The incorporation of a spacer among membranes has a major influence on fluid dynamics and performance metrics. Spacers create feed channels and operate as turbulence promoters to increase mixing and reduce concentration/temperature polarization effects. However, spacer geometry remains unoptimized, and studies continue to investigate a wide range of commercial and custom-made spacer designs. The in-depth discussion of the present systematic review seeks to discover the influence of Reynolds number or solution flowrate on flow hydrodynamics throughout a spacer-filled channel. A fast-flowing solution sweeping one membrane's surface first, then the neighboring membrane's surface produces good mixing action, which does not happen commonly at laminar solution flowrates. A sufficient flowrate can suppress the polarization layer, which may normally require the utilization of a simple feed channel rather than complex spacer configurations. When a recirculation eddy occurs, it disrupts the continuous flow and effectively curves the linear fluid courses. The higher the flowrate, the better the membrane performance, the higher the critical flux (or recovery rate), and the lower the inherent limitations of spacer design, spacer shadow effect, poor channel hydrodynamics, and high concentration polarization. In fact, critical flow achieves an acceptable balance between improving flow dynamics and reducing the related trade-offs, such as pressure losses and the occurrence of concentration polarization throughout the cell. If the necessary technical flowrate is not used, the real concentration potential for transport is relatively limited at low velocities than would be predicted based on bulk concentrations. Electrodialysis stack therefore may suffer from the dissociation of water molecules. Next studies should consider that applying a higher flowrate results in greater process efficiency, increased mass transfer potential at the membrane interface, and reduced stack thermal and electrical resistance, where pressure drop should always be indicated as a consequence of the spacer and circumstances used, rather than a problem.
Electrodialysis desalination uses ion exchange membranes, membrane spacers, and conductors to remove salt from water. Membrane spacers, made of polymeric strands, reduce concentration polarization. These spacers have properties such as porosity and filament shape that affect their performance. One important property is the spacer-bulk attack angle. This study systematically reviews the characteristics of a 45° attack angle of spacers and its effects on concentration polarization and fluid dynamics. Membrane spacers in a channel create distinct flow fields and concentration profiles. When set at a 45° attack angle, spacers provide greater turbulence and mass-heat transfer than traditional spacers. This is because both the transverse and longitudinal filaments become diagonal in relation to the bulk flow direction. A lower attack angle (<45°) results in a lower pressure drop coupled with a decline in wakes and stream disruption because when the filaments are more parallel to the primary fluid direction, the poorer their affect. This research concludes that membrane spacers with a 45° spacer-bulk attack angle function optimally compared to other angles.
Concentration polarization, which creates a thin boundary layer along the membranes in electrochemical reactors and electrodialysis-related processes, is one of the main issues. Membrane spacers provide swirling motion in the stream and distribute fluid toward the membrane, which effectively breaks the polarization layer and maximizes flux steadily. Membrane spacers and the spacer-bulk attack angle are reviewed systematically in the current study. The study then in-depth reviews a ladder-type configuration composed of longitudinal (0° attack angle) and transverse (90° attack angle) filaments, and its effects on solution flow direction and hydrodynamics. The review discovered that, at the tradeoff of high-pressure losses, a laddered spacer can provide mass transfer and mixing activity along the channel while preserving comparable patterns of concentration near the membrane wall. Pressure losses are driven by a change in the direction of velocity vectors. Dead spots in the spacer design that are created by the large contribution of the spacer manifolds can be reduced using the high-pressure drop. Laddered spacers also permit long, tortuous flow paths, which help to create turbulent flow and prevent concentration polarization. The absence of spacers produces limited mixing and broad polarization effects. A major portion of streamlines changes direction at ladder spacer strands positioned transverse to the main flow by moving in a zigzag manner up and down the filaments of the spacer. Flow at 90° is perpendicular to the transverse wires in [Formula: see text]-coordinate, no change in [Formula: see text]-coordinate.
Electrodialysis desalination is constructed with a number of anion exchange membranes (AEM), cation exchange membranes (CEM), anode, cathode, adjacent silicon gasket integrated membrane spacers, and inlet/outlet holes per cell. At the boundary among an ionic solution and an ion exchange membrane, concentration polarization develops. Spacers placed in between channel's walls function as stream baffles to increase turbulence, improve heat and mass transfer, diminish the laminar boundary layer, and lessen fouling problems. The current study offers a systematic review of membrane spacers, spacer-bulk attack angles, and irregular attack angles. Spacer-bulk attack angle is accountable for variations in the pattern and direction of stream which impact heat-mass transfer and concentration polarization. Irregular attack angles (e.g., 0°, 15°, 30°, 37°, 45°, 55°, 60°, 62°, 70°, 74°, 80°, 90°, 110°, 120°) in the present study were found to provide unique stream patterns due to the spacer's filaments being less or more transverse in respect to the primary solution direction, which may significantly alter heat transfer, mass transport, pressure drop, and overall flow dynamics. Spacer applies shear stress resulting by continuous stream tangent to the membrane exterior, which lessens polarization. In the end, 45° is concluded as the preferred attack angle that offers balanced rates of heat transfer, mass transport, and pressure drop throughout the feed channel while greatly lowering the rate of concentration polarization.