Affiliations 

  • 1 Chemical Engineering Department, University of Malaya, Kuala Lumpur 50603, Malaysia. abu_ismaiel@hotmail.com
  • 2 Chemical Engineering Department, University of Malaya, Kuala Lumpur 50603, Malaysia. mk_aroua@um.edu.my
  • 3 Chemical Engineering Department, University of Malaya, Kuala Lumpur 50603, Malaysia. ryusoff@um.edu.my
Sensors (Basel), 2014;14(7):13102-13.
PMID: 25051034 DOI: 10.3390/s140713102

Abstract

In this study, a potentiometric sensor composed of palm shell activated carbon modified with trioctylmethylammonium thiosalicylate (TOMATS) was used for the potentiometric determination of mercury ions in water samples. The proposed potentiometric sensor has good operating characteristics towards Hg (II), including a relatively high selectivity; a Nernstian response to Hg (II) ions in a concentration range of 1.0 × 10(-9) to 1.0 × 10(-2) M, with a detection limit of 1 × 10(-10) M and a slope of 44.08 ± 1.0 mV/decade; and a fast response time (~5 s). No significant changes in electrode potential were observed when the pH was varied over the range of 3-9. Additionally, the proposed electrode was characterized by good selectivity towards Hg (II) and no significant interferences from other cationic or anionic species.

* Title and MeSH Headings from MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine.