Intra- and intermolecular C-h.pi interactions in bis[benzyl 3-(fluoren-9-ylidene)dithiocarbazato-N3,S]nickel(II)

Shanmuga Sundara Raj S; Fun HK; Wu J; Tian YP; Xie FX; Shao ZH; Li SL

Intra- and intermolecular C-h.pi interactions in bis[benzyl 3-(fluoren-9-ylidene)dithiocarbazato-N3,S]nickel(II)

Shanmuga Sundara Raj S ¹ , Fun HK , Wu J , Tian YP , Xie FX , Shao ZH Show all authors , Li SL

Affiliations

¹ X-ray Crystallography Unit, School of Physics, Universiti Sains Malaysia, 11800 USM, Penang, Malaysia

Acta Crystallogr C, 2000 Nov;56 Pt 11:1321-2.

PMID: 11077284

Abstract

The title compound, [Ni(C(21)H(15)N(2)S(2))(2)], has a novel cis configuration with two fluorene moieties on the same side. The Ni atom is in a square-planar configuration. The molecular packing is stabilized by intramolecular stacking between the fluorene moieties and extensive C-H.pi interactions.

* Title and MeSH Headings from MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine.