Affiliations 

  • 1 Department of Chemistry, Shiga University of Medical Science, Seta, Otsu, Shiga 520-2192, Japan. Electronic address: mitue@belle.shiga-med.ac.jp
  • 2 Laboratoire de Chimie Moléculaire et Environnement, CISM, Université de Savoie Mont-Blanc, 73376 Le Bourget du Lac cedex, France; Department of Fundamental and Applied Sciences, Universiti Teknologi PETRONAS, Bandar Seri Iskandar, 32610 Tronoh, Perak, Malaysia
  • 3 Department of Chemistry, Shiga University of Medical Science, Seta, Otsu, Shiga 520-2192, Japan
Ultrason Sonochem, 2015 Nov;27:247-51.
PMID: 26186842 DOI: 10.1016/j.ultsonch.2015.04.030

Abstract

A novel, mild "sono-halogenation" of various aromatic compounds with potassium halide was investigated under ultrasound in a biphasic carbon tetrachloride/water medium. The feasibility study was first undertaken with the potassium bromide and then extended to chloride and iodide analogues. This methodology could be considered as a new expansion of the ultrasonic advanced oxidation processes (UAOPs) into a synthetic aspect as the developed methodology is linked to the sonolytic disappearance of carbon tetrachloride. Advantages of the present method are not only that the manipulation of the bromination is simple and green, but also that the halogenating agents used are readily available, inexpensive, and easy-handling.

* Title and MeSH Headings from MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine.