It is known that carbon nanotubes show desirable physical and chemical properties with a wide array of potential applications. Nonetheless, their potential has been hampered by the difficulties in acquiring high purity, chiral-specific tubes. Considerable advancement has been made in terms of the purification of carbon nanotubes, for instance chemical oxidation, physical separation, and myriad combinations of physical and chemical methods. The aqueous two-phase separation technique has recently been demonstrated to be able to sort carbon nanotubes based on their chirality. The technique requires low cost polymers and salt, and is able to sort the tubes based on their diameter as well as metallicity. In this review, we aim to provide a review that could stimulate innovative thought on the progress of a carbon nanotubes sorting method using the aqueous two-phase separation method, and present possible future work and an outlook that could enhance the methodology.
ZrO2 nanotubes (ZrNTs) were produced by anodisation of zirconium foil in H2O2/NH4F/ethylene glycol electrolyte. The as-anodised foils were then soaked in the anodising electrolyte for 12 h. Soaking weakens the adherence of the anodic layer from the substrate resulting in freestanding ZrNTs (FS-ZrNTs). Moreover, the presence of H2O2 in the electrolyte also aids in weakening the adhesion of the film from the foil, as foil anodised in electrolyte without H2O2 has good film adherence. The as-anodised FS-ZrNTs film was amorphous and crystallised to predominantly tetragonal phase upon annealing at >300 °C. Annealing must, however, be done at <500 °C to avoid monoclinic ZrO2 formation and nanotubes disintegration. FS-ZrNTs annealed at 450 °C exhibited the highest photocatalytic ability to degrade methyl orange (MO), whereby 82% MO degradation was observed after 5 h, whereas FS-ZrNTs with a mixture of monoclinic and tetragonal degraded 70% of MO after 5 h.
An ethanol gas sensor with enhanced sensor response was fabricated using Ni-doped SnO2 nanorods, synthesized via a simple hydrothermal method. It was found that the response (R = R 0/R g) of a 5.0 mol% Ni-doped SnO2 (5.0Ni:SnO2) nanorod sensor was 1.4 × 104 for 1000 ppm C2H5OH gas, which is about 13 times higher than that of pure SnO2 nanorods, (1.1 × 103) at the operating temperature of 450 °C. Moreover, for 50 ppm C2H5OH gas, the 5.0Ni:SnO2 nanorod sensor still recorded a significant response reading, namely 2.0 × 103 with a response time of 30 s and recovery time of 10 min. To investigate the effect of Ni dopant (0.5-5.0 mol%) on SnO2 nanorods, structural characterizations were demonstrated using field emission scanning electron microscopy, high-resolution transmission electron microscopy, Fourier transform infrared spectroscopy, x-ray diffraction (XRD) analysis, x-ray photoelectron spectroscopy and an ultraviolet-visible spectrometer. XRD results confirmed that all the samples consisted of tetragonal-shaped rutile SnO2 nanorods. It was found that the average diameter and length of the nanorods formed in 5.0Ni:SnO2 were four times smaller (∼6 and ∼35 nm, respectively) than those of the nanorods formed in pure SnO2 (∼25 and 150 nm). Interestingly, both samples had the same aspect ratio, ∼6. It is proposed that the high response of the 5.0Ni:SnO2 nanorod sensor can be attributed to the particle size, which causes an increase in the thickness of the charge depletion layer, and the presence of oxygen vacancies within the matrix of SnO2 nanorods.
Visible-light-active freestanding zirconia (ZrO2) nanotube (FSZNT) arrays were fabricated by a facile electrochemical anodization method in fluoride containing ethylene glycol electrolyte added to it was 1 vol% of potassium carbonate (K2CO3) at 60 V for 1 h. Poor adhesion at the metal∣oxide interface was induced by K2CO3 leading to the formation of FSZNT flakes. The effect of the crystal structures of the FSZNTs e.g., amorphous, amorphous/tetragonal, and tetragonal/monoclinic was investigated towards the photocatalytic reduction of 10 ppm hexavalent chromium, Cr(VI) at pH 2 under sunlight. The results demonstrate the amorphous FSZNTs exhibited the highest Cr(VI) removal efficiency than the crystalline FSZNTs (95% versus 33% after 5 h). The high photocatalytic activity of the amorphous FSZNTs can be attributed to enhanced Cr(VI) adsorption, high visible light absorption, and better charge carrier separation. The low photocatalytic activity of the crystalline FSZNTs annealed at 500 °C was mainly attributed to poor Cr(VI) adsorption, low visible light absorption, and less photoactive monoclinic-ZrO2.
A graphene nanoplatelet (GNP) coating is utilized as a functionalized surface in enhancing the evaporation rate of micro-spray cooling for light-emitting diodes (LEDs). In micro-spray cooling, water is atomized into micro-sized droplets to reduce the surface energy and to increase the surface area for evaporation. The GNP coating facilitates the effective filmwise evaporation through the attribute of fast water permeation. The oxygenated functional groups of GNPs provide the driving force that initiates the intercalation of water molecules through the carbon nanostructure. The water molecules slip through the frictionless passages between the hydrophobic carbon walls, resulting an effective filmwise evaporation. The enhancement of evaporation leads to an enormous temperature reduction of 61.3 °C. The performance of the LED is greatly enhanced: a maximum increase in illuminance of 25% and an extension of power rating from 9 W to 12 W can be achieved. With the application of GNP coating, the high-temperature region is eliminated while maintaining the LED surface temperature for optimal operation. This study paves the way for employing the effective hybrid spray-evaporation-nanostructure technique in the development of a compact, low-power-consumption cooling system.
Supercapacitors, based on fast ion transportation, are among the most promising energy storage solutions that can deliver fast charging-discharging within seconds and exhibit excellent cycling stability. The development of a good electrode material is one of the key factors in enhancing supercapacitor performance. Graphene (G), an allotrope of carbon that consists of a single layer of carbon atoms arranged in a hexagonal lattice, elicits research attention among scientists in the field of energy storage due to its remarkable properties, such as outstanding electrical conductivity, good chemical stability, and excellent mechanical behavior. Furthermore, numerous studies focus on 2D materials that are analogous to graphene as electrode supercapacitors, including transition metal dichalcogenides (TMDs). Recently, scientists and researchers are exploring TMDs because of the distinct features that make 2D TMDs highly attractive for capacitive energy storage. This study provides an overview of the structure, properties, synthesis methods, and electrochemical performance of G/TMD supercapacitors. Furthermore, the combination of G and TMDs to develop a hybrid structure may increase their energy density by introducing an asymmetric supercapacitor system. We will also discuss the future prospect of this system in the energy field.
Anodic aluminium oxide (AAO) is a self-organised nanopore that has been widely studied due to the ease of its synthesization and pore properties manipulation. However, pore growth behaviour under different geometrical surfaces is rarely studied, particularly on the effect of combined curved surfaces towards pore growth properties, which is crucial in designing unique porous platform for specific applications. This paper reports study on the decisive effect of curvature surfaces on development of pore structure and properties at a constant potential. In this work, AAO grown on treated convex and concave surfaces were analysed in terms of pore quantity, pore diameter, interpore distance, pore length and other parameters of pore bottom geometry in conjugation with observation of pore cessation, bifurcation, bending and tapering. The unique formation of tapered pore was observed and described. Major factors deciding pore properties under curved surfaces were identified and discussed. We introduced a new parameter for surface quantification known as central inscribed angle, which was identified to be the central factor which decides pore growth behaviour under a curvature. Here, we observed a different trend in growth rate of pores under different curvatures, which oppose the commonly accepted convex > planar > concave pattern. Levelling height was later identified to be the decisive factor in determining growth rate of pores under a curvature at different geometrical location. These findings open up possibility to precisely control and tailor the growing path and pore structures of AAO simply via anodising an Al sheet under combined curvature surfaces, which could be beneficial for future novel applications.
