Affiliations 

  • 1 Department of Chemistry, Shahjalal University of Science and Technology, Sylhet 3114, Bangladesh
  • 2 School of Chemical Sciences, Universiti Sains Malaysia, Penang 11800 USM, Malaysia
Acta Crystallogr E Crystallogr Commun, 2019 Oct 01;75(Pt 10):1486-1489.
PMID: 31636980 DOI: 10.1107/S2056989019012623

Abstract

The PtII atom in the title complex, [Pt(C15H18N4O4S)(C2H6OS)], exists within a square-planar NS2O donor set provided by the N, S, O atoms of the di-anionic tridentate thio-semicarbazo ligand and a dimethyl sulfoxide S atom. The two chelate rings are coplanar, subtending a dihedral angle of 1.51 (7)°. The maximum deviation from an ideal square-planar geometry is seen in the five-membered chelate ring with an S-Pt-S bite angle of 96.45 (2)°. In the crystal, mol-ecules are linked via N-H⋯O, C-H⋯O, C-H⋯N and C-H⋯π inter-actions into two-dimensional networks lying parallel to the ab plane. The conformations of related cyclo-hexyl-hydrazine-1-carbo-thio-amide ligands are compared to that of the title compound.

* Title and MeSH Headings from MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine.