Affiliations 

  • 1 Department of Chemistry, BITS, Pilani - K. K. Birla Goa Campus, Goa 403 726, India
  • 2 Centre for Organic and Medicinal Chemistry, School of Advanced Sciences, VIT University, Vellore 632 014, India
  • 3 Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia ; Chemistry Department, Faculty of Science, King Abdulaziz University, PO Box 80203 Jeddah, Saudi Arabia
  • 4 Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia
PMID: 24427050 DOI: 10.1107/S1600536813022022

Abstract

In the title ethanol solvate, C29H20Cl2N2O·C2H5OH, the quinolinyl residues form a dihedral angle of 46.41 (4)° with each other, and each is inclined [Cp-C-C=O and C=C-C-Cp (p = pyridyl) torsion angles = 54.8 (2) and 144.44 (19)°, respectively] with respect to the almost planar bridging prop-2-en-1-one residue [O=C-C=C torsion angle = -4.1 (3)°]. The ethanol solvent mol-ecule is disordered over two positions of equal occupancy and is located close to a centre of inversion. These mol-ecules reside in cavities defined by the organic mol-ecules, which are connected into a three-dimensional architecture by C-H⋯Cl, C-H⋯O and C-H⋯N inter-actions, as well as π-π contacts [inter-centroid distances = 3.5853 (10) and 3.8268 (11) Å], each involving pyridyl rings.

* Title and MeSH Headings from MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine.