Adsorption isotherms, kinetics, and thermodynamics of Au(III) on chitosan/palm kernel fatty acid distillate/magnetite nanocomposites

This study examined the adsorption isotherms, kinetics, and thermodynamics of Au(III) onto chitosan/palm kernel fatty acid distillate/magnetite nanocomposites (CPMNs) to enhance the understanding of adsorption behavior and mechanisms. Adsorption experiments were conducted across various initial Au(III) concentrations, contact times, and temperatures. The experimental data were analyzed using nonlinear isotherm and kinetic models, and thermodynamic parameters were evaluated. The results revealed that the Langmuir model best fits the adsorption equilibrium data, showing a maximum monolayer adsorption capacity of 1.102-1.163 mmol/g (217-229 mg/g). The pseudo-first-order model best describes the kinetic data, suggesting first-order kinetics and a physisorption-dominated process. Thermodynamic analysis indicated that the adsorption is spontaneous, endothermic, entropy-driven, and highly favorable, primarily governed by physisorption. This study provides significant insights into the adsorption mechanisms of CPMNs for Au(III), contributing to advancing cost-effective and eco-friendly adsorbents for industrial use, such as wastewater treatment and metal recovery in mining, metallurgy, and electronic waste recycling industries.