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  1. Al-Wabli RI, El-Emam AA, Alroqi OS, Chidan Kumar CS, Fun HK
    Acta Crystallogr E Crystallogr Commun, 2015 Feb 1;71(Pt 2):o115-6.
    PMID: 25878859 DOI: 10.1107/S2056989015000596
    The title compound, C18H20ClN3S, is a functionalized triazoline-3-thione derivative. The benzene ring is almost perpendic-ular to the planar 1,2,4-triazole ring [maximum deviation = 0.007 (1) Å] with a dihedral angle of 89.61 (5)° between them and there is an adamantane substituent at the 3-position of the triazole-thione ring. In the crystal, N-H⋯S hydrogen-bonding inter-actions link the mol-ecules into chains extending along the c-axis direction. The crystal packing is further stabilized by weak C-H⋯π inter-actions that link adjacent chains into a two-dimensional structure in the bc plane. The crystal studied was an inversion twin with a 0.50 (3):0.50 (3) domain ratio.
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