Affiliations 

  • 1 Department of Chemistry, Sri Jayachamarajendra College of Engineering, JSS Science and Technology University, Mysuru 570 006, Karnataka, India
  • 2 Department of Engineering Chemistry, Vidya Vikas Institute of Engineering & Technology, Visvesvaraya Technological University, Alanahally, Mysuru 570 028, India
  • 3 Department of Physics, School of Engineering and Technology, Jain University, Bangalore 562 112, India
  • 4 Department of Chemistry, Cauvery Institute of Technology, Mandya 571 402, Karnataka, India
  • 5 X-ray Crystallography Unit, School of Physics, Universiti Sains Malaysia, 11800 USM, Penang, Malaysia
  • 6 Head of TVE Department, Islamic University of Technology (IUT), Gazipur 1704, Bangladesh
Acta Crystallogr E Crystallogr Commun, 2019 Feb 01;75(Pt 2):264-267.
PMID: 30800464 DOI: 10.1107/S205698901900104X

Abstract

In the title chalcone derivative, C15H9BrCl2O, the aryl rings are inclined to each by 14.49 (17)°, and the configuration about the C=C bond is E. There is a short intra-molecular C-H⋯Cl contact present resulting in the formation of an S(6) ring motif. In the crystal, the shortest inter-molecular contacts are Cl⋯O contacts [3.173 (3) Å] that link the mol-ecules to form a 21 helix propagating along the b-axis direction. The helices stack up the short crystallographic a axis, and are linked by offset π-π inter-actions [inter-centroid distance = 3.983 (1) Å], forming layers lying parallel to the ab plane. A qu-anti-fication of the inter-molecular contacts in the crystal were estimated using Hirshfeld surface analysis and two-dimensional fingerprint plots.

* Title and MeSH Headings from MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine.