In this study, the use of nano-silica (nano-SiO2) and bentonite as mortar additives for combating reinforcement corrosion is reported. More specifically, these materials were used as additives in ordinary Portland cement (OPC)/fly ash blended mortars in different amounts. The effects of nano-silica and bentonite addition on compressive strength of mortars at different ages was tested. Accelerated corrosion testing was used to assess the corrosion resistance of reinforced mortar specimens containing different amounts of nano-silica and bentonite. It was found that the specimens containing nano-SiO2 not only had higher compressive strength, but also showed lower steel mass loss due to corrosion compared to reference specimens. However, this was accompanied by a small reduction in workability (for a constant water to binder ratio). Mortar mixtures with 4% of nano-silica were found to have optimal performance in terms of compressive strength and corrosion resistance. Control specimens (OPC/fly ash mortars without any additives) showed low early age strength and low corrosion resistance compared to specimens containing nano-SiO2 and bentonite. In addition, samples from selected mixtures were analyzed using scanning electron microscopy (SEM) and energy-dispersive X-ray spectroscopy (EDX). Finally, the influence of Ca/Si ratio of the calcium silicate hydrate (C-S-H) in different specimens on the compressive strength is discussed. In general, the study showed that the addition of nano-silica (and to a lesser extent bentonite) can result in higher strength and corrosion resistance compared to control specimens. Furthermore, the addition of nano-SiO2 can be used to offset the negative effect of fly ash on early age strength development.
The advent of digital concrete fabrication calls for advancing our understanding of the interaction of 3D printing with material rheology and print parameters, in addition to developing new measurement and control techniques. Thixotropy is the main challenge associated with printable material, which offers high yield strength and low viscosity. The higher the thixotropy, the better the shape stability and the higher buildability. However, exceeding a minimum value of thixotropy can cause high extrusion pressure and poor interface bond strength if the printing parameters are not optimized to the part design. This paper aims to investigate the effects of both material and process parameters on the buildability and inter-layer adhesion properties of 3D printed cementitious materials, produced with different thixotropy and print head standoff distances. Nano particles are used to increase the thixotropy and, in this context, a lower standoff distance is found to be useful for improving the bond strength. The low viscosity "control" sample is unaffected by the variation in standoff distances, which is attributed to its flowability and low yield stress characteristics that lead to strong interfacial bonding. This is supported by our microscopic observations.
This study evaluates the mechanical, durability, and residual compressive strength (after being exposed to 20, 120, 250, 400 and 600 °C) of mortar that uses recycled iron powder (RIP) as a fine aggregate. Within this context, mechanical strength, shrinkage, durability, and residual strength tests were performed on mortar made with seven different percentages (0%, 5%, 10%, 15%, 20%, 30% and 50%) of replacement of natural sand (NS) by RIP. It was found that the mechanical strength of mortar increased when replaced with up to 30% NS by RIP. In addition, the increase was 30% for compressive, 18% for tensile, and 47% for flexural strength at 28 days, respectively, compared to the reference mortar (mortar made with 100% NS). Shrinkage was observed for the mortar made with 100% NS, while both shrinkage and expansion occurred in the mortar made with RIP, especially for RIP higher than 5%. Furthermore, significantly lower porosity and capillary water absorption were observed for mortar made with up to 30% RIP, compared to that made with 100% NS, which decreased by 36% for porosity and 48% for water absorption. As the temperature increased, the strength decreased for all mixes, and the drop was more pronounced for the temperatures above 250 °C and 50% RIP. This study demonstrates that up to 30% RIP can be utilized as a fine aggregate in mortar due to its better mechanical and durability performances.