Conducting polypyrrole (PPy) nanoparticles were synthesized by chemical oxidative polymerization of pyrrole in aqueous solution containing ferric sulfate (Fe2(SO4)3), anionic surfactants (sodium dodecylbenzene-sulfonate (NaDBS) or sodium dodecyl sulfate (SDS)), 1-pentanol as the oxidant, dopant and co-emulsifier, respectively. The polymerization was carried out at 0 ºC and 25 ºC. Fourier transform infrared spectroscopy (FTIR) and elemental analysis indicated that anionic surfactants were successfully incorporated into the PPy backbone. Incorporation of anionic surfactants caused enhanced electrical conductivity, increased yield, decreased the size of particles as well as improved the thermal stability of the resultant PPy. The presence of anionic surfactant seems to inhibit undesirable side reactions so as to improve the regularity of the PPy backbone. Globular PPy particles were obtained with diameter ranged from 40 to 118 nm as revealed by field emission scanning electron microscopy (FE-SEM) and conductivity of 7.89×10-4 –2.35×10-2 S cm-1, as measured using impedance analyzer. It was found that polymerization at low temperature (0 ºC) produced PPy particles with smaller size and higher conductivity. The sodium dodecyl sulfate-doped PPy (SDS-doped PPy) exhibited higher conductivity than that of the sodium dodecylbenzenesulfonate-doped PPy (NaDBS-doped PPy), due to the bulkiness of NaDBS as compared to SDS.
Many residential areas of Kuala Lumpur are susceptible to landslides; this is seen in the frequency of landslide occurences in these areas. The objective of this study is to delineate landslide risk areas in support of development planning, monitoring and control of unstable areas. In this study, five landslide causative factors were extracted from satellite imagery and maps provided by the Geological Survey Department of Malaysia. Factors included in the study including land use, river density and lineament derived from Landsat ETM image, precipitation amount from rain gauge stations and lithology, were extracted from the geological map of the study area. Layers were analyzed and divided into subclasses. An average weightage score was applied to calculate the subclasses into percentage weights of influence on landslide. Overlay, geo-processing and geo-statistic techniques in GIS were used to discriminate these weighted subclasses into landslide susceptibility at low, medium and high levels of risk areas. Results showed very high susceptible areas covering 0.21% of Kuala Lumpur of which 5.02% were found in the highly urbanized areas. Meanwhile, a landslide susceptibility map was generated to show low, medium and high susceptible areas in Kuala Lumpur. Results were verified using recorded cases of landslides in Kuala Lumpur which showed a 77% agreement with the study.
In this study a GIS model was developed and spatial analytical techniques performed to identify and select a suitable location for a waste transfer station in the sprawling suburban town of Petaling Jaya. The lack of a transfer station in urban centres of Malaysia has caused many problems and affects the efficiency of waste collection and disposal. With diminishing space for landfills and the increasing cost of solid waste management, the need for urban solid-waste recycling has become very important. However, finding a place for waste to be efficiently sorted before unwanted waste can be carried to disposal landfills has social and physical constraints. This study applies GIS techniques and analysis for site selection and identifies an acceptable area. In the model, environmental, physical and social constraints were taken into account, resulting in the selection of a potential area that is acceptable to the residents of the area because it is out of range of causing public nuisance and within minimum travelling distance for collection vehicles. The results show that the potential location for the transfer station should be in proximity of the industrial area of Petaling Jaya, allowing for the possible sale of recyclable materials to local industries. The location is also sited near a major highway to allow quick transportation of the rest of the unwanted waste to the landfill.
Recent rootkit-attack mitigation work neglected to address the integrity of the mitigation tool itself. Both detection and prevention arms of current rootkit-attack mitigation solutions can be given credit for the advancement of multiple methodologies for rootkit defense but if the defense system itself is compromised, how is the defense system to be trusted? Another deficiency not addressed is how platform integrity can be preserved without availability of current RIDS or RIPS solutions, which operate only upon the loading of the kernel i.e. without availability of a trusted boot environment. To address these deficiencies, we present our architecture for solving rootkit persistence – Rootkit Guard (RG). RG is a marriage between TrustedGRUB (providing trusted boot), IMA (Integrity Measurement Architecture) (serves as RIDS) and SELinux (serves as RIPS). TPM hardware is utilised to provide total integrity of our platform via storage of the aggregate of the clean snapshot of our platform OS kernel into TPM hardware registers (i.e. the PCR) – of which no software attacks have been demonstrated to date. RG solves rootkit persistence by leveraging on one vital but simple strategy: the mounting of rootkit defense via prevention of the execution of configuration binaries or build initialisation scripts. We adopted the technique of rootkit persistence prevention via thwarting the initialisation of a rootkit’s installation procedure; if the rootkit is successfully installed, proper deployment via thwarting of the rootkit’s
configuration is prevented. We had subjected the RG to 8 real world Linux 2.6 rootkits and the RG was successful in solving rootkit persistence in all 8 evaluated rootkits. In terms of performance, the RG introduced a maximum of 11% overhead and an average of 4% overhead, hence permitting deployment in production environments.
In the moving layer of particles with variable concentration, the shear estimation is not directly predictable and there is no existing clear mathematical or empirical formula to achieve this objective. This paper presents a developed approach to estimate the shear forces in a flow having suspended and moving layers of solid particles in liquid flow. The two-layer approach was taken whereby the flow consisting of one upper suspended layer of particles in the liquid, and the bottom layer was the moving bed of particles. In the present work, the method of finding the force acting on the pipe wall by the particles in the layer, termed as the ‘dry force’, was presented using a “pseudo hydrostatic pressure” method. To attain the equation for the dry force, a mathematical approach is taken with the assumptions that the flow is horizontal, two-phase pipe flow (solid in Newtonian liquid), incompressible and it is at steady-state. The analysis was conducted considering various particles densities, various concentrations in the suspended layer and different thicknesses of the moving bed. Changing the concentration in the suspended layer from 0.00001 up to 0.001 didn’t showed significant changes in the dry force evaluation. The dry friction force is increasing with increasing moving bed thickness. The developed mathematical model can be
applicable in solving for the shear force in horizontal solid liquid two-phase flows.
Link analysis algorithms for Web search engines determine the importance and relevance of Web pages. Among the link analysis algorithms, PageRank is the state of the art ranking mechanism that is used in Google search engine today. The PageRank algorithm is modeled as the behavior of a randomized Web surfer; this model can be seen as Markov chain to predict the behavior of a system that travels from one state to another state considering only the current condition. However, this model has the dangling node or hanging node problem because these nodes cannot be presented in a Markov chain model. This paper focuses on the application of Markov chain on PageRank algorithm and discussed a few methods to handle the dangling node problem. The Experiment is done running on WEBSPAM-UK2007 to show the rank results of the dangling nodes.
An AC to DC voltage rectifier and its respective regulator were designed and integrated on a 0.25μm CMOS process. Its input impedance was measured along with the regulated DC output. Input impedance of a series of rectangular coil microstrip antenna on FR4 PCB with outer dimension of 78mm x 41mm was measured. The positive reactance of the antenna was matched at resonance with negative reactance of the integrated rectifier and regulator with addition of external capacitor. Relationship between incidental electromagnetic field in A/m at the coil microstrip antenna all the way to the rectified DC voltage at the output of the regulator is presented. In the context of wireless power transfer, this work focuses on the remote unit that absorbs electromagnetic field generated by another system and converts the energy into DC supply voltage for remote device
The aim of this project is to produce electricity from citronella biomass using isolated microbes from wastewater as biocatalyst in a dual chamber microbial fuel cell (MFC). MFC is one such system that not only reduced biomass, which contains mostly waste products but can also liberate electricity from them. MFC system is well-established and using lignocellulosic biomass as fuel is one step to future energy generation. Trials of MFC experiments have been conducted but using citronella bagasse (CB) as fuel source. Furthermore, pre-treatment of the biomass was done using NaOH pre-treament and effluent treatment wastewater from a palm edible oil company as a source for microorganism. The end results indicate that bioelectricity production from CB is possible though very low yield in the present MFC.
Recently, there has been great interest on the applicability of Recycled Concrete Aggregate (RCA) as a new ecological construction material that can be sustainable in a gradually expanding construction industry. This paper reports the structural performance particularly on shear behaviour of high strength reinforced recycled concrete beams. Compressive cube strength of the tested beams ranged from 65-74 MPa at the age of 28-days. The experimental program compared conventional concrete mix with concrete mix having substitution of 25% recycled concrete aggregates of grade 25-30 MPa. In this study, three 150 mm x 200 mm x 1200 mm simply supported rectangular concrete beams in each mix were tested under a four-point bending static load with various shear span to effective depth ratios (a/d = 1.0, 1.5, 2.0). Subsequently, the shear behavior of the beams was investigated through studies of load-deflection responses, effect of a/d ratios and crack patterns. The test results reported that the substitution of 25% recycled concrete coarse aggregates barely affects the shear capacity of the high strength reinforced concrete beams with a/d of 1.5 onwards. Finally, experimental results were compared using existing design codes by ACI 318, Eurocode-2 and AS3600 which lie on the safe side.
The importance of numerical analysis in investigation of piled embankment over soft soil has been developed since 1990. Several investigators have extended the numerical analysis to model ground improvement using soil-column to support embankment or structures. This paper presents a numerical analysis of the Pulverized Fuel Ash (PFA) column-treated peat and compared with field static-loading test results. Back analysis was performed to determine the material parameters and soil stiffness surrounding soil & soil-column. Two geometrical models were used in this analysis: (a) block (Model A), and (b) column group (Model B). This situation was analyzed using commercially available finite element package PLAXIS 2D ver. 8.2. It is found that both models are reliable to simulate the field static-loading test for column-treated peat. Model B shows a higher stability to failure if compared to Model A.
The search for a high temperature lead-free solder replacement for high temperature leaded solder eutectic alloy has been an evolving process as the threat of a regional lead ban became a reality in July 2006. The advantages and disadvantages of lead-free solder in terms of manufacturing, performance and reliability have been increasingly revealed through companies’ Research and Development (R&D), industrial consortia and university researchers. Materials and component design are the primary criteria to focus on the development for the current generation of high temperature lead-free solder alloys. According to the current status of high temperature lead free soldering, there are many unsolved technical problems such as explanation on the lift-off phenomenon, establishment of high temperature lead-free plating technology, construction of a database of physical properties (solder, parts, PCBs), standardization of high temperature solder materials evaluation technology, and most importantly, the best candidate material for high temperature solder. Clearly, high temperature soldering is one of the unsolved problems of the century in lead-free soldering. Moreover, most of the questions still remain unanswered by researchers. This paper reviews research conducted on the Bi-Ag solder alloy, which is one of the candidate alloys that has been proposed as an alternative for high temperature lead-free solder.
Linear array of permutations is hard to be factorised. However, by using a starter set, the process of listing the permutations becomes easy. Once the starter sets are obtained, the circular and reverse of circular operations are easily employed to produce distinct permutations from each starter set. However, a problem arises when the equivalence starter sets generate similar permutations and, therefore, willneed to be discarded. In this paper, a new recursive strategy is proposed to generate starter sets that will not incur equivalence by circular operation. Computational advantages are presented that compare the results obtained by the new algorithm with those obtained using two other existing methods. The result indicates that the new algorithm is faster than the other two in time execution.
In this work, 10 mol% yttrium-doped ceria powders, Ce0.9Y0.1O1.95, were synthesised using a new mechanical technique, mechanochemical reaction, in which both impact action and shearing forces were applied for efficient fine grinding, subsequently leading to higher homogeneity of the resultant powders. Ce0.9Y0.1O1.95 prepared using this new technique was systematically compared with a sample of the same prepared using conventional solid-state methodology. X-ray diffraction analysis showed all prepared samples were single phase with a cubic fluorite structure. Generally, Y2O3-doped CeO2 electrolytes prepared by mechanochemical reactions were stable at a lower temperature (1100 °C) compared with a sample of the same synthesised using the conventional solid-state method. Characterisations using differential thermal analysis (DTA) and thermogravimetric analysis (TGA) showed no thermal changes and phase transitions, indicating all materials were thermally stable. The electrical properties of the samples investigated by AC impedance spectroscopy in the temperature range 200–800 ˚C are presented and discussed. Scanning electron microscopy (SEM) was used to study the morphology of the materials. Fine-grained powders with uniform grain-size distribution were obtained from the mechanochemical reaction.
This paper describes a study on the design, fabrication and testing of a prototype digging device for sweet potato tubers in bris soil. The soil texture was sandy soil (fine sand 94.53%), with mean moisture content of 9.16% and mean bulk density of 1.44 g-cm-3. The soil was prepared in a soil bin. Three types of soil digging tools were designed and fabricated to determine the optimum draft force. These were Flat or plane, V-shaped and Hoe type blades. Plane and V-shaped blades were 30 cm long, and 13 cm wide, while the Hoe type had three rods, 25 mm in diameter, 30 cm long and 6.5 cm wide with sharp cutting edge. The digging tools were tested in a soil bin filled with bris soil to determine the optimum draft force and area of soil disturbance. The results were analysed using statistical analysis of variance (ANOVA). Comparison between all blade types and blade depths to measured draft force and the area of soil disturbed showed that the highest draft of 0.54 kN-m-2 was caused by a flat or plane blade at the optimum depth of 20 cm when the area of soil disturbed was 0.180 m2 . The V-shaped blade had the mean draft of 0.51 kN-m-2, with area of soil disturbance of 0.185 m2 . Thebest choice was V-shaped blade with a rake angle of 30o at 20 cm. depth. The selected blade was fixed onto the sweet potato harvester and tested on bris soil planted with sweet potato of Telong and VitAto varieties. The harvesting efficiency of the machine in bris soil was 93.64% and 90.49% for Telong (Plot A) and VitAto (Plot B) varieties, respectively. The average ground speed and turning time during operation for plots A and B was 0.56 km-hr-1 and 102.7 s and 0.99 km-hr-1 and 81.22 s, respectively. The harvesting efficiencies for both plots showed no significant difference. The total productive time (harvesting time) and unproductive time (turning time) in plot A, at a tractor speed of 0.56 km.hr-1, was 14.8 hours for harvesting a hectare of sweet potato ( 0.068 ha.hr-1). In plot B, the total time for harvesting a hectare of sweet potato was 8.35 hours (0.12 ha.hr-1) at a tractor speed of 0.99 km.hr-1. The average harvesting time for both plots was 11.47 hr.ha-1. The average field work rate was 0.087 ha.hr-1 or 34 man-hr.ha-1 compared to manual harvesting of 150 man-hrs.ha-1.
Land development, especially construction works, increase storm water volumes and pollution loads into rivers and lakes. The temporary drainage system at construction sites, particularly during the construction stage discharges a large amount of pollutants that can damage the aquatic system of the receiving water bodies. The potential of vegetative swale to alleviate this problem was evaluated. The size of the constructed vegetative swale was 7cm deep, 400cm long and 15cm wide at the bottom, and 17cm wide at the top. The experiment was conducted batch wise by filling the storage tank with the run-off water from the construction site. The water was allowed to flow through a pipe into the retention basin to maintain uniform flow before it entered the swale. The study showed that the run-off infiltrated through the soil at a rate of 489.6 mm/hr. Samples of surface run-off and infiltration water were collected at the end and the bottom of the swale. The results indicate that chemical oxygen demand (COD), total suspended solid (TSS), turbidity, iron and zinc were reduced by 85.4%, 80.8%, 36.4%, 52.8% and 96.0%, respectively, by surface flow and 91.1%, 98.8%, 58.2% 55.5% and 98.1%, respectively, by infiltration. Removal of nitrate and phosphorus by the planted vegetation was 69.4% and 21.1%, respectively, by infiltration. However, nutrient removal by surface flow was negligible. In conclusion, the vegetative swale was able to improve the water quality of the storm water run-off from the construction site from Class V to Class III, according to the Interim National Water Quality Standards for Malaysia.
Liberica coffee is the most important coffee species grown in Malaysia. However, there is little or no research at all conducted on coffee berries and green coffee beans since the plant itself is a low income crop in Malaysia. Therefore, research on Malaysian Liberica coffee can help to increase the knowledge of coffee farmers and coffee manufacturers in the processing and handling of the coffee. Physical properties of Liberica coffee berries and beans were investigated the current study. The properties investigated include the size, mass, density, coefficient of friction, angle of repose, fracture force and colour. In comparison to Arabica and Robusta coffee, Liberica coffee has the biggest size, mass, true density and fracture force values but were lower in bulk density in both berries and beans. The Liberica berries and beans were found to be orange-ish and yellowish colour respectively. Angle of repose was low and approximately similar in berries and beans while jute fibre gave the highest friction to both Liberica berries and beans.
