Ocean sediments give information on the paleoclimatic evolution in the geological past which gives detailed information on both the age of the sediments and both paleoceanographic and paleoclimatic conditions during sedimentation. One possible way to date sediments is with 210Pb method which can be used to date sediments up to 100 years. In this study, two core samples labelled as JB15 and JB17 were collected using pledging corer, analysed and measured for the activity of 209Po and 210Po using the alpha spectrometer. Applying the methods, average sedimentation rates for JB15 and JB17 were calculated as 0.38 cmyr-1 and 0.43 cmyr-1, respectively. Assuming that the sedimentation rate values are accurate, this might imply that the sediments at the depth of 30 cm were deposited 70 years ago.
Stone Mastic Asphalt (SMA) is one type of asphalt mixture which is highly dependent on the method
of compaction as compared to conventional Hot Mix Asphalt (HMA) mixture. A suitable laboratory compaction method which can closely simulate field compaction is evidently needed as future trend
in asphalt pavement industry all over the world is gradually changing over to the SMA due to its excellent performance characteristics. This study was conducted to evaluate the SMA slab mixtures compacted using a newly developed Turamesin roller compactor, designed to cater for laboratory compaction in field simulation conditions. As the newly developed compaction device, there is a need for evaluating the compacted slab dimensions (which include length, width, and thickness), analyzing the consistency of the measured parameters to verify the homogeneity of the compacted slabs and determining the reliability of Turamesin. A total of 15 slabs from three different types of asphalt mixtures were compacted, measured, and analyzed for their consistencies in terms of length, width, and thickness. Based on study the conducted, the compacted slabs were found to have problems in terms of the improperly compacted section of about 30 mm length at both ends of the slabs and the differences in the thickness between left- and right-side of the slab which were due to unequal load distribution from the roller compactor. The results obtained from this study have led to the development of Turamesin as an improved laboratory compaction device.
The present conventional (destructive) method used in determining LAI is laborious, difficult and time consuming. Thus, an image-based measurement using camera system with fish eye lens offers an alternative means for an accurate indirect measurement of LAI in oil palm. In this study, a methodology was developed to improve the leaf area index of the oil palm determination using hemispherical photography as an indirect method. A set of true LAI data, collected using the destructive method, were used as a reference to calibrate the LAI measurements obtained by the hemispherical photography. A good relationship (r = 0.85) was found between age of palm and hemispherical photographic LAI. However, the estimated LAI obtained by the hemispherical photographic method was underestimated as compared to the destructive method. Some means of calibration was necessary to determine the relationship between the actual LAI and the hemispherical photographic LAI. It was necessary to multiply the LAI value from 5 years to 16 years, by a clumping factor of 2.14 for 5 to 9 year old palms, 2.33 for 10 to 14-year old palms and 2.37 for above 15- year old palms to calculate the accurate LAI values. For palms which are less than 5 year old (i.e. 2 to 3 years in this study), the photography LAI value was equal to the calculated LAI value. This proposed that correction factors would solve this underestimation effect. In addition, two equations were also proposed to estimate the true LAI from the Photographic LAI for immature and mature oil palm plantation.
Proper integrated management of a dam reservoir requires that all components of the water resource system be known. One of these components is the daily reservoir inflow which is the subject matter of this study, i.e. to establish predictions of what is coming in the next rainfall-runoff process over a catchment. The transformation of rainfall into runoff is an extremely complex, dynamic, and more of a non-linear process. The available six-year average daily rainfall data across the Sembrong dam catchment were computed using the well-known Theissen’s polygon method. Daily reservoir inflow data were extracted by applying the water balance model to the Sembrong dam reservoir. Modelling of relationship between rainfall and reservoir inflow data was done using feed-forward back-propagation neural networks. The final selected model has one hidden layer with 11 neurons in the hidden layer. The selected model was applied for an independent data series testing. Results in relation to specific climatic and hydrologic properties of a small tropical catchment suggested that the model is suitable to be used in forecasting the next day’s reservoir inflow. The efficiencies of the model Abtained indicated the validity of using the neural network for modelling reservoir inflow series.
An attempt was made in this investigation to trace the dynamic response of roller compacted concrete dam, which is subjected to horizontal ground motion by considering the interactions between flexible foundations, reservoir water, and bottom reservoir sediments. Two-dimensional finiteinfinite element was used for the non-linear elasto-plastic dynamic analysis. In this analysis, special emphasis was given to the non-linear behaviour of discontinuities along RCC dam-bedding rock foundation which was modelled by thin layer interface. Analysis was first carried out under static loading (self-weight and hydrostatic pressure), and this this was followed by seismic analysis, with hydrodynamic pressure effect in a dam-reservoir system. Based on the numerical dynamic results, it is concluded that the bottom reservoir sediment has significant effect on the seismic response of the RCC gravity dam. Moreover, there is a redistribution of the stresses at thin layer interface with significant stresses reduction, which is resulted from the release of energy through different modes of deformation in this region.
This paper presents investigations into the development of control schemes for end-point vibration
suppression and input tracking of a flexible manipulator. A constrained planar single-link flexible manipulator is considered and the dynamic model of the system is derived using the assumed mode method. To study the effectiveness of the controllers, a Linear Quadratic Regulator (LQR) was initially developed for control of rigid body motion. This is then extended to incorporate a noncollocated PID controller and a feedforward controller based on input shaping techniques to control vibration (flexible motion) of the system. For feedforward controller, positive and modified specified negative amplitude (SNA) input shapers are proposed and designed based on the properties of the system. Results from the simulation of the manipulator responses with the controllers are presented in time and frequency domains. The performances of the control schemes are assessed in terms of level of vibration reduction, input tracking capability and time response specifications. Finally, a comparative assessment of the control techniques is presented and discussed.
Our continuing interest in anthraquinones from the Guttiferae family has led us to look at the genus Cratoxylum. A detailed chemical study on Cratoxylum aborescens resulted in the isolation of three anthraquinones, namely 1,8-dihydroxy-3-methoxy-6-methylanthraquinone (1), vismiaquinone (2) and vismione (3). These compounds were identified using 1D and 2D NMR spectroscopy. This is the first report on the chemistry of Cratoxylum aborescens.
A series of batch laboratory studies were conducted to investigate the suitability of activated carbon SA2 for the removal of cadmium ions and zinc ions from their aqueous solutions. The single component equilibrium data were analyzed using the Langmuir and Freundlich isotherms. Overall, the Langmuir isotherm showed a better fitting for all adsorptions under investigation in terms of correlation coefficient and error analysis (SSE only 18.2 for Cd2+ and 47.95 for Zn2+). As the binary adsorption is competitive, extended Langmuir models could not predict the binary component isotherm well. The modified extended Langmuir models were used to fit the binary system equilibrium data. The binary isotherm data could be described reasonably well by the modified
extended Langmuir model, as indicated in the error analysis.
Polyaniline (PANI) and polyaniline composites with aluminium oxide (Al2O3) were prepared using the in situ polymerization method. The composites were then blended with acrylic paint and applied to carbon steel panels. The coated steel panels were evaluated for corrosion using the immersion test technique. The results revealed that the steel panels coated with polyaniline composites and with Al2O3 containing coatings had small corrosion as compared to the bare sample and the samples coated with polyaniline and paint alone. The samples were characterized by Fourier transform infrared (FTIR) and X-ray diffraction(XRD). In addition, the morphology of the finished samples was observed using the scanning electron microscopy (SEM). This novel composite was used as a paint pigment for enhancing the barrier properties and the paint protectable against aggressive ions. Meanwhile, corrosion was evaluated through visual monitoring using a digital camera after 60 days of fully immersion test in 5% NaCl. The weight loss method was also used to evaluate corrosion.
This study was conducted for the development of the green protection garments. For this purpose, laminate composite material was developed from Kevlar 29-ramie-unsaturated polyester resin. The aim of this study was to develop a solid body armour that meets the specific requirements of ballistic resistance. This composite is subjected to high impact loading. The target was shot using gas gun machine that is supported by camera hardware to capture the projectile speed. In order to achieve the goal of the research, several experiments were conducted with the aim to estimate the ballistic limit, maximum energy absorption, composite failure mode, life time rupture, target geometry, and environmental effect. The results of these experiments indicated that the maximum ballistic limit validated at impact speed is in the range of 250 m/s to 656.8 m/s for the second protection level. The targets are improved in term of the impact response with the increase in the relative humidity, i.e. the range of 50% ± 20%, whereas, reduction of resistance results in the increase of temperature. The range of temperatures was between 20oC and 70oC. A limited delamination was generated under multiple shots. Targets geometry plays a major role in increasing the impact response. Hence, the results present a high resistant impact for pairs from the panels with total thickness arrived to 15
mm ± 3 mm. This body armour is one of the most economical armour products, in which common materials are used in its production, particularly to reduce the amount of Kevlar, and this could further lead to a decrease in its production cost. On the other hand, this armour meets the ballistic threats under 623 m/s of 15 mm ± 3 mm target thickness and 837.5 m/s of 25 mm ± 2.mm. Thus, the armour is equivalent to the third level of protective ballistic limits in the National Institute of Justice (NIJ) standards.
The physical properties by natural fibre have a great importance, specifically in the structural of natural fibre which reinforces matrix. Response surface methodology with Box-Behnken (BB) design of experiment was utilized to study water absorption and melt flow index (MFI) of abaca fibre reinforced high impact polystyrene (HIPS) composites. The design utilizes fraction of weight abaca fibre, maleic anhydride (MAH), and impact modifier to develop models for characteristic behaviours of water absorption and MFI of composites. Abaca fibre reinforced high impact polystyrene (HIPS) composites were produced with different fibre loadings (30, 40, and 50 wt%), different compositions of coupling agent, maleic anhydried (MAH) (1, 2, and 3 wt%) and different compositions of impact modifier (4, 5, 6 wt%). The individual optimum of water absorption was found when loading abaca fibre close to 34.61 wt%, maleic anhydride 1 wt%, and impact modifier 4.01 wt%. The individual optimum of melt flow index dealt with loading abaca fibre 36.71 wt%, maleic anhydride 3 wt% and impact modifier 4.02 wt%. Meanwhile, the optimum condition for water absorption of abaca fibre reinforced HIPS composites was followed by a decreasing trend of the value of melt flow index.
This work was carried out with the aim to optimise the tool path by simulating the removal of material in a finite element environment which is controlled by a genetic algorithm (GA). To simulate the physical removal of material during machining, a finite element model was designed to represent a thin walled workpiece. The target was to develop models which mimic the actual cutting process using the finite element method (FEM), to validate the developed tool path strategy algorithm with the actual machining process and to programme the developed algorithm into the software. The workpiece was to be modelled using the CAD (ABAQUS CAE) software to create a basic geometry co-ordinate system which could then be used to create the finite element method and necessary requirement by ABAQUS, such as the boundary condition, the material type, and the element type.
A hybrid composite consisting of untreated kenaf fibre and glass fibre was investigated by varying the fibre glass weight ratios and using interply fabrication method. The expected results were to have better composite performance in terms of its toughness and impact strength as a comparison between the hybrid (kenaf/E-glass fibre composites) and E-GF composites alone. For the purpose of this study, all the samples were prepared using typical sample preparation. Results show that the incorporation of E–glass fibre resulted in brittle failure and a higher amount of E-Glass fibre with low percentage of kenaf fibre causing high strength, low ductile, and low toughness behaviours.
A study of kaolin addition in polypropylene (PP-kaolin) melt was carried out to characterize its flow behaviour and viscoelasticity at different temperatures. The compound of 20 wt% kaolin was prepared by melt mixing using two roll-mill heated at 185°C, while the compounded composites were put through a single screw extruder to evaluate its melt flow properties. The prepared PPKaolin composites exhibited a shear thinning behaviour and appeared to be strongly dependent on temperature. Moreover, it was also found that the power law index was constantly increased as the temperature increased. Meanwhile, a similar trend was observed for swelling ratio, whereby it also increased with increasing temperature. It was also observed that changes in the die temperatures would result in the formation of obvious bubble like surface morphology, and it became more prominent when the temperature was lowered.
An experimental study was performed to determine the drying characteristics of dried papaya using different drying methods. They were dried using several methods, such as sun drying, solar drying, oven drying, and microwave drying. The effects of different operating conditions on physical quality attributes were investigated. The papaya were cut into different thicknesses and cooked in sugar syrup with different sugar concentration for 24 hours. Three different temperature settings were used in oven and microwave drying. The drying curve and drying rate of each method, temperature, sample
thickness and sugar concentration were studied. The drying times were found as in 6-15 minutes, 5 to 11 h, 10 to 18 h, and 14 to 23 h for the microwave, oven, sun and solar drying, respectively. The drying time increased with the increase of sample thickness and sugar concentration, as well as with the decrease of the drying temperature. In this study, quality attributes like colours and textural property of dried papaya were explored. Among the various methods of the drying characteristics
of papaya halwa, oven drying was preferred with the optimum sample in 5 mm thickness and at the air temperature of 70ºC as it saved up to 40% of the drying time as compared to other methods, except microwave, and produced acceptable physical quality of product.
Controller tuning is needed to select the optimum response for the controlled process. This work presents a new tuning procedure of PID controllers with safety and response quality measures on a non-linear process model by optimization procedure, with a demonstration of two tanks in series. The model was developed to include safety constraints in the form of path constraints. The model was then solved with a new optimization solver, NLPOPT1, which uses a primal-dual interior point method with a novel non-monotone line search procedure with discretized penalty parameters. This procedure generated a grid of optimal PID tuning parameters for various switching of steadystates to be used as apredictor of PID tunings for arbitrary transitions. The interpolation of tuning parameters between the available parameters was found to be capable to produce state profiles with no violation on the safety measures, while maintaining the quality of the solution with the final set points targeted achievable.
Xylitol can be obtained from lignocellulosic materials containing xylose. However, the fraction of lignocellulose converted through dilute acid hydrolysis contains compounds that inhibit the fermenting micro-organisms. These inhibitors can be removed from the hydrolysate by detoxification method, prior to fermentation. This study describes effectiveness of overliming process to reduce the toxicity of hydrolysates generated from pre-treatment of sago trunk for xylitol production. The overliming pH 9 and 10 was studied and the results showed that pH 9 was showed 20% of sugar loss, which is low compared to pH 10. Candida tropicalis strain was used to evaluate the fermentability of overlimed sago trunk hydrolysate at pH 9 and non-overlimed hydrolysate medium. Meanwhile, Xylitol accumulation and productivity in the overlimed medium was found to be higher than the non-treated medium. The maximum production of xylitol was increased up to 74% and converted within 76 h. The results obtained improved the fermentation process when compared with the nontreated medium.
Yeast producing alcohol dehydrogenase 1 (YADH 1) enzyme has been used as a biocatalyst for the synthesis of an optically active flavouring compound known as citronellol. However, the slow growth of yeast (Saccharomyces cerevisiae) has deterred the progress of biotransformation. The main purpose of this work is to clone the genes producing YADH1 enzyme from yeast into a faster growing bacteria, Escherichia coli. Initially, the sequence of the gene encoding this protein has been identified in the S. cerevisiae Genome Databases (SGD). The so-called Yadh1 gene sequence is located from coordinate 159548 to 160594 on chromosome XV of yeast. Based on this information, two primer sequences (Forward and Reverse) were constructed. Each of these primers will bind to either end of the Yadh1 gene. The Yadh1 gene was then amplified using Polymerase Chain Reaction (PCR) technique. The amplified Yadh 1 gene was successfully cloned into a cloning vector, TOPO TA plasmid. This plasmid also contains a gene which confers resistance to ampicillin. This recombinant
plasmid was then inserted into Escherichia coli TOP 10 using heat shock protocol at 42oC. Finally, the cloned bacteria containing the recombinant TOPO TA plasmid harbouring Yadh1 gene was able to grow on Luria Bertani (LB) media supplied with antibiotic.
A Boolean permutation is called nonlinear if it has at least one nonlinear component function. All nonlinear Boolean permutations and their complements are called non-affine Boolean permutations. Any non-affine Boolean permutation is a potential candidate for bijective S-Box of block ciphers. In this paper, we find the number of n-variable non-affine Boolean permutations up to multiplicative n and show a simple method of construction of non-affine Boolean permutations. However, non-affinity property is not sufficient for S-Boxes. Nonlinearity is one of the basic properties of an S-Box. The nonlinearity of Boolean permutation is a distance between set of all non-constant linear combinations of component functions and set of all non-affine Boolean functions. The cryptographically strong S-Boxes have high nonlinearity. In this paper, we show a method of construction of 8-variable highly nonlinear Boolean permutations. Our construction is based on analytically design (8, 1), (8, 2), and (8, 3) highly nonlinear vectorial balanced functions and random permutation for other component functions.
The partial integrals of the N-fold Fourier integrals connected with elliptic polynomials (not necessarily
homogeneous; principal part of which has a strictly convex level surface) are considered. It is proved that if a + s > (N – 1)/2 and ap = N then the Riesz means of the nonnegative order s of the N-fold Fourier integrals of continuous finite functions from the Sobolev spaces Wpa (RN) converge uniformly on every compact set, and if a + s > (N – 1)/2 and ap = N, then for any x0 ∈ RN there exists a continuous finite function from the Sobolev space such, that the corresponding Riesz means of the N-fold Fourier integrals diverge to infinity at x0. AMS 2000 Mathematics Subject Classifications: Primary 42B08; Secondary 42C14.