Affiliations 

  • 1 Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia
PMID: 21202251 DOI: 10.1107/S1600536808011045

Abstract

In the crystal structure of the title compound, [Fe(C(6)H(4)NO(2))(2)](n), one nicotinate group O,O'-chelates one Fe atom and binds through the N atom to the other Fe atom; the second nicotinate group bridges three Fe atoms through the N and two O atoms. The μ(2)- and μ(3)-bridging modes of the two nicotinate groups result in a polymeric three-dimensional network structure. The Fe atom shows octa-hedral coordination geometry but one of the Fe-O bonds is somewhat long [2.522 (2) Å].

* Title and MeSH Headings from MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine.