Displaying 1 publication

Abstract:
Sort:
  1. Yamin BM, Ismail W, Daran JC
    Acta Crystallogr Sect E Struct Rep Online, 2012 Jul 1;68(Pt 7):m886-7.
    PMID: 22807730 DOI: 10.1107/S1600536812024932
    In the title compound, [Cu₂Cl₄(C₁₆H₃₂N₄)](n), the central Cu(II) anion of the macrocyclic complex cation is weakly linked to two Cl atoms of the tetrachloridocuprate anion with Cu-Cl distances of 3.008 (3) and 3.220 (3) Å, respectively, forming a chain parallel to [10-1]. The geometry of the Cu-macrocyclic complex is distorted octa-hedral with the bridging Cl atoms occupying the axial position at an angle of 173.44 (7)° about the central Cu(II) atom. The tetrachloridocuprate anion adopts a distorted tetra-hedral geometry. In the crystal, the chain is stabilized by intra- and inter-molecular N-H⋯Cl hydrogen bonds.
Related Terms
Filters
Contact Us

Please provide feedback to Administrator (afdal@afpm.org.my)

External Links