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  1. Jhatial AA, Goh WI, Mastoi AK, Rahman AF, Kamaruddin S
    PMID: 33745050 DOI: 10.1007/s11356-021-13435-2
    The production of cement contributes to 10% of global carbon dioxide (CO2) pollution and 74 to 81% towards the total CO2 pollution by concrete. In addition to that, its low strength-to-weight ratio, high density and thermal conductivity are among the few limitations of heavy weight concrete. Therefore, this study was carried out to provide a solution to these limitations by developing innovative eco-friendly lightweight foamed concrete (LFC) of 1800 kg/m3 density incorporating 20-25% palm oil fuel ash (POFA) and 5-15% eggshell powder (ESP) by weight of total binder as supplementary cementitious material (SCM). The influence of combined utilization of POFA and ESP on the fresh state properties of eco-friendly LFC was determined using the J-ring test. To determine the mechanical properties, a total of 48 cubes and 24 cylinders were prepared for compressive strength, splitting tensile strength and modulus of elasticity each. A total of 24 panels were prepared to determine the thermal properties in terms of surface temperature and thermal conductivity. Furthermore, to assess the environmental impact and eco-friendliness of the developed LFC, the embodied carbon and eco-strength efficiency was calculated. It was determined that the utilization of POFA and ESP reduced the workability slightly but enhanced the mechanical properties of LFC (17.05 to 22.60 MPa compressive strength and 1.43 to 2.61 MPa tensile strength), thus satisfies the ACI213R requirements for structural lightweight concrete and that it can be used for structural applications. Additionally, the thermal conductivity reduced ranging from 0.55 to 0.63 W/mK compared to 0.82 W/mK achieved by control sample. Furthermore, the developed LFC showed a 16.96 to 33.55% reduction in embodied carbon and exhibited higher eco-strength efficiency between 47.82 and 76.97%. Overall, the combined utilization of POFA and ESP as SCMs not only enhanced the thermo-mechanical performance, makes the sustainable LFC as structural lightweight concrete, but also has reduced the environmental impacts caused by the disposal of POFA and ESP in landfills as well as reducing the total CO2 emissions during the production of eco-friendly LFC.
  2. Jhatial AA, Goh WI, Mastoi AK, Traore AF, Oad M
    Environ Sci Pollut Res Int, 2022 Jan;29(2):2985-3007.
    PMID: 34383212 DOI: 10.1007/s11356-021-15076-x
    Rapid urbanization and 'concretization' have increased the use of concrete as the preferred building material. However, the production of cement and other concrete-related activities, contribute significantly to both the carbon dioxide emissions and climate change. Agro-industrial wastes such as Palm Oil Fuel Ash (POFA) and Eggshell Powder (ESP) have been utilized in concrete as supplementary cementitious materials, to reduce the cement content, in order to minimize the carbon footprint and the environmental pollution associated with the dumping of waste. Both POFA and ESP have been utilized in ternary binder foamed concrete; however, higher content of cement replacement tends to reduce the concrete's strength significantly. Therefore, this research was conducted to study the influence of ternary binder foamed concrete, incorporating 30% POFA and 5-15% ESP by weight of the total binder, when reinforced with polypropylene (PP) fibres. Based on the results, the ternary binder foamed concrete showed better strength than the control foamed concrete due to the pozzolanic reaction and the addition of PP fibres slightly improved the strength. Furthermore, ternary binder foamed concrete can reduce up to 33.79% of the total CO2 emissions. In terms of cost, all ternary binder foamed concrete mixes reduced the overall cost of the mix. The lowest cost per 1 MPa was achieved by ternary binder foamed concrete mix which incorporated 30% POFA, 5% ESP and 0.20% PP fibres. However, the optimum S5 ternary binder foamed concrete mix, which incorporated 30% POFA, 10% ESP and 0.20% PP fibres, exhibited a cost of $3.74 per 1 MPa strength, which was $1.1 lower than the control foamed concrete. PP reinforced ternary binder foamed concrete is an eco-efficient and cost-effective concrete that can be used in numerous civil engineering applications, mitigating the environmental and the emissions generated by agro-industrial waste.
  3. Rid ZA, Shah SNR, Memon MJ, Jhatial AA, Keerio MA, Goh WI
    PMID: 34985632 DOI: 10.1007/s11356-021-18379-1
    With the recent increase in demand for high-strength concrete, higher cement content is utilized, which has increased the need for cement. The cement industry is one of the most energy-consuming sectors globally, contributing to 10% of global carbon dioxide (CO2) gas emissions and global warming. Similarly, with rapid urbanization and industrialization, a vast number of by-products and waste materials are being generated in abundance, which causes environmental and health issues. Focusing on these two issues, this study aimed to develop an M50-grade eco-friendly high-strength concrete incorporating waste materials like marble dust powder (MDP) and fly ash (FA) as partial cement replacement. 2.5%, 5%, 7.5%, and 10% MDP and FA by weight of total binder was utilized combinedly, such that the 5%, 10%, 15%, and 20% cement content was replaced, respectively. The fresh state properties in terms of workability and hardened state properties in terms of compressive and flexural strengths were evaluated at 7, 14, 28, 56, and 90 days. Furthermore, to assess the environmental impact of MDP and FA, the embodied carbon and eco-strength efficiency were calculated. Based upon the results, it was observed that a combined 10% (5% MDP and 5% FA) achieved the highest strength; however, 15% (7.5% MDP and 7.5% FA) substitution could be optimal. Furthermore, the combined utilization of FA and MDP also enabled a reduction in the total embodied carbon. It decreased the cost of concrete, resulting in an eco-friendly, high-strength concrete.
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