The purpose of the study is to investigate the utilisation of Napier fiber (Pennisetum purpureum) as a source for the fabrication of cellulose nanofibers (CNF). In this study, cellulose nanofibers (CNF) from Napier fiber were isolated via ball-milling assisted by acid hydrolysis. Acid hydrolysis with different molarities (1.0, 3.8 and 5.6 M) was performed efficiently facilitate cellulose fiber size reduction. The resulting CNFs were characterised through Fourier-transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), thermogravimetric analysis (TGA), particle size analyser (PSA), field-emission scanning electron microscopy (FESEM), atomic force microscopy (AFM), and transmission electron microscopy (TEM). The FTIR results demonstrated that there were no obvious changes observed between the spectra of the CNFs with different molarities of acid hydrolysis. With 5.6 M acid hydrolysis, the XRD analysis displayed the highest degree of CNF crystallinity at 70.67%. In a thermal analysis by TGA and DTG, cellulose nanofiber with 5.6 M acid hydrolysis tended to produce cellulose nanofibers with higher thermal stability. As evidenced by the structural morphologies, a fibrous network nanostructure was obtained under TEM and AFM analysis, while a compact structure was observed under FESEM analysis. In conclusion, the isolated CNFs from Napier-derived cellulose are expected to yield potential to be used as a suitable source for nanocomposite production in various applications, including pharmaceutical, food packaging and biomedical fields.
In this paper, the effects of stacking sequence and ply orientation on the mechanical properties of pineapple leaf fibre (PALF)/carbon hybrid laminate composites were investigated. The hybrid laminates were fabricated using a vacuum infusion technique in which the stacking sequences and ply orientations were varied, which were divided into the categories of cross-ply symmetric, angle-ply symmetric, and symmetric quasi-isotropic. The results of tensile and flexural tests showed that the laminate with interior carbon plies and ply orientation [0°, 90°] exhibited the highest tensile strength (187.67 MPa) and modulus (5.23 GPa). However, the highest flexural strength (289.46 MPa) and modulus (4.82 GPa) were recorded for the laminate with exterior carbon plies and the same ply orientation. The fracture behaviour of the laminates was determined by using scanning electron microscopy, and the results showed that failure usually initiated at the weakest PALF layer. The failure modes included fibre pull-out, fibre breaking, matrix crack, debonding, and delamination.
This study examined the fatigue behaviour of pineapple leaf fibre/carbon hybrid laminate composites under various stacking sequences. The vacuum infusion technique was used to fabricate the symmetric quasi-isotropic oriented laminates, in which the stacking was varied. The laminate was tested under static and fatigue tensile load according to ASTM D3039-76 and ASTM D3479-96, respectively. Maximum tensile strength and modulus of 119.34 MPa and 6.86 GPa, respectively, were recorded for the laminate with external PALF ply and internal carbon ply oriented at [± 45°2, 0°/90°2]s (PCCP_45090). The fatigue tests showed that PCCP_45090 and CPPC_09045 (with internal PALF ply and external carbon ply oriented at [0°/90°2, ± 45°2]s) exhibited a higher useful life, especially at the high-stress level of the ultimate tensile strength. The normalised stress against the number of cycles showed that the stacking sequences of different ply orientations affected the fatigue behaviour more than the stacking sequences of the material. The laminate stacking sequence significantly affected the hysteresis energy and stiffness evolution. The scanning electron microscopy images showed that the fatigue failure modes included fibre pull-out, fibre breakage, matrix cracking, debonding, and delamination. The study concluded that PCCP_45090 exhibited an outstanding fatigue performance.