Ni-doped cobalt aluminate NixCo1-xAl2O4 (x = 0.0, 0.2, 0.4, 0.6, 0.8 and 1.0) spinel nanoparticles were successfully synthesized by a simple microwave combustion method using urea as the fuel and as well as reducing agent. X-ray powder diffraction (XRD) was confirmed the formation of single phase, cubic spinel cobalt-nickel aluminate structure without any other impurities. Average crystallite sizes of the samples were found to be in the range of 18.93 nm to 21.47 nm by Scherrer's formula. Fourier transform infrared (FT-IR) spectral analysis was confirmed the corresponding functional groups of the M-O, Al-O and M-Al-O (M = Co and Ni) bonds of spinel NixCo1-xAl2O4 structure. Scanning electron microscope (SEM) and transmission electron microscope (TEM) images was confirmed the particle like nanostructured morphology. Energy band gap (Eg) value was calculated using UV-Visible diffuse reflectance spectra (DRS) and the Eg values increased with increasing Ni2+ dopant from x = 0.2 (3.58 eV) to x = 1.0 (4.15 eV). Vibrating sample magnetometer (VSM) measurements exposed that undoped and Ni-doped CoAl2O4 samples have superparamagnetic behavior and the magnetization (Ms) values were increased with increasing Ni2+ ions. Spinel NixCo1-xAl2O4 samples has been used for the catalytic oxidation of benzyl alcohol into benzaldehyde and was found that the sample Ni0.6Co0.4Al2O4 showed higher conversion 94.37% with 100% selectivity than other samples, which may be due to the smaller particle size and higher surface area.
Undoped and Mn2+ doped CoAl2O4 (MnxCo1-xAl2O4; x = 0.0 to 1.0) spinel nanoparticles were successfully synthesized by a microwave heating method using glycine as the fuel. X-ray powder diffraction (XRD) was confirmed the cubic spinel structure. The average crystallite size of the samples was found to be in the range of 16.46 nm to 20.25 nm calculated by Scherrer's formula. The nano-sized particle-like morphology of the samples was confirmed by high resolution scanning electron microscopy (HR-SEM) and transmission electron microscopy (HR-TEM) analysis. Energy dispersive X-ray (EDX) results showed the pure form of spinel aluminate structure. The band gap energy (Eg) of pure CoAl2O4 was estimated to be 3.68 eV from UV-Visible diffuse reflectance spectroscopy (DRS), and the Eg values increased with increase of Mn2+ ions, due to the smaller grain size. The magnetic hysteresis (M-H) loop showed the superparamagnetic nature, and the magnetization and coercivity values increased with increasing Mn2+ ions, which was confirmed by vibrating sample magnetometer (VSM). All compositions of the nano-catalysts were tested as catalyst successfully for the conversion of benzyl alcohol into benzaldehyde and observed good catalytic activity.
The ever-rising environmental problems because of heavy metals emerging from anthropogenic activities pose an impending threat to all biota globally. Considering their persistence and possibility in biomagnification, they are prominent among pollutants. There has been an apparent shift of research interest in advancing cost-effective and competent technologies to mitigate environmental contaminants, specifically heavy metals. In the recent two decades, tailored nanomaterials (NMs), nanoparticles, and NM-based adsorbents have been emerging for removing heavy metal pollution on a sustainable scale, especially the green synthesis of these nanoproducts effective and nonhazardous means. Hence, this review explores the various avenues in nanotechnology, an attempt to gauge nanotechnological approaches to mitigate heavy metals in the aqueous system, especially emphasizing the recent trends and advancements. Inputs on remediating heavy metal in sustainable and environmentally benign aspects recommended future directions to compensate for the voids in this domain have been addressed.
Microalgae have been publicized for their diversified dominance responsiveness and bioaccumulation potential toward pollutants in an ecosystem. Also, algal's incredible capability as biocatalysts in environmental appliances has been well elucidated owing to their robustness and simple nutritional demand. Additionally, microalgae can deliver various collections of bio-based chemical compounds helpful for diversified applications, especially as green alternatives. The environment has been contaminated with various polluting agents; one principal polluting agent is heavy metals which are carcinogenic and show toxicity even in minimal quantity, cause unsatisfactory threats to the environmental ecosystem, including human and animal health. There is a prominent tendency to apply microalgae in the phytoremediation of heavy metals compounds because of its vast benefits, including great accessibility, cost-effective, excellent toxic metal eliminating efficiency, and nontoxic to the ecosystem. This review uncovers the most recent advancements and mechanisms associated with the bioremediation process and biosorption interaction of substantial harmful synthetic compounds processing microalgae species. Furthermore, future challenges and prospects in the utilization of microalgae in heavy metals bioremediation are also explored. The current review aims to give valuable information to aid the advancement of robust and proficient future microalgae-based heavy metal bioremediation innovations and summarizing a wide range of benefits socioeconomic scope to be employed in heavy metal compound removal in environment system.