This paper presents an investigation on the physio-mechanical properties and AC breakdown voltage of the Kenaf paper in the presence of Polyvinyl Alcohol (PVA) for transformers application. Kenaf bast fibers were used in order to produce the paper through the soda pulping process. The pulps were subjected to beating up to 12,000 revolutions, whereby the PVA was added to the pulps at a different weight percentage concentration up to 12%. Morphological study was carried out on the Kenaf paper based on Scanning Electron Microscopy (SEM). The apparent density, Tensile Index (TI), Burst Index (BI), Tear Index (TeI), and AC breakdown voltage of the Kenaf paper were measured. It is found that the TI and BI of Kenaf paper can be slightly improved through the introduction of PVA. On other hand, the TeI of the Kenaf paper decreases with the increment of the PVA. The AC breakdown voltage of the Kenaf paper slightly increases with the increment of PVA weight percentage concentration.
A new meta-surface structure (MSS) with a near-zero refractive index (NZRI) is proposed to enhance the performance of a square loop antenna array. The main challenge to improve the antenna performance is increment of the overall antenna volume that is mitigated by assimilating the planar NZRI MSS at the back of the antenna structure. The proposed NZRI MSS-loaded CPW-fed (Co-Planar Waveguide) four-element array antenna is designed on ceramic-bioplastic-ceramic sandwich substrate using high-frequency structure simulator (HFSS), a finite-element-method-based simulation tool. The gain and directivity of the antenna are significantly enhanced by incorporating the NZRI MSS with a 7 × 6 set of elements at the back of the antenna structure. Measurement results show that the maximum gains of the antenna increased from 6.21 dBi to 8.25 dBi, from 6.52 dBi to 9.05 dBi and from 10.54 dBi to 12.15 dBi in the first, second and third bands, respectively. The effect of the slot configuration in the ground plane on the reflection coefficient of the antenna was analyzed and optimized. The overall performance makes the proposed antenna appropriate for UHFFM (Ultra High Frequency Frequency Modulation) telemetry-based space applications as well as mobile satellite, microwave radiometry and radio astronomy applications.
The effect of milling time on the morphology, microstructure, physical and mechanical properties of pure Al-5 wt % Al₂O₃ (Al-5Al₂O₃) has been investigated. Al-5Al₂O₃ nanocomposites were fabricated using ball milling in a powder metallurgy route. The increase in the milling time resulted in the homogenous dispersion of 5 wt % Al₂O₃ nanoparticles, the reduction of particle clustering, and the reduction of distances between the composite particles. The significant grain refining during milling was revealed which showed as a reduction of particle size resulting from longer milling time. X-Ray diffraction (XRD) analysis of the nanocomposite powders also showed that designated ball milling contributes to the crystalline refining and accumulation of internal stress due to induced severe plastic deformation of the particles. It can be argued that these morphological and microstructural variations of nanocomposite powders induced by designated ball milling time was found to contribute to an improvement in the density, densification, micro-hardness (HV), nano-hardness (HN), and Young's modulus (E) of Al-5Al₂O₃ nanocomposites. HV, HN, and E values of nanocomposites were increased by ~48%, 46%, and 40%, after 12 h of milling, respectively.
Photodynamic therapy (PDT) is a cancer treatment that employs the production of cytotoxic reactive oxygen species (ROS), subsequently triggering tumor apoptosis and tumor size reduction. However, this approach suffers from insufficient light penetration depth. In order to mitigate this issue, pollen-structured gold clusters (PSGCs) were designed for mediating X-ray-induced PDT for radiotherapy enhancement. The structure of PSGCs provides a large surface area that is able to generate ROS upon X-ray irradiation. The synthesized PSGCs were exposed to different X-ray doses and the generated ROS was then quantified by dihydroethidium (DHE) assay. Furthermore, at the cellular level, the PDT efficacy of PSGCs was evaluated via immunofluorescence staining with γ-H2AX and comet assay. The results demonstrated that PSGCs possess a significantly high ROS-generating capacity and a remarkable PDT efficacy in the treatment of breast cancer cells, thus showing potential clinical uses in deep-tissue cancer treatment.
Welding parameters obviously determine the joint quality during the resistance spot welding process. This study aimed to investigate the effect of welding current and electrode force on the heat input and the physical and mechanical properties of a SS316L and Ti6Al4V joint with an aluminum interlayer. The weld current values used in this study were 11, 12, and 13 kA, while the electrode force values were 3, 4, and 5 kN. Welding time and holding time remained constant at 30 cycles. The study revealed that, as the welding current and electrode force increased, the generated heat input increased significantly. The highest tensile-shear load was recorded at 8.71 kN using 11 kA of weld current and 3 kN of electrode force. The physical properties examined the formation of a brittle fracture and several weld defects on the high current welded joint. The increase in weld current also increased the weld diameter. The microstructure analysis revealed no phase transformation on the SS316L interface; instead, the significant grain growth occurred. The phase transformation has occurred on the Ti6Al4V interface. The intermetallic compound layer was also investigated in detail using the EDX (Energy Dispersive X-Ray) and XRD (X-Ray Diffraction) analyses. It was also found that both stainless steel and titanium alloy have their own fusion zone, which is indicated by the highest microhardness value.
The carbonation rate of reinforced concrete is influenced by three parameters, namely temperature, relative humidity, and concentration of carbon dioxide (CO₂) in the surroundings. As knowledge of the service lifespan of reinforced concrete is crucial in terms of corrosion, the carbonation process is important to study, and high-performance durable reinforced concretes can be produced to prolong the effects of corrosion. To examine carbonation resistance, accelerated carbonation testing was conducted in accordance with the standards of BS 1881-210:2013. In this study, 10⁻30% of micro palm oil fuel ash (mPOFA) and 0.5⁻1.5% of nano-POFA (nPOFA) were incorporated into concrete mixtures to determine the optimum amount for achieving the highest carbonation resistance after 28 days water curing and accelerated CO₂ conditions up to 70 days of exposure. The effect of carbonation on concrete specimens with the inclusion of mPOFA and nPOFA was investigated. The carbonation depth was identified by phenolphthalein solution. The highest carbonation resistance of concrete was found after the inclusion of 10% mPOFA and 0.5% nPOFA, while the lowest carbonation resistance was found after the inclusion of 30% mPOFA and 1.5% nPOFA.
Nanofluids have attracted significant attention from researchers due to their ability to significantly enhance heat transfer, especially in jet impingement flows, which can improve their cooling performance. However, there is a lack of research on the use of nanofluids in multiple jet impingements, both in terms of experimental and numerical studies. Therefore, further investigation is necessary to fully understand the potential benefits and limitations of using nanofluids in this type of cooling system. Thus, an experimental and numerical investigation was performed to study the flow structure and heat transfer behavior of multiple jet impingement using MgO-water nanofluids with a 3 × 3 inline jet array at a nozzle-to-plate distance of 3 mm. The jet spacing was set to 3, 4.5, and 6 mm; the Reynolds number varies from 1000 to 10,000; and the particle volume fraction ranges from 0% to 0.15%. A 3D numerical analysis using ANSYS Fluent with SST k-ω turbulent model was presented. The single-phase model is adopted to predict the thermal physical nanofluid. The flow field and temperature distribution were investigated. Experimental results show that a nanofluid can provide a heat transfer enhancement at a small jet-to-jet spacing using a high particle volume fraction under a low Reynolds number; otherwise, an adverse effect on heat transfer may occur. The numerical results show that the single-phase model can predict the heat transfer trend of multiple jet impingement using nanofluids correctly but with significant deviation from experimental results because it cannot capture the effect of nanoparticles.
The complex reaction between liquid solder alloys and solid substrates has been studied ex-situ in a few studies, utilizing creative setups to "freeze" the reactions at different stages during the reflow soldering process. However, full understanding of the dynamics of the process is difficult due to the lack of direct observation at micro- and nano-meter resolutions. In this study, high voltage transmission electron microscopy (HV-TEM) is employed to observe the morphological changes that occur in Cu6Sn5 between a Sn-3.0 wt%Ag-0.5 wt%Cu (SAC305) solder alloy and a Cu substrate in situ at temperatures above the solidus of the alloy. This enables the continuous surveillance of rapid grain boundary movements of Cu6Sn5 during soldering and increases the fundamental understanding of reaction mechanisms in solder solid/liquid interfaces.
The curvature correction factor is an important parameter in the stress calculation formulation of a helical extension spring, which describes the effect of spring wire curvature on the stress increase towards its inner radius. In this study, the parameters affecting the curvature correction factor were investigated through theoretical and numerical methods. Several finite element (FE) models of an extension spring were generated to obtain the distribution of the tensile stress in the spring. In this investigation, the hook orientation and the number of coils of the extension spring showed significant effects on the curvature correction factor. These parameters were not considered in the theoretical model for the calculation of the curvature correction factor, causing a deviation between the results of the FE model and the theoretical approach. A set of equations is proposed for the curvature correction factor, which relates both the spring index and the number of coils. These equations can be applied directly to the design of extension springs with a higher safety factor.
This study discloses a method for painting artwork using a CO2 laser. The continuous-wave laser beam, at a predetermined heat flux and a predetermined number of laser beam passes, mixes and displaces the plurality of colored polymer-based compositions, respectively, by way of melting and vaporizing them. Experiments showed a great accuracy of colors and designed patterns between the computer aided design (CAD) drawing and what was achieved after laser discoloration. It was found that lower values of power and speed provide sufficient energy and time to make a melt pool of colors and cause their vaporization from the surface. A detailed numerical simulation was performed to obtain a detailed understanding of the physics of laser interaction with paint using ABAQUS software. The comparative analysis indicated that the top layer of paint (including yellow and green colors) melted upon increasing cutting speed and employing one laser pass. For blue and red paints, two passes of lasers are required; in the case of red color, lower laser speed is also necessary to intensify the heat. This method can be applied for making art designs on each surface color because it is based on melting and vaporization using a laser.
The development of Friction Stir Welding (FSW) has provided an alternative approach for producing high-quality welds, in a fast and reliable manner. This study focuses on the mechanical properties of the dissimilar friction stir welding of AA6061-T6 and AA7075-T6 aluminum alloys. The FSW process parameters such as tool rotational speed, tool traverse speed, tilt angle, and tool offset influence the mechanical properties of the friction stir welded joints significantly. A mathematical regression model is developed to determine the empirical relationship between the FSW process parameters and mechanical properties, and the results are validated. In order to obtain the optimal values of process parameters that simultaneously optimize the ultimate tensile strength, elongation, and minimum hardness in the heat affected zone (HAZ), a metaheuristic, multi objective algorithm based on biogeography based optimization is proposed. The Pareto optimal frontiers for triple and dual objective functions are obtained and the best optimal solution is selected through using two different decision making techniques, technique for order of preference by similarity to ideal solution (TOPSIS) and Shannon's entropy.
Many studies have been done using recycled waste materials to minimise environmental problems. It is a great opportunity to explore mechanical recycling and the use of recycled and virgin blend as a material to produce new products with minimum defects. In this study, appropriate processing parameters were considered to mould the front panel housing part using R0% (virgin), R30% (30% virgin: 70% recycled), R40% (40% virgin: 60% recycled) and R50% (50% virgin: 50% recycled) of Polycarbonate (PC). The manufacturing ability and quality during preliminary stage can be predicted through simulation analysis using Autodesk Moldflow Insight 2012 software. The recommended processing parameters and values of warpage in x and y directions can also be obtained using this software. No value of warpage was obtained from simulation studies for x direction on the front panel housing. Therefore, this study only focused on reducing the warpage in the y direction. Response Surface Methodology (RSM) and Genetic Algorithm (GA) optimisation methods were used to find the optimal processing parameters. As the results, the optimal ratio of recycled PC material was found to be R30%, followed by R40% and R50% materials using RSM and GA methods as compared to the average value of warpage on the moulded part using R0%. The most influential processing parameter that contributed to warpage defect was packing pressure for all materials used in this study.
One of the difficulties with bobbin friction stir welding (BFSW) has been the visualisation of microstructure, particularly grain boundaries, and this is especially problematic for materials with fine grain structure, such as AA6082-T6 aluminium as here. Welds of this material were examined using optical microscopy (OM) and electron backscatter diffraction (EBSD). Results show that the grain structures that form depend on a complex set of factors. The motion of the pin and shoulder features transports material around the weld, which induces shear. The shear deformation around the pin is non-uniform with a thermal and strain gradient across the weld, and hence the dynamic recrystallisation (DRX) processes are also variable, giving a range of observed polycrystalline and grain boundary structures. Partial DRX was observed at both hourglass boundaries, and full DRX at mid-stirring zone. The grain boundary mapping showed the formation of low-angle grain boundaries (LAGBs) at regions of high shear as a consequence of thermomechanical nature of the process.
Basalt fibre is a promising mineral fibre that has high potential to replace synthetic based glass fibre in today's stringent environmental concern. In this study, friction and wear characteristics of glass and basalt fibres reinforced epoxy composites were studied and comparatively evaluated at two test stages. The first stage was conducted at fixed load, speed and distance under three different conditions; adhesive, abrasive and erosive wear, wherein each composite specimens slide against steel, silicon carbide, and sand mixtures, respectively. The second stage was conducted involving different types of adhesive sliding motions against steel counterpart; unidirectional and reciprocating motion, with the former varied at pressure-velocity (PV) factor; 0.23 MPa·m/s and 0.93 MPa·m/s, while the latter varied at counterpart's configuration; ball-on-flat (B-O-F) and cylinder-on-flat (C-O-F). It was found that friction and wear properties of composites are highly dependent on test conditions. Under 10 km test run, Basalt fibre reinforced polymer (BFRP) composite has better wear resistance against erosive sand compared to Glass fibre reinforced polymer (GFRP) composite. In second stage, BFRP composite showed better wear performance than GFRP composite under high PV of unidirectional sliding test and under B-O-F configuration of reciprocating sliding test. BFRP composite also exhibited better friction properties than GFRP composite under C-O-F configuration, although its specific wear rate was lower. In scanning electron microscopy examination, different types of wear mechanisms were revealed in each of the test conducted.
On-stream inspections are the most appropriate method for routine inspections during plant operation without undergoing production downtime. Ultrasonic inspection, one of the on-stream inspection methods, faces challenges when performed at high temperatures exceeding the recommended 52 °C. This study aims to determine the ultrasonic velocity and attenuation with known material grade, thickness, and temperatures by comparing theoretical calculation and experimentation, with temperatures ranging between 30 °C to 250 °C on low-carbon steel, covering most petrochemical equipment material and working conditions. The aim of the theoretical analysis was to obtain Young's modulus, Poisson's ratio, and longitudinal velocity at different temperatures. The experiments validated the theoretical results of ultrasonic change due to temperature increase. It was found that the difference between the experiments and theoretical calculation is 3% at maximum. The experimental data of velocity and decibel change from the temperature range provide a reference for the future when dealing with unknown materials information on site that requires a quick corrosion status determination.
Petrochemical plants use on-stream inspection often to detect and monitor the corrosion on the equipment and piping system. Compared to ultrasonic thickness gauging and pulse-echo A-scan, phased array corrosion mapping has better coverability and can scan a large area to detect general and localized corrosion. This paper's objective is to obtain documentary evidence for the accuracy of corrosion detection from 30 °C to 250 °C on A36 low-carbon steel by carrying out simulation experiments every 10 °C step. A minimum of three sets of phased array corrosion mapping data in each temperature were collected to study and evaluate the detectability. The data evidence could enhance the confidence level of the plant's end users in using phased array mapping in the future during inspections. The experiments were found to be insufficiently thorough despite addressing the initial concerns, leaving more area for discussion in further studies, such as expanding the investigation to thicker carbon steel, stainless steel, and wedge materials.
Thermoplastic starch is a material that has the potential to be environmentally friendly and biodegradable. However, it has certain drawbacks concerning its mechanical performance and is sensitive to the presence of moisture. The current study assessed agar-containing thermoplastic sago starch (TPSS) properties at various loadings. Variable proportions of agar (5%, 10%, and 15% wt%) were used to produce TPSS by the hot-pressing method. Then, the samples were subjected to characterisation using scanning electron microscopy (SEM), mechanical analysis, differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), Fourier transform infrared spectroscopy (FT-IR), and moisture absorption tests. The results demonstrated that adding agar to starch-based thermoplastic blends significantly improved their tensile, flexural, and impact properties. The samples' morphology showed that the fracture had become more erratic and uneven after adding agar. FT-IR revealed that intermolecular hydrogen bonds formed between TPSS and agar. Moreover, with an increase in agar content, TPSS's thermal stability was also increased. However, the moisture absorption values among the samples increased slightly as the amount of agar increased. Overall, the proposed TPSS/agar blend has the potential to be employed as biodegradable material due to its improved mechanical characteristics.
Every year, structural flaws or breakdowns cause thousands of people to be harmed and cost billions of dollars owing to the limitations of design methods and materials to withstand extreme earthquakes. Since earthquakes have a significant effect on sustainability factors, there is a contradiction between these constraints and the growing need for more sustainable structures. There has been a significant attempt to circumvent these constraints by developing various techniques and materials. One of these viable possibilities is the application of smart structures and materials such as shape memory and piezoelectric materials. Many scholars have examined the use of these materials and their structural characteristics up to this point, but the relationship between sustainability considerations and the deployment of smart materials has received little attention. Therefore, through a review of previous experimental, numerical, and conceptual studies, this paper attempts to draw a more significant relationship between smart materials and structural sustainability. First, the significant impact of seismic events on structural sustainability and its major aspects are described. It is then followed by an overview of the fundamentals of smart material's behaviour and properties. Finally, after a comprehensive review of the most recent applications of smart materials in structures, the influence of their deployment on sustainability issues is discussed. The findings of this study are intended to assist researchers in properly addressing sustainability considerations in any research and implementation of smart materials by establishing a more explicit relationship between these two concepts.
Currently, pultruded glass fibre-reinforced polymer (pGFRP) composites have been extensively applied as cross-arm structures in latticed transmission towers. These materials were chosen for their high strength-to-weight ratio and lightweight characteristics. Nevertheless, several researchers have discovered that several existing composite cross arms can decline in performance, which leads to composite failure due to creep, torsional movement, buckling, moisture, significant temperature change, and other environmental factors. This leads to the composite structure experiencing a reduced service life. To resolve this problem, several researchers have proposed to implement composite cross arms with sleeve installation, an addition of bracing systems, and the inclusion of pGFRP composite beams with the core structure in order to have a sustainable composite structure. The aforementioned improvements in these composite structures provide superior performance under mechanical duress by having better stiffness, superiority in flexural behaviour, enhanced energy absorption, and improved load-carrying capacity. Even though there is a deficiency in the previous literature on this matter, several established works on the enhancement of composite cross-arm structures and beams have been applied. Thus, this review articles delivers on a state-of-the-art review on the design improvement and mechanical properties of composite cross-arm structures in experimental and computational simulation approaches.
A photodetector converts optical signals to detectable electrical signals. Lately, self-powered photodetectors have been widely studied because of their advantages in device miniaturization and low power consumption, which make them preferable in various applications, especially those related to green technology and flexible electronics. Since self-powered photodetectors do not have an external power supply at zero bias, it is important to ensure that the built-in potential in the device produces a sufficiently thick depletion region that efficiently sweeps the carriers across the junction, resulting in detectable electrical signals even at very low-optical power signals. Therefore, two-dimensional (2D) materials are explored as an alternative to silicon-based active regions in the photodetector. In addition, plasmonic effects coupled with self-powered photodetectors will further enhance light absorption and scattering, which contribute to the improvement of the device's photocurrent generation. Hence, this review focuses on the employment of 2D materials such as graphene and molybdenum disulfide (MoS2) with the insertion of hexagonal boron nitride (h-BN) and plasmonic nanoparticles. All these approaches have shown performance improvement of photodetectors for self-powering applications. A comprehensive analysis encompassing 2D material characterization, theoretical and numerical modelling, device physics, fabrication and characterization of photodetectors with graphene/MoS2 and graphene/h-BN/MoS2 heterostructures with plasmonic effect is presented with potential leads to new research opportunities.