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Bis(μ2-N-methyl-N-phenyl-dithio-carbamato)-κ(3)S,S':S;κ(3)S:S,S'-bis-[(N-methyl-N-phenyl-dithio-carbamato-κ(2)S,S')cadmium]: crystal structure and Hirshfeld surface analysis

Suwardi SA 1 , Lee SM 2 , Lo KM 2 , Jotani MM 3 , Tiekink ER 2

Affiliations 

  • 1 Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia
  • 2 Research Centre for Crystalline Materials, School of Science and Technology, Sunway University, 47500 Bandar Sunway, Selangor Darul Ehsan, Malaysia
  • 3 Department of Physics, Bhavan's Sheth R. A. College of Science, Ahmedabad, Gujarat 380 001, India
Acta Crystallogr E Crystallogr Commun, 2017 Mar 01;73(Pt 3):429-433.
PMID: 28316825 DOI: 10.1107/S2056989017002705

Abstract

The title compound, [Cd2(C8H8NS2)4], is a centrosymmetric dimer with both chelating and μ2-tridentate di-thio-carbamate ligands. The resulting S5 donor set defines a Cd(II) coordination geometry inter-mediate between square-pyramidal and trigonal-bipyramidal, but tending towards the former. The packing features C-H⋯S and C-H⋯π inter-actions, which generate a three-dimensional network. The influence of these inter-actions, along with intra-dimer π-π inter-actions between chelate rings, has been investigated by an analysis of the Hirshfeld surface.

* Title and MeSH Headings from MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine.

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