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  1. Saleh Salga M, Khaledi H, Mohd Ali H
    PMID: 21836911 DOI: 10.1107/S1600536811022100
    In the title compound, [CdCl(2)(C(14)H(21)N(3)O(2))], the Schiff base ligand chelates the Cd(II) ion in an N,N,O-tridentate fashion. Two Cl atoms complete a distorted square-pyramidal coordination environment around the metal atom. In the crystal, adjacent mol-ecules are linked through C-H⋯π inter-actions into infinite chains along the a axis. The mol-ecules are further connected into a three-dimensional network via N-H⋯O, N-H⋯Cl and C-H⋯Cl inter-actions. The ethyl-ene group is disordered over two sets of sites in a 0.520 (10):0.480 (10) ratio.
  2. Saleh Salga M, Khaledi H, Mohd Ali H
    PMID: 21588532 DOI: 10.1107/S1600536810032563
    In the title compound, [CdCl(2)(C(13)H(19)N(3)O)], the Cd(II) ion is penta-coordinated with the N,N,O-tridentate Schiff base 2-{[2-(piperazin-4-ium-1-yl)eth-yl]imino-meth-yl}phenolate ligand and two Cl atoms in a highly distorted square-pyramidal geometry; the piperazine ring adopts a chair conformation. In the crystal structure, adjacent mol-ecules are linked together via N-H⋯O and N-H⋯Cl hydrogen bonds, forming infinite layers parallel to the ab plane. The layers are further connected through C-H⋯Cl inter-actions into a three-dimensional network.
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