This research is designed to enhance the physio-chemical properties, constancy, and antioxidant activities of water-in-oil (W/O) emulsions containing chia seed oil (CSO) by utilizing mung bean protein isolate (MBPI)-peach gum (PG) conjugates, which were created through the Maillard reaction (MR), as the emulsifying agents. The emulsions were prepared using MBPI-PG produced through the Maillard reaction (EMRP) at concentrations of 0.5 %, 1 %, and 1.5 %. Another set of emulsions, serving as control samples, was prepared using MBPI-PG without the MR (EC) at the same concentrations. The EMRP samples demonstrated optimum characteristics during storage over 30 days at 25 °C, particularly at 1 % concentration, including the droplet size (176.37 nm), PDI (0.3), zeta potential (-47.52 Mv), quantity of absorbed protein (63.48 %), creaming index (22.99 %), and viscosity compared to EC. The emulsions prepared with MRP exhibited significantly lower POV (1.45 mM/kg oil) and TBARS (59.17 mM/kg oil) formation rates than EC. The EMRP1% formulation displayed the lowest release of antioxidant compounds among all formulations, suggesting low release control during storage. Molecular docking results confirmed that adding EMRP1% to the CSO emulsion significantly improved its quality and stability. This emulsifier could hold significant promise for future advancements in the food industry.