Affiliations 

  • 1 Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia
PMID: 21588567 DOI: 10.1107/S1600536810034033

Abstract

In the centrosymmetric title mol-ecule, [Cu(2)(CH(3)COO)(4)(C(6)H(9)N(3))(2)], each of the four acetate groups bridges a pair of Cu(II) atoms [Cu-Cu = 2.6540 (4) Å]. The distorted octa-hedral geometry of the metal atom is completed by an N-donor atom of the N-ethyl-pyrimidin-2-amine ligand: an intra-molecular N-H⋯O hydrogen links its N-H group to an acetate carboxyl-ate O atom. In the crystal, C-H⋯O inter-actions link the mol-ecules into a supra-molecular chain along the b axis.

* Title and MeSH Headings from MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine.