Affiliations 

  • 1 Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia
Acta Crystallogr Sect E Struct Rep Online, 2011 Aug 1;67(Pt 8):m1044-5.
PMID: 22090835 DOI: 10.1107/S1600536811026493

Abstract

In the title compound, [Mn(C(14)H(19)N(2)O(2))(2)Cl(H(2)O)]·H(2)O, the Mn(III) atom is N,O-chelated by two monoanionic Schiff bases, forming two six-membered chelate rings. One Cl atom and one water mol-ecule in trans positions complete a distorted octa-hedral geometry around the metal atom. In the crystal, the complex mol-ecules and the uncoordinated water mol-ecules are connected via O-H⋯N, O-H⋯O and O-H⋯Cl hydrogen bonds into layers parallel to the ac plane and these are consolidated by C-H⋯π inter-actions. The layers are further linked into a three-dimensional network through C-H⋯O inter-actions.

* Title and MeSH Headings from MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine.