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  1. Thien GSH, Chan KY, Marlinda AR, Yap BK
    Nanoscale, 2023 Dec 07;15(47):19039-19061.
    PMID: 37987540 DOI: 10.1039/d3nr03874b
    Oxide perovskites (OPs) have emerged as promising photocatalysts for numerous applications, such as energy conversion, renewable fuels, and environmental remediation. Although OPs are gaining traction, their efficacies are still hindered by low charge carrier mobility and poor stability. This study investigated the function of polymers actively participating in OP structures to improve the overall characteristics. An overview of the polymer-enhanced perovskite oxide photocatalyst (PEPOP) field was effectively reviewed. These PEPOPs were demonstrated in photovoltaics, pollutant degradation, and gas conversion and reduction. Nonetheless, additional research is needed to explore the potential of PEPOPs to establish their efficacy in photocatalytic applications. The technological improvements of PEPOPs were hindered by significant challenges related to stability and sensitivity. The urgency of this review was apparent due to the fast-paced nature of research in the field of photocatalysis. Recent breakthroughs and emerging applications highlight the need for a comprehensive overview of PEPOPs and their enhanced catalytic capabilities. Consequently, a broad outlook was provided for the current state of PEPOP-related studies, highlighting the potential of these materials for future applications.
  2. Shukor NIA, Chan KY, Thien GSH, Yeoh ME, Low PL, Devaraj NK, et al.
    Sensors (Basel), 2023 Oct 12;23(20).
    PMID: 37896506 DOI: 10.3390/s23208412
    Solar cells are pivotal in harnessing renewable energy for a greener and more sustainable energy landscape. Nonetheless, eco-friendly materials for solar cells have not been as extensive as conventional counterparts, highlighting a significant area for further investigation in advancing sustainable energy technologies. This study investigated natural dyes from cost-effective and environmentally friendly blueberries and mulberries. These dyes were utilized as alternative sensitizers for dye-sensitized solar cells (DSSCs). Alongside the natural dyes, a green approach was adopted for the DSSC design, encompassing TiO2 photoanodes, eco-friendly electrolytes, and green counter-electrodes created from graphite pencils and candle soot. Consequently, the best-optimized dye sensitizer was mulberry, with an output power of 13.79 µW and 0.122 µW for outdoor and indoor environments, respectively. This study underscored the feasibility of integrating DSSCs with sensitizers derived from readily available food ingredients, potentially expanding their applications in educational kits and technology development initiatives.
  3. Thien GSH, Ab Rahman M, Yap BK, Tan NML, He Z, Low PL, et al.
    ACS Omega, 2022 Nov 08;7(44):39472-39481.
    PMID: 36385870 DOI: 10.1021/acsomega.2c03206
    Due to their remarkable electrical and light absorption characteristics, hybrid organic-inorganic perovskites have recently gained popularity in several applications such as optoelectronics, lasers, and light-emitting diodes. Through this, there has recently been an increase in the use of halide perovskites (HPs) in resistive switching (RS) devices. However, lead-based (Pb-based) perovskites are notorious for being unstable and harmful to the environment. As a result, lead-free (Pb-free) perovskite alternatives are being investigated in achieving the long-term and sustainable use of RS devices. This work describes the characteristics of Pb-based and Pb-free perovskite RS devices. It also presents the recent advancements of HP RS devices, including the selection strategies of perovskite structures. In terms of resistive qualities, the directions of both HPs appear to be identical. Following that, the possible impact of switching from Pb-based to Pb-free HPs is examined to determine the requirement in RS devices. Finally, this work discusses the opportunities and challenges of HP RS devices in creating a stable, efficient, and sustainable memory storage technology.
  4. Islam MS, Chan KY, Thien GSH, Low PL, Lee CL, Wong SK, et al.
    Polymers (Basel), 2023 Aug 16;15(16).
    PMID: 37631477 DOI: 10.3390/polym15163420
    Polymer-dispersed liquid crystal (PDLC) film is an active smart film penetrating the market due to its unique functionalities. These functional characteristics include switchable tint capabilities, which shield building residents from the sun's harmful ultraviolet (UV) rays, improve energy-saving features, and produce higher cost-efficiency. Although PDLC films are promising in several applications, there is still ambiguity on the performance of PDLC films. Particularly, the sizing effects' (such as film thickness and area) correlation with visible light transmission (VLT), ultraviolet rejection (UVR), infrared rejection (IRR), light intensity, current consumption, and apparent power consumption is not well understood. Therefore, this study investigated the sizing effects of PDLC films, including the thickness effect on VLT, UVR, IRR, light intensity, and area influence on current and apparent power consumptions. The varying applied voltage effect on the light transmittance of the PDLC film was also effectively demonstrated. A 0.1 mm PDLC film was successfully presented as a cost-efficient film with optimal parameters. Consequently, this study paves the way for a clearer understanding of PDLC films (behavior and sizing effects) in implementing economic PDLC films for large-scale adoption in commercial and residential premises.
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