Renewable energy projects in many developing countries need financial and legal back up from
governments and other supportive bodies. There is a viable alternative to finite energy via usage of
biomass waste a renewable energy source. The electrical energy production analysis on biomass waste
presented in this paper is based on the experimental analysis carried out using the laboratory and pilot
scale bioreactors. Electrical energy generated with oscillatory flow bioreactor (OFBR) was 10.12 kWh or
up to 91% higher than the 10 L lab scale bioreactor (0.9 kWh), demonstrating that the novel OFBR has a
great potential for renewable electricity. Also, the pilot scale plant achieves a value of 12.3 kWh, which
the difference is not quite significant with that of OFBR. These results illustrate that the generation of
the renewable electricity is feasible especially with the OFBR thereby achieving high methane potential
during the treatment of manure and food waste. Nevertheless, energy recoveries should be enhanced to
improve the entire operational performance.
Palm oil-based Trimethylolpropane ester (TMP ester), with an iodine value of 66.4 g/100g, was epoxidizedto produce epoxidized TMP esters. In situ epoxidation method was used with peracetic acid to eliminatefatty acid double bonds in palm oil-based TMP ester and change it into oxirane ring. This was done toimprove the oxidative stability of trimethylolpropane ester which is a key concern limiting the usefulservice life in lubricants. The epoxidation was performed by reacting acetic acid as active oxygen carrierwith concentrated hydrogen peroxide as oxygen donor and a small amount of homogeneous catalyst(sulphuric acid). The effects of various parameters on the rate of epoxidation (such as the ratio of moleacetic acid to ethylenic unsaturation, hydrogen peroxide to ethylenic unsaturation and acetic acid moleratio, and amount of catalyst) were studied. The rate of oxidation was investigated by the percentageof oxirane oxygen analysis and iodine value.
Research on the use of Jatropha curcas triglycerides as biodiesel feedstock has received worldwide attention due to its inherent characteristics. Unlike palm oil, J. curcas oil is not edible, and thus, it will not disturb the food supply. However, to the researchers' experiences with the synthesis of J. curcas, oil-based biodiesel has shown that the fuel characteristics depend largely on the type of alcohol used as the excess reactants. Transesterification reaction is chosen for this process with sodium methoxide as the catalyst. Comparison studies on the yield of esters using methanol and ethanol, as well as the impacts on the reaction rate are discussed. The effects of reaction time and molar ratio on the reaction conversion are also examined. The determination of reaction yield is based on the conversion of triglycerides into alkyl esters as the main product. The findings are described as follows: the highest percentage yield of product is attained at 96% for methanol as an excess reactant, and this is 90% when ethanol is used. The optimum conditions of parameters are achieved at 6:1 molar ratio of alcohol to triglycerides, 50 min of reaction time and reaction temperature of 65°C for methanol and 75°C for ethanol. The biodiesel properties of both ester fuels were determined according to the existing standards for biodiesel and compared to the characteristics of diesel fuel.
The feasibility of an anaerobic digestion of cattle manure for biogas production is studied in this paper.
A batch thermophilic oscillatory flow anaerobic bioreactor (OFBR) operated in thermophilic (55o
C)
condition was used. Within the experimental conditions set in this study, the effect of mixing intensity on
volatile solids removal was found out to be significant. Results demonstrated that increasing the level of
mixing decreased the digester performance. Low intensity mixing at oscillatory Reynolds number (Reo)
of 100 achieved an increase of 37% in biogas yields compared to high mixing intensity, Reo of 500. It
was observed that the mixing intensity effect interacts with the methane composition in the biogas. The
benefit of decreasing mixing intensity emerges to significantly increase the methane composition in the
biogas. These experiments established that high intensity mixing was not essential for good performance
of oscillatory flow anaerobic bioreactor. In addition, the effect of mixing intensity might be reduced
through the use of a slightly lower total solid concentration, hence, lowering the operational cost of the
process. Although the study was lab scale a pilot-scale system where mixing retention times are longer
would be useful.