In the past few years, solid liquid extraction (SLE) has shown greater potential in extraction of rare earth elements (REE) compared to liquid-liquid extraction (LLE). The objective of this study is to analyse the extraction behaviour of dysprosium (Dy) using the extractant immobilised resin (EIR) in SLE. In this study, the synergist activity between ionic liquid (1-ethyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide ([C2mim][NTf2]) or 1-butyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide ([C4mim][NTf2])) with conventional extractant of Aliquat 336 (A336) were investigated and the most effective synergist extractant (SE) was further immobilised onto resins (CR11, HP20 and SP207) to synthesise EIR. Inductively coupled plasma mass spectrometry (ICP-MS) was used to detect the concentration Dy before and after extraction. Fourier transform infrared spectroscopy (FTIR) and field emission scanning electron microscopy (FESEM) were used to characterise EIRs. From the study, [C2mim][NTf2] showed better compatibility with A336 since this SE (A336- [C2mim][NTf2]) gives higher extraction efficiency of Dy at 90% compared to A336- [C4mim][NTf2] with less than 11% efficiency. SLE using resins immobilised with A336- [C2mim][NTf2] proved that only EIR1 (CR11) can effectively extract Dy compared to EIR2 (HP20) and EIR3 (SP207). The porosity of CR11 was higher compared to other resins which made EIR1 very efficient in adsorbing Dy. Plus, using 0.1 g of EIR1, 100% of Dy was extracted from 5 mL of aqueous phase in SLE compared to 2 mL of aqueous phase in LLE. Conclusively, this research has the potential to improvise the conventional practise of LLE into SLE using EIR with reduction in the use of extractant.
Scholars have opined that the courtyard is a passive architectural design element and
that it can act as a microclimate modifier provided that its design requirements are not
ignored. But despite the assertions, empirical studies on the microclimatic
performance of a fully enclosed courtyard house and the non-courtyard house seems
to be deficient, and the assumption that the Courtyard is a passive architectural design
element needs to be substantiated. Therefore, the purpose of this study is to
investigate the microclimatic performance of a fully enclosed courtyard and noncourtyard
residential buildings. The main objective is to compare their microclimatic
performances in other to draw a conclusion on the best option. Three Hobo Weather
Data