In the current study, we developed an adaptive algorithm that can predict oil mobilization in a porous medium on the basis of optical data. Associated mechanisms based on tuning the electromagnetic response of magnetic and dielectric nanoparticles are also discussed. This technique is a promising method in rational magnetophoresis toward fluid mobility via fiber Bragg grating (FBG). The obtained wavelength shift due to Fe3O4 injection was 75% higher than that of dielectric materials. This use of FBG magneto-optic sensors could be a remarkable breakthrough for fluid-flow tracking in oil reservoirs. Our computational algorithm, based on piecewise linear polynomials, was evaluated with an analytical technique for homogeneous cases and achieved 99.45% accuracy. Theoretical values obtained via coupled-mode theory agreed with our FBG experiment data of at a level of 95.23% accuracy.