High porous ZnO nanoflakes were successfully prepared using microwave assisted hydrothermal method. The presence of aluminum changes the environment of preparation reaction which controlled the crystallographic orientation. The unique morphology and properties of ZnO nanoflakes may due to the effect of microwave irradiation and the ambient condition. The approach is very simple and rapid that grows around 3 μm ZnO within 30 minutes. The mechanism of the construction of unique ZnO nanoflakes growth using the present approach will be proposed. Hence, the prospective performance of ethanol vapor sensing for the rapid growth of ZnO porous nanostructures was investigated.
In this research work, nanowires were grown on brass (Cu - 37.2 wt% Zn) substrate by thermal oxidation process. The substrate was oxidized at temperature ranging from 350-600 °C in the presence of varying concentrations of O2 in N2 (1-100%) flown at a rate of 200 sccm. The oxidized brass surface was characterized by field emission scanning electron microscope (FESEM) equipped with energy dispersive X-ray (EDX) spectroscope and transmission electron microscope (TEM). Four different types of morphological variations such as thin, thick with branches, circular-flake and flat-cone shape were observed during oxidation at different conditions. However, the prevalence of thin, thick morphology with branches was more prominent and found in all growth conditions. The length and diameter of the nanowires were varied from 1-30 µm and 50-500 nm, respectively whereas the length of the branches varied from 1-3 µm. The composition of the nanowires was ZnO possessing of hexagonal wurtzite structure. The selected area diffraction confirms that the nanowires grew along <1 1 0> directions. Based on the results, a stress induced based mechanism is proposed for the growth of ZnO nanowires on Cu - 37.2 wt% Zn substrate.
To synthesize lithium ferrite with various Gd concentrations (Li0.5Fe2.5-xGdxO4), x = 0.00, 0.025, 0.05, 0.075, 0.1, solutes were dissolved in glycol, i.e. by using the without water and surfactant (WOWS) sol-gel method. X-ray diffraction (XRD) analysis confirmed that the material possessed an inverse spinel cubic structure and is single phase. Pellets of all samples were sintered at 700 °C and XRD confirmed that samples were crystalline, phase pure and had an inverse spinel cubic lattice. Scanning electron microscopy indicated that the grains were agglomerated and had a predominantly spherical shape. It is concluded that Gd acts as a grain refiner in lithium ferrite up to a Gd concentration of 0.05. AC conductivity and dielectric constant increased by increasing Gd concentration. The Maxwell-Wagner model and Johnsher's power law were used to explain the dielectric properties. DC conductivity was measured from 100 to 600 °C. DC conductivity was explained by the hopping mechanism. It is concluded that DC resistivity and dielectric constant values are related reciprocally in the prepared sample. AC electrical properties were also measured at a constant frequency of 1 MHz in the temperature range from 400 to 600 °C. Gd-substituted lithium ferrite showed high AC conductivity, high DC resistivity and constant dielectric values, but low dielectric loss values as compared to pure lithium ferrite.
Multi-walled carbon nanotubes (MWCNTs) are a contemporary class of nanoparticles that have a prominent thermal, electrical and mechanical properties. There have been numerous studies on the enhancement of thermophysical properties of nanofluids. However, there is only limited research on thermal and stability analysis of MWCNT nanofluids with various kinds of solvents or base fluids, namely propylene glycol, ethanol, ethylene glycol, polyethylene glycol, methanol and water. This paper reports the enhancement of thermophysical properties and stability of MWCNTs with six different base fluids in the presence of sodium dodecyl benzene sulfonate surfactant with a mass concentration of 0.5 wt%. Thermal and dispersion stabilities were determined using a thermogravimetric analyzer (TGA) and Zeta potential, along with a visual inspection method to evaluate the agglomeration or sedimentation of MWCNT nanoparticles over a period of one month. Ultraviolet-visible spectroscopy and Fourier transform infrared spectroscopy were utilized to identify the molecular components and light absorption of the formulated nanofluids at their maximum wavenumber (4500 cm-1) and wavelength (800 nm). In addition, thermophysical properties such as thermal conductivity, specific heat capacity, viscosity and density with a peak temperature of 200 °C were also experimentally evaluated. The TGA results illustrated that MWCNT/ethylene glycol nanofluid achieved maximum thermal stability at 140 °C and it revealed a maximum zeta potential value of -61.8 mV. Thus, ethylene glycol solution was found to be the best base liquid to homogenize with MWCNTs for acquiring an enhanced thermophysical property and a long-term stability.
Precision temperature measurement of a nano system with high sensitivity and fast response is still a challenge. The marvelous thermal and mechanical properties of graphite will allow the creation of superior nanoscale temperature sensors. In-situ x-ray diffraction was employed to determine the graphite hexagonal crystal lattice dimensions and the coefficient of thermal expansion based on the calculation of its interatomic distance. The energy of graphite was mapped over the first Brillouin zone in the temperature range of 50 °C-1200 °C at intervals of 50 °C. Energy-based comparative studies between the quantum free electron approach obtained by an inelastic scattering and an harmonic oscillator are introduced by the principal quantum number associated with the excitation level. The hexagonal lattice constants, interlayer distance and interatomic distance of graphite crystals are investigated analytically with consideration given to their temperature dependence and the carbon peak (002), where the 2θ value decreases slightly with increasing temperature. The coefficient of thermal expansion of graphite-based interatomic distance is negative and tends toward zero with increasing temperature, which is in very good agreement with experiments. Moreover, the energy probability distributions enclosed by reciprocal lattice vectors of the hexagonal lattice are defined and interpreted based on lattice dimensions with varying temperature. Linear changes of the temperature-driven unit cell lattice dimensions and analysis of the kinetic energy of the electron in graphite may both be utilised for the advanced temperature interpretation model and preliminary design of a precise nanothermometer.
Vertically standing MoS2 nanoflakes are favourable in applications such as energy storage devices, hydrogen evolution reactions, and gas sensors due to their large surface area and high density of exposed edges. In this work, we report the effect of Mo vapor concentration on the morphology of vertical MoS2 nanoflakes prepared by chemical vapor deposition at atmospheric pressure. A series of MoS2 samples were grown under different Mo vapor concentrations by varying the separation distance (x) between the MoO3 source and the substrate. Field emission scanning electron microscopy showed the sample grown at x = 1 cm had a high density of vertical flakes (7 vertical flakes µm-2) with an average flake length of ~770 nm and thickness of ~10 nm. As x increased to 4 cm, the average flake length was reduced to ~150 nm while the flake orientation changed from vertical to lateral. That is, high Mo vapor concentration favours the formation of large and vertical MoS2 nanoflakes. However, oversupply of Mo vapor results in significantly thicker flakes. Raman spectra of all samples showed two main peaks at 380 and 407 cm-1 that correspond to the E12g and A1g vibrational peaks of MoS2. As x decreased from 4 to 1, the peak intensity ratio (E12g/A1g) reduced from 0.58 to 0.42, suggesting greater dominance of vertical flakes at low x. X-ray diffraction data showed a prominent peak at 14.4°, which corresponded to the (002) diffraction peak of 2H MoS2. Transmission electron microscopy verified the flakes consist of eight layers with an interlayer spacing of 0.62 nm. Based on hydrogen evolution reaction measurements, samples with thin flakes have high catalytic activity. This work highlights the importance of optimizing Mo vapor concentration to obtain a high density of thin, large, and vertically standing MoS2 nanoflakes.
The present study aims at engineering, fabrication, characterization, and qualifications of papain (PPN) conjugated SiO2-coated iron oxide nanoparticles 'IONPs@SiO2-PPN'. Initially fabricated iron oxide nanoparticles (IONPs) were coated with silica (SiO2) using sol-gel method to hinder the aggregation and to enhance biocompatibility. Next, PPN was loaded as an anticancer agent into the silica coated IONPs (IONPs@SiO2) for the delivery of papain to the HeLa cancer cells. This fabricated silica-coated based magnetic nanoparticle is introduced as a new physiologically-compatible and stable drug delivery vehicle for delivering of PPN to the HeLa cancer cell line. The IONPs@SiO2-PPN were characterized using FT-IR, AAS, FESEM, XRD, DLS, and VSM equipment. Silica was amended on the surface of iron oxide nanoparticles (IONPs, γ-Fe2O3) to modify its biocompatibility and stability. The solvent evaporation method was used to activate PPN vectorization. The following tests were performed to highlight the compatibility of our proposed delivery vehicle: in vitro toxicity assay, in vivo acute systemic toxicity test, and the histology examination. The results demonstrated that IONPs@SiO2-PPN successfully reduced the IC50 values compared with the native PPN. Also, the structural alternations of HeLa cells exposed to IONPs@SiO2-PPN exhibited higher typical hallmarks of apoptosis compared to the cells treated with the native PPN. The in vivo acute toxicity test indicated no clinical signs of distress/discomfort or weight loss in Balb/C mice a week after the intravenous injection of IONPs@SiO2 (10 mg kg-1). Besides, the tissues architectures were not affected and the pathological inflammatory alternations detection failed. In conclusion, IONPs@SiO2-PPN can be chosen as a potent candidate for further medical applications in the future, for instance as a drug delivery vehicle or hyperthermia agent.
The ultrafast water transport in graphene nanoplatelets (GNPs) coating is attributed to the low friction passages formed by pristine graphene and the hydrophilic functional groups which provide a strong interaction force to the water molecules. Here, we examine the influence of the supporting substrate on the ultrafast water transport property of multilayer graphene coatings experimentally and by computational modelling. Thermally cured GNPs manifesting ultrafast water permeation are coated on different substrate materials, namely aluminium, copper, iron and glass. The physical and chemical structures of the GNPs coatings which are affected by the substrate materials are characterized using various spectroscopy techniques. Experimentally, the water permeation and absorption tests evidence the significant influence of the substrate on the rapid water permeation property of GNPs-coating. The water transport rates of the GNPs coatings correspond to the wettability and the free surface energy of their substrates where the most hydrophilic substrate induces the highest water transport rate. In addition, we conduct molecular dynamics (MD) simulations to investigate the transport rate of water molecules through multilayer GNPs adjacent to different substrate materials. The MD simulations results agree well with the experimental results inferring the strong influence of the substrate materials on the fast water transport of GNPs. Therefore, selection of substrate has to be taken into consideration when the GNPs-coating is placed into applications.
Upconversion (UC) of lanthanide-doped nanostructure has the unique ability to convert low energy infrared (IR) light to high energy photons, which has significant potential for energy conversion applications. This review concisely discusses the basic concepts and fundamental theories of lanthanide nanostructures, synthesis techniques, and enhancement methods of upconversion for photovoltaic and for near-infrared (NIR) photodetector (PD) application. In addition, a few examples of lanthanide-doped nanostructures with improved performance were discussed, with particular emphasis on upconversion emission enhancement using coupling plasmon. The use of UC materials has been shown to significantly improve the NIR light-harvesting properties of photovoltaic devices and photocatalytic materials. However, the inefficiency of UC emission also prompted the need for additional modification of the optical properties of UC material. This improvement entailed the proper selection of the host matrix and optimization of the sensitizer and activator concentrations, followed by subjecting the UC material to surface-passivation, plasmonic enhancement, or doping. As expected, improving the optical properties of UC materials can lead to enhanced efficiency of PDs and photovoltaic devices.