Autocorrelation problem causes unduly effects on the variance of Ordinary Least Squares (OLS) estimates. Hence, it is very essential to detect the autocorrelation problem so that appropriate remedial measures can be taken. The Breusch-Godfrey (BG) test is the most popular and commonly used test for the detection of autocorrelation. Since this test is based on the OLS estimates, which are not robust, it is easily affected by outliers. In this paper, we propose a robust Breusch-Godfrey (MBG) test which is not easily affected by outliers. The results of the study indicate that the MBG test is more powerful than the BG test in the detection of autocorrelation problem.
An audit of Diabetes Control and Management-Diabetes Registry Malaysia (ADCM-DRM) was started to monitor the provision of diabetes care in the country. A total of 20,646 patients were registered in the registry until 31st December 2008. This report set out to determine the Type 2 diabetes controls and treatment profiles of these cohorts of patients. This was a registry-based observational study conducted from May to December, 2008. An online standard case record form was available for site data providers to register their diabetic patients aged 18 years old and above annually. Demographic data, diabetes duration, treatment modalities, as well as various risk factors and diabetes complications were reported. Data were analyzed using Data Analysis and Statistical Software (Stata) version 9. A total of 81 centres, 6 of which were hospitals, participated in this registry until 31st December 2008, contributing a total of 20646 patients. A majority of them (99.2%) had Type 2 diabetes mellitus. The mean HbA1c was 8.0% (SD 2.10), with 30.1% and 17.9% of the patients who attained HbA1c < 7% and HbA1c < 6.5%, respectively. Metformin was prescribed more than sulfonylurea while only 11% had insulin. A review of the diabetic care policy and strategies in the primary health care clinics is needed to implement a more effective treatment of diabetes in this country.
The computer, together with Lab View software, can be used as an automatic data acquisition system. This project deals with the development of a computer interfacing technique for the study of Hall Effect and converting the existing automation system into a Web-based automation system. The drive board RS 217-3611 with PCI 6025E card and stepper motor RS191-8340 with a resolution of 0.1mm, was used to move a pair of permanent magnets backward and forward against the sample. The General Interface Bus (GPIB) card interfaces, together with digital nano voltmeter and Tesla meter using serial port RS232 interface, are used for measuring the potential difference and magnetic field strength respectively. Hall Effect measurement on copper (Cu) and tantalum (Ta) showed negative and positive sign Hall coefficient. Therefore, the system has electron and hole charge carriers respectively at room temperature. The parameters such as drift velocity, conductivity, mobility, Hall Coefficient and charge carrier concentration were also automatically displayed on the front panel of Lab View programming and compared with standard value. The Web-based automation system can be remotely controlled and monitored by users in remote locations using only their web browsers. In addition, video conferencing through Net Meeting has been used to provide audio and video feedback to the client.
This study was performed to evaluate the antifungal activities of methanolic fractions from the stem bark of Entada spiralis Ridl. against human dermatophytes and yeast-like fungus in vitro. Three types of human dermatophyte, Trichophyton mentagrophytes ATCC 9533, Microsporum gypseum ATCC 24102 and Trichophyton tonsurans ATCC 28942, and one yeast-like fungus, Candida glabrata ATCC 66032, were tested against the methanolic fractions labelled FA1, FA4 and FA5. T. mentagrophytes, T. tonsuran and M. gypseum were susceptible to all tested fractions in a concentration-dependent manner whereas C. glabrata was resistant. Fraction FA1 at a concentration of 400 mg/mL was found to exhibit the highest antifungal activity with the inhibition zone diameter of 22 mm (T. mentagrophytes). This fraction showed a minimum inhibitory concentration MIC of 0.097 mg/mL while the MIC value for the fraction FA4 and fraction FA5 was 3.12 mg/ml and 1.56 mg/ml respectively. Agar overlay bioautography assay results showed that most of the bioactive compounds were found in the fraction FA1. Based on these findings, it can be concluded that the stem bark extracts of E. spiralis can be a future source of potent natural antimicrobial drugs for superficial skin diseases.