Displaying all 3 publications

Abstract:
Sort:
  1. Camargo LR, Zukerman-Schpector J, Deobald AM, Braga AL, Tiekink ER
    Acta Crystallogr E Crystallogr Commun, 2015 Mar 1;71(Pt 3):o200-1.
    PMID: 25844248 DOI: 10.1107/S2056989015003242
    Two independent mol-ecules, A and B, comprise the asymmetric unit of the title compound, C20H21N3OSe. While the benzene ring directly bound to the central triazole ring is inclined to the same extent in both mol-ecules [dihedral angles = 40.41 (12) (mol-ecule A) and 44.14 (12)° (B)], greater differences are apparent in the dihedral angles between the Se-bound rings, i.e. 74.28 (12) (mol-ecule A) and 89.91 (11)° (B). Close intra-molecular Se⋯N inter-actions of 2.9311 (18) (mol-ecule A) and 2.9482 (18) Å (B) are noted. In the crystal, supra-molecular chains along the a axis are formed via O-H⋯N hydrogen bonding. These are connected into layers via C-H⋯O and C-H⋯N inter-actions; these stack along (01-1) without directional inter-molecular inter-actions between them.
  2. Camargo LR, Zukerman-Schpector J, Deobald AM, Braga AL, Tiekink ER
    Acta Crystallogr E Crystallogr Commun, 2015 Mar 01;71(Pt 3):o202-3.
    PMID: 25844249 DOI: 10.1107/S2056989015003230
    In the title compound, C21H17N3OSe, the dihedral angles between the central five-membered ring and the C- and N-bound rings are 17.89 (10) and 42.35 (10)°, respectively, indicating the mol-ecule is twisted. The dihedral angle between the Se-bound rings is 85.36 (10)°. A close intra-molecular Se⋯O contact of 2.8507 (13) Å is noted. In the crystal, C-H⋯O, C-H⋯N and C-H⋯π inter-actions lead to the formation of supra-molecular layers parallel to (011); these stack with no specific inter-molecular inter-actions between them.
  3. Camargo LR, Zukerman-Schpector J, Deobald AM, Braga AL, Tiekink ER
    Acta Crystallogr E Crystallogr Commun, 2015 Mar 01;71(Pt 3):o204-5.
    PMID: 25844250 DOI: 10.1107/S2056989015003229
    In the title compound, C23H21N3Se, the C-bound phenyl ring is almost coplanar with the central five-membered ring [dihedral angle = 2.84 (10)°], but the N-bound benzene ring is inclined [dihedral angle = 47.52 (10)°]. The dihedral angle between the Se-bound rings is 69.24 (9)°. An intra-molecular Se⋯N inter-action of 3.0248 (15) Å is noted. In the crystal, C-H⋯π inter-actions connect mol-ecules into double layers that stack along the a axis with no directional inter-actions between them.
Related Terms
Filters
Contact Us

Please provide feedback to Administrator (afdal@afpm.org.my)

External Links