Affiliations 

  • 1 Organic Synthesis Labratory, Institute of Science, Universiti Tecknologi MARA, 40450 Shah Alam, Selangor, Malaysia
Acta Crystallogr Sect E Struct Rep Online, 2013 Feb 1;69(Pt 2):o293-4.
PMID: 23424562 DOI: 10.1107/S1600536813001943

Abstract

The asymmetric unit of the title compound, C(14)H(17)NO(4)·1.25H(2)O, consists of four substituted pyrrolidone mol-ecules (two pairs of enanti-omers) and five water mol-ecules. The five-membered rings each have an envelope conformation, with the C atom bonded to the ester group as the flap. The mean planes of the five-membered rings of the four pyrrolidone mol-ecules make dihedral angles of 60.87 (5), 64.45 (5), 62.03 (5) and 65.79 (5)° with respect to the phenyl rings. In the crystal, the pyrrolidone and water mol-ecules are connected through O-H⋯O hydrogen bonds, forming a layer parallel to the ab plane. The two-dimensional network is further stabilized by inter-molecular C-H⋯O hydrogen bonds.

* Title and MeSH Headings from MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine.