Affiliations 

  • 1 Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia
Acta Crystallogr Sect E Struct Rep Online, 2009 Apr 30;65(Pt 5):m593.
PMID: 21583815 DOI: 10.1107/S1600536809015128

Abstract

The title stannoxane is a toluene-solvated dimer, [Sn(4)(C(7)H(6)Cl)(8)Cl(2)O(2)(OH)(2)]·C(7)H(8), the tetra-nuclear mol-ecule lying across a center of inversion. The Sn(4)O(4) framework, whose two independent Sn atoms show trigonal bipyramidal coordination, is essentially planar (r.m.s deviation = 0.02 Å). One of the two chloro-benzyl groups of the chloridodiorganyltin unit is disordered over two positions with the chloro-phenyl residue refined over two positions in a 50:50 ratio. The solvent mol-ecule is disordered about a twofold axis.

* Title and MeSH Headings from MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine.