Affiliations 

  • 1 Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia
Acta Crystallogr Sect E Struct Rep Online, 2011 Jun 1;67(Pt 6):m744-5.
PMID: 21754636 DOI: 10.1107/S1600536811017247

Abstract

The Sn(IV) atom in the title carboxyl-ate-bridged polymer, [Sn(C(7)H(7))(3)(C(9)H(7)O(2))](n), exists in a trans-C(3)SnO(2) trigonal-bipyramidal geometry (average covalent Sn-O = 2.167 Å, average dative Sn-O = 2.361 Å and average O-Sn-O = 169.6°). The polymer propagates as a helical chain along the b axis with a repeat distance that is half the b-axial length. There are four independent formula units in the asymmetric unit; two are disposed about a false center of inversion with respect to the other two so that the space group emulates a centric space group.

* Title and MeSH Headings from MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine.