Biodegradable films made from biopolymer materials have the potential to replace conventional plastics, which can reduce waste disposal problems. This study aims to explore the potential of different seaweed derivate films consisting of 2% (w/w) of kappaphycus alverezi (KA), kappa carrageenan (KC), refined carrageenan (RC) and semi-refined carrageenan (SRC) as bio-based materials with 0.9% (w/w) glycerol (G), and reinforced with different concentrations of cellulose nanofibers (CNFs) derived from palm waste. A characterization of the glycerol-plasticized seaweed derivatives containing 0, 5, 10, and 15% (v/w) cellulose nanofiber is carried out. The CNFs were studied based on their mechanical, physical and thermal properties including mechanical properties, thickness, moisture content, opacity, water solubility, water vapor permeability and thermal stability. The hydrogen bonding was determined using the DFT calculation generated by Gauss view software version 9.6. The KA + G + 10%CNF film exhibited a surface with slight cracks, roughness, and larger lumps and dents, resulting in inferior mechanical properties (18.50 Mpa), making it unsuitable for biofilm production. The KC + G + 10%CNF film exhibited mechanical properties 24.97 Mpa and water vapor permeability of 1.42311 × 10-11 g s-1 m-1 Pa-1. The RC/G/10%CNF film displayed the highest TS (48.23 MPa) and water vapor permeability (1.4168 × 10-11 g s-1 m-1 Pa-1), but it also had higher solubility in water (66%). In contrast, the SRC + G + 10%CNF film demonstrated excellent mechanical properties (45.98 MPa), low water solubility (42.59%), low water vapor permeability (1.3719 × 10-11 g s-1 m-1 Pa-1), and a high decomposition temperature (250.62 °C) compared to KA, KC and RC. These attributes develop films suitable for various applications, including food packaging with enhanced properties and stability.
This paper introduces a novel active carrageenan film designed for meat preservation, featuring the release of antioxidants eugenol (Eu) and α-tocopherol (Tp). The film is composed of semi-refined carrageenan, plasticized with 0.9 % glycerol, and reinforced with 10 % cellulose nanofibers derived from waste biomass. Lipid oxidation was measured through TBARS and percent metmyoglobin to evaluate the film's effectiveness in extending the shelf-life and maintaining the quality of meat. The film containing 0.4 % Tp demonstrates superior mechanical properties and thermal stability, achieving a tensile strength of 66.79 MPa and an elongation at break of 46.54 %. Notably, it exhibits a significant antioxidant release rate over 25 days, with TBARS and percent metmyoglobin values of 0.652 and 35.98 %, respectively. These results suggest that this biodegradable packaging solution not only prolongs meat shelf-life but also aligns with sustainable practices in food preservation. The release profiles of Eu and Tp follow a first-order kinetic model, indicating a controlled and sustained release mechanism. Overall, these findings highlight the potential of active films in enhancing food packaging solutions while promoting eco-friendliness.