Currently, fossil materials form the majority of our energy and chemical source. Many global concerns force us to rethink about our current dependence on the fossil energy. Limiting the use of these energy sources is a key priority for most countries that pledge to reduce greenhouse gas emissions. The application of biomass, as substitute fossil resources for producing biofuels, plastics and chemicals, is a widely accepted strategy for sustainable development. Aquatic plants including algae possess competitive advantages as biomass resources compared to the terrestrial plants in this current global situation. Bio-oil production from algal biomass is technically and economically viable, cost competitive, requires no capacious lands and minimal water use and reduces atmospheric carbon dioxide. The aim of this paper is to review the potential of converting algal biomass, as an aquatic plant, into high-quality crude bio-oil through applicable processes in Malaysia. In particular, bio-based materials and fuels from algal biomass are considered as one of the reliable alternatives for clean energy. Currently, pyrolysis and hydrothermal liquefaction (HTL) are two foremost processes for bio-oil production from biomass. HTL can directly convert high-moisture algal biomass into bio-oil, whereas pyrolysis requires feedstock drying to reduce the energy consumption during the process. Microwave-assisted HTL, which can be conducted in aqueous environment, is suitable for aquatic plants and wet biomass such as algae.
Plant disease control has traditionally relied heavily on the use of agrochemicals despite their potentially negative impact on the environment. An alternative strategy is that of induced resistance (IR). However, while IR has proven effective in controlled environments, it has shown variable field efficacy, thus raising questions about its potential for disease management in a given crop. Mathematical modelling of IR assists researchers with understanding the dynamics of the phenomenon in a given plant cohort against a selected disease-causing pathogen. Here, a prototype mathematical model of IR promoted by a chemical elicitor is proposed and analysed. Standard epidemiological models describe that, under appropriate environmental conditions, Susceptible plants (S) may become Diseased (D) upon exposure to a compatible pathogen or are able to Resist the infection (R) via basal host defence mechanisms. The application of an elicitor enhances the basal defence response thereby affecting the relative proportion of plants in each of the S, R and D compartments. IR is a transient response and is modelled using reversible processes to describe the temporal evolution of the compartments. Over time, plants can move between these compartments. For example, a plant in the R-compartment can move into the S-compartment and can then become diseased. Once in the D-compartment, however, it is assumed that there is no recovery. The terms in the equations are identified using established principles governing disease transmission and this introduces parameters which are determined by matching data to the model using computer-based algorithms. These then give the best match of the model with experimental data. The model predicts the relative proportion of plants in each compartment and quantitatively estimates elicitor effectiveness. An illustrative case study will be given; however, the model is generic and will be applicable for a range of plant-pathogen-elicitor scenarios.
Carbon dioxide (CO2) emission will increase due to the increasing global plastic demand. Statistical data shows that plastic production alone will contribute to at least 20% of the annual global carbon budget in the near future. Hence, several alternative methods are recommended to overcome this problem, such as bio-product synthesis. Algae consist of diverse species and have huge potential to be a promising biomass feedstock for a range of purposes, including bio-oil production. The convenient cultivation method of algae could be one of the main support for algal biomass utilization. The aim of this study is to forecast and outline the strategies in order to meet the future demand (year 2050) of plastic production and, at the same time, reduce CO2 emission by replacing the conventional plastic with bio-based plastic. In this paper, the analysis for 25%, 50% and 75% CO2 reduction has been done by using carbon emission pinch analysis. The strategies of biomass utilization in Malaysia are also enumerated in this study. This study suggested that the algal biomass found in Malaysia coastal areas should be utilized and cultivated on a larger scale in order to meet the increasing plastic demand and, at the same time, reduce carbon footprint. Some of the potential areas for macroalgae sea-farming cultivation in Sabah coastline (Malaysia), comprised of about 3885 km2 (388,500 ha) in total, have been highlighted. These potential areas have the potential to produce up to 14.5 million tonnes (Mt)/y of macroalgae in total, which can contribute 370 Mt of phenol for bioplastic production.
Nitrocellulose (NC)-based propellants have played a pivotal role in the development of energetic materials for both military and civilian applications. This review offers a comprehensive exploration of NC-based propellants, tracing their evolution from their historical origins as smokeless gunpowder to modern advancements. It discusses the chemical composition and classifications of NC propellants, along with continuous efforts to refine smokeless powder formulations through studies on smoke formation, residues, and additives. Modern techniques such as PCR-based detection and dynamic light scattering have enabled precise analysis of NC properties, including variations in the degree of substitution and molar mass, which allow for tailoring the chemical structure to meet specific performance needs. Special attention is given to the combustion dynamics of NC-based propellants, with an emphasis on reaction zones, performance characteristics, and optimization strategies that enhance their overall efficacy. The review also highlights the significant impact of nitrogen content, additives, and processing methods on the performance, stability, and safety of NC-infused propellants. While higher nitrogen content improves energetic output, it also increases surface cracking and gas production, necessitating the use of stabilizers and additives like Bu-NENA, copper compounds, and MgH2 to enhance flexibility, thermal stability, and reduce sensitivity to mechanical and thermal stimuli. Aging and environmental factors further influence burn rate variation, underscoring the need for tailored formulations. In terms of environmental sustainability, this review addresses safety considerations in handling and disposing of NC-based materials, focusing on innovations such as alkaline hydrolysis and NC recovery to mitigate environmental risks. Stabilizers and eco-friendly additives effectively prevent chemical degradation, reduce shock sensitivity, and enhance thermal stability. The review concludes with future research directions aimed at further improving the stability and safety of NC-based propellants, ensuring their continued relevance in modern applications.