Different type of fibers which is EFB and KC were liquefied in phenol with the presence of sulphuric acid as a catalyst. The liquefied residue was characterized by using Fourier transform infrared (FTIR) to determine the functional groups presents in both residues, X-ray diffraction (XRD) to determine the degree of crystallinity in the residue, thermogravimetric analysis (TGA) to analyze the thermal properties of the residue and scanning electron microscope (SEM) to investigate the structure and morphology of the residue. Phenol-to-EFB/KC ratio shows great effect on the amount of residue in the liquefaction process. Peak appearance can be observed in the FTIR analysis at 810 and 750 cm-1 which is attributed to the para and meta benzene, respectively or to be specific its associated to the p-alkyl phenol and m-alkyl phenol. In the XRD analysis, CrI of lignocellulosic materials increased after liquefaction process. Liquefaction process caused chemical penetration across the grain of the fiber, thus the fiber bundles started to separate into individual fibers shown in the SEM micrograph and the weights lost curve for both liquefied EFB and KC experienced three region decompositions.
In this study oil palm empty fruit bunches (EFB) fibres was used to synthesize biophenolic resin (BPR) at a different
formaldehyde/liquefied empty fruit bunches (F/LEFB) molar ratio which is 1.0, 1.5 and 2.0. The higher molar ratio of F/
LEFB used has resulted in an increased of viscosity and solid content of BPR resin. The first decomposition of BPR resin
occured around 86 to 130°C due to the evaporation of low molecular weight substance which were water, free phenol
and formaldehyde. Glass fibre reinforced biophenolic composite (BPC) and glass fibre reinforced biophenolic elastomer
composite (BPEC) was successfully fabricated using BPR resin. The impact strength and flexural strain of BPEC were
higher than that of BPC. The impact strength of BPEC 1.5 was the highest at 47.71 kJm-2. However, the flexural strength
of BPEC was lower compared with BPC, which the highest flexural strength was obtained by BPC 1.0 at 65.18 MPa. The
cross-sectional image from scanning electron microscope (SEM) of BPEC and BPC confirmed the presence of epoxidized
natural rubber (ENR) improved the compatibility between glass fibre and BPR resin.