Metal sulfides are promising anode materials for lithium ion batteries because of the high specific capacities and better electrochemical kinetics comparing to their oxide counterparts. In this paper, novel monocrystalline wurtzite ZnS@N-doped carbon (ZnS@N-C) nanoplates, whose morphology and phase are different from the common ZnS particles with cubic phase, are successfully synthesized. The ZnS@N-C nanoplates exhibit long cycle life with a high reversible specific capacity of 536.8 mAh · g-1after 500 cycles at a current density of 500 mA · g-1, which is superior to the pure ZnS nanoplates, illustrating the obvious effect of the N-doped carbon coating for mitigating volume change of the ZnS nanoplates and enhancing the electronic conductivity during charge/discharge processes. Furthermore, it is revealed that the ZnS single crystals with wurtzite phase in the ZnS@N-C nanoplates are transformed to the polycrystalline cubic phase ZnS after charge/discharge processes. In particular, the ZnS@N-C nanoplates are combined with the commercial LiNi0.6Co0.2Mn0.2O2cathode to fabricate a new type of LiNi0.6Co0.2Mn0.2O2/ZnS@N-C complete battery, which exhibits good cycling durability up to 120 cycles at a charge/discharge rate of 1 C after the prelithiation treatment on the ZnS@N-C anode, highlighting the potential of the ZnS@N-C nanoplates anode material applied in lithium ion battery.
Main limitation of conventional antibiotic therapies concerns the low efficacy to bacteria attacks for long treatment times. In this context, the integrated use of electrofluidodynamics (EFDs) - basically electrospinning and electrospraying - may represent an interesting route to design nanostructured platforms with controlled release to prevent the formation of bacterial biofilms in oral implant sites. They allow for the deposition of nanofibres and nanoparticles by different modes - i.e., sequential, simultaneous - for the fabrication of more efficacious systems in terms of degradation protection, pharmacokinetic control and drug distribution to the surrounding tissues. Herein, we will investigate EFDs processing modes and conditions to decorate polycaprolactone (PCL) nanofibres surfaces by chitosan (CS) nano-reservoirs for the administration of Amoxicillin Trihydrate (AMX-DHT) as innovative antibacterial treatment of the periodontal pocket.
The estimation of nanoparticle number concentration in colloidal suspensions is a prerequisite in many procedures, and in particular in multi-stage, low-yield reactions. Here, we describe a rapid, non-destructive method based on optical extinction and dynamic light scattering, which combines measurements using common bench-top instrumentation with a numerical algorithm to calculate the particle size distribution and concentration. These quantities were derived from Mie theory applied to measurements of the optical extinction spectrum of homogeneous, non-absorbing nanoparticles, and the relative particle size distribution of a colloidal suspension. The work presents an approach to account for particle size distributions achieved by dynamic light scattering which, due to the underlying model, may not be representative of the true sample particle size distribution. The presented approach estimates the absolute particle number concentration of samples with mono-, bi-modal and broad size distributions with <50% precision. This provides a convenient and practical solution for number concentration estimation required during many applications of colloidal nanomaterials.
Self-organized, 23 μm-thick anodic TiO2 nanotube (TNT) arrays were formed in sodium hydroxide/fluoride/ethylene glycol (EG) electrolyte at 60 V for 60 min. The presence of sodium hydroxide (NaOH) in the fluoride/EG electrolyte accelerates the formation of the TiO2 nanotube arrays. The anodic film was then decorated with silver nanoparticles (Ag NPs) by the photodeposition process and used as a photoanode in a rear-side-illuminated dye-sensitized solar cell. The Ag NPs decorated TNT arrays, with the former having diameters of 10-30 nm formed from 0.2 M of Ag-precursor solution and exhibiting the highest photoconversion efficiency (η) of 3.7% and a short-circuit current density of 12.2 mA cm(-2) compared to η = 3% and short-circuit current density of 9.1 mA cm(-2) for a sample without Ag NPs. The increase in η is thought to be due to the surface plasmon resonance and excess electrons from the nanoparticles.