Affiliations 

  • 1 Department of Chemical & Process Engineering, Faculty of Engineering & Built Environment, UKM, Bangi 43600, Selangor, Malaysia
  • 2 Fuel Cell Institute, UKM, Bangi 43600, Selangor, Malaysia
Molecules, 2022 Dec 17;27(24).
PMID: 36558155 DOI: 10.3390/molecules27249024

Abstract

This study reports on the synthesis of bi-metal compound (BMC) adsorbents based on commercial coconut activated carbon (CAC), surface-modified with metal acetate (ZnAc2), metal oxide (ZnO), and the basic compounds potassium hydroxide (KOH) and sodium hydroxide (NaOH). The adsorbents were then characterized by scanning electron microscopy and elemental analysis, microporosity analysis through Brunauer-Emmett-Teller (BET) analysis, and thermal stability via thermogravimetric analysis. Adsorption-desorption test was conducted to determine the adsorption capacity of H2S via 1 L adsorber and 1000 ppm H2S balanced 49.95% for N2 and CO2. Characterization results revealed that the impregnated solution homogeneously covered the adsorbent surface, morphology, and properties. The adsorption test result reveals that the ZnAc2/ZnO/CAC_B had a higher H2S breakthrough adsorption capacity and performed at larger than 90% capability compared with a single modified adsorbent (ZnAc2/CAC). Therefore, the synthesized BMC adsorbents have a high H2S loading, and the abundance and low cost of CAC may lead to favorable adsorbents in H2S captured.

* Title and MeSH Headings from MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine.