• 1 Department of Applied Chemistry, School of Advanced Materials and Nanotechnology, Xidian University, Xi'an, 710126, P. R. China
  • 2 School Advanced of Chemical Sciences, Shoolini University of Biotechnology and Management Sciences, Bajhol, Solan, HP, 173212, India
  • 3 Graphene and Advanced 2D Materials Research Group (GAMRG), School of Engineering and Technology, Sunway University, No. 5, Jalan University, Bandar Sunway, Petaling Jaya, Selangor, 47500, Malaysia
  • 4 School of Physics and Material science, Shoolini University of Biotechnology and Management Sciences, Bajhol, Solan, HP, 173212, India
  • 5 Department of Botany, Ramjas College, University of Delhi, Delhi, 110007, India
  • 6 Department of Chemical Engineering, School of New Energy and Chemical Engineering, Xiamen University Malaysia, Jalan Sunsuria, Bandar Sunsuria, Sepang, Selangor, 43900, Malaysia
  • 7 NanoBioTech Laboratory, Health System Engineering, Department of Environmental Engineering, Florida Polytechnic University, Lakeland, FL, 33805, USA
  • 8 Research Cell and Department of Physics, Bhagini Nivedita College, University of Delhi, New Delhi, India
Adv Sci (Weinh), 2022 Dec;9(36):e2203527.
PMID: 36316226 DOI: 10.1002/advs.202203527


The continuous deterioration of the environment due to extensive industrialization and urbanization has raised the requirement to devise high-performance environmental remediation technologies. Membrane technologies, primarily based on conventional polymers, are the most commercialized air, water, solid, and radiation-based environmental remediation strategies. Low stability at high temperatures, swelling in organic contaminants, and poor selectivity are the fundamental issues associated with polymeric membranes restricting their scalable viability. Polymer-metal-carbides and nitrides (MXenes) hybrid membranes possess remarkable physicochemical attributes, including strong mechanical endurance, high mechanical flexibility, superior adsorptive behavior, and selective permeability, due to multi-interactions between polymers and MXene's surface functionalities. This review articulates the state-of-the-art MXene-polymer hybrid membranes, emphasizing its fabrication routes, enhanced physicochemical properties, and improved adsorptive behavior. It comprehensively summarizes the utilization of MXene-polymer hybrid membranes for environmental remediation applications, including water purification, desalination, ion-separation, gas separation and detection, containment adsorption, and electromagnetic and nuclear radiation shielding. Furthermore, the review highlights the associated bottlenecks of MXene-Polymer hybrid-membranes and its possible alternate solutions to meet industrial requirements. Discussed are opportunities and prospects related to MXene-polymer membrane to devise intelligent and next-generation environmental remediation strategies with the integration of modern age technologies of internet-of-things, artificial intelligence, machine-learning, 5G-communication and cloud-computing are elucidated.

* Title and MeSH Headings from MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine.