Affiliations 

  • 1 Institute of Materials Research and Engineering, Agency for Science, Technology and Research, 3 Research Link, Singapore 117602 (Singapore)
  • 2 College of Chemistry, Chemical Engineering and Materials Science Soochow University, Suzhou 215123 (P. R. China)
Chempluschem, 2015 Aug;80(8):1231-1234.
PMID: 31973310 DOI: 10.1002/cplu.201500134

Abstract

Pyridinemethanol-carboxylate esters form octahedral complexes with Zn(NO3 )2 in aqueous DMF that subsequently undergo hydrolysis at elevated temperatures to form metal-carboxylate zwitterions. In situ deprotonation of the hydroxy group leads to thermally robust, neutral MOFs. This stepwise synthesis can be controlled by temperature and is made possible by the subtle difference in reactivity of the functional groups.

* Title and MeSH Headings from MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine.