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  1. Tayamon S, Mazlan NA, Ravoof TB, Mohamed Tahir MI, Crouse KA
    Acta Crystallogr Sect E Struct Rep Online, 2012 Nov 1;68(Pt 11):o3104-5.
    PMID: 23284431 DOI: 10.1107/S1600536812042018
    The title compound C(8)H(15)N(3)S has two mol-ecules in the asymmetric unit in which cis-trans isomerism is exhibited around the N(NH)C=S bonds. The cyclo-hexyl rings in both mol-ecules adopt a chair conformation. In the crystal, N-H⋯S hydrogen bonding produces dimers, which are inter-connected through further N-H⋯S hydrogen bonds, forming chains along the b-axis direction.
  2. Tayamon S, Ravoof TB, Tahir MI, Crouse KA, Tiekink ER
    PMID: 23476568 DOI: 10.1107/S1600536813003966
    In the title salt, C14H17N2(+)·Cl(-), the central N atom is pyramidal (sum of bond angles = 330.9°) and there is a near orthogonal relationship between the benzene rings [dihedral angle = 89.95 (10)°]. The crystal packing features N-H⋯Cl hydrogen bonds, which lead to a supra-molecular undulating ribbon along the a axis comprising edge-shared eight-membered {⋯HNH⋯Cl}2 synthons. The chains are connected into layers in the ab plane by C-H⋯π inter-actions.
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