute to an understanding of the distribution and disparities in LOC and OPC burden globally and support cancer control planning efforts.