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  1. Solangi NH, Karri RR, Mubarak NM, Mazari SA, Sharma BP
    Nanoscale, 2024 Nov 28;16(46):21216-21263.
    PMID: 39470605 DOI: 10.1039/d4nr03008g
    Essential biosensor use has become increasingly important in drug discovery and recognition, biomedicine, food safety, security, and environmental research. It directly contributed to the development of specialized, reliable diagnostic instruments known as biosensors, which use biological sensing components. Traditional biosensors have poor performance, so scientists need to develop advanced biosensors with promising selectivity, sensitivity, stability, and reusability. These are all parameter modifications associated with the characteristics of the sensing material. Carbon nanotubes (CNTs) and MXenes are promising as targeted sensing agents in advanced functional materials because of their promising chemical and physical properties and limited toxic effects. Based on available data and sensing performance, MXene is better for biosensing applications than CNTs. Because of their large specific surface area (SSA), superior electrical conductivity, and adaptable surface chemistry that facilitates simple functionalization and robust interactions with biomolecules, MXenes are typically regarded as the superior option for biosensors. Additionally, because of their hydrophilic nature, they are more suited to biological settings, which increases their sensitivity and efficacy in identifying biological targets. MXenes are more suitable for biosensing applications due to their versatility and compatibility with aquatic environments, even if CNTs have demonstrated stability and muscular mechanical strength. However, MXenes offer better thermal stability, which is crucial for applications in diverse temperature environments. This study reviews and compares the biosensing capabilities, synthesis methods, unique properties, and toxicity of CNTs and MXenes. Both nanomaterials effectively detect various pollutants in food, biological substances, and human bodies, making them invaluable in environmental monitoring and medical diagnostics. In conclusion, CNTs work better for biosensors that must be strong, flexible, and long-lasting under different conditions. MXenes, on the other hand, work better when chemical flexibility and compatibility with wet environments are essential.
  2. Jatoi AS, Mubarak NM, Hashmi Z, Solangi NH, Karri RR, Hua TY, et al.
    Chemosphere, 2023 Feb;313:137497.
    PMID: 36493892 DOI: 10.1016/j.chemosphere.2022.137497
    Multiple ecological contaminants in gaseous, liquid, and solid forms are vented into ecosystems due to the huge growth of industrialization, which is today at the forefront of worldwide attention. High-efficiency removal of these environmental pollutants is a must because of the potential harm to public health and biodiversity. The alarming concern has led to the synthesis of improved nanomaterials for removing pollutants. A path to innovative methods for identifying and preventing several obnoxious, hazardous contaminants from entering the environment is grabbing attention. Various applications in diverse industries are seen as a potential directions for researchers. MXene is a new, excellent, and advanced material that has received greater importance related to the environmental application. Due to its unique physicochemical and mechanical properties, high specific surface area, physiological compatibility, strong electrodynamics, and raised specific surface area wettability, its applications are growing. This review paper examines the most recent methods and trends for environmental pollutant removal using advanced 2D Mxene materials. In addition, the history and the development of MXene synthesis were elaborated. Furthermore, an extreme summary of various environmental pollutants removal has been discussed, and the future challenges along with their future perspectives have been illustrated.
  3. Raheem I, Mubarak NM, Karri RR, Solangi NH, Jatoi AS, Mazari SA, et al.
    Chemosphere, 2023 Jan;311(Pt 2):137056.
    PMID: 36332734 DOI: 10.1016/j.chemosphere.2022.137056
    Water consumption has grown in recent years due to rising urbanization and industry. As a result, global water stocks are steadily depleting. As a result, it is critical to seek strategies for removing harmful elements from wastewater once it has been cleaned. In recent years, many studies have been conducted to develop new materials and innovative pathways for water purification and environmental remediation. Due to low energy consumption, low operating cost, and integrated facilities, membrane separation has gained significant attention as a potential technique for water treatment. In these directions, MXene which is the advanced 2D material has been explored and many applications were reported. However, research on MXene-based membranes is still in its early stages and reported applications are scatter. This review provides a broad overview of MXenes and their perspectives, including their synthesis, surface chemistry, interlayer tuning, membrane construction, and uses for water purification. Application of MXene based membrane for extracting pollutants such as heavy metals, organic contaminants, and radionuclides from the aqueous water bodies were briefly discussed. Furthermore, the performance of MXene-based separation membranes is compared to that of other nano-based membranes, and outcomes are very promising. In order to shed more light on the advancement of MXene-based membranes and their operational separation applications, significant advances in the fabrication of MXene-based membranes is also encapsulated. Finally, future prospects of MXene-based materials for diverse applications were discussed.
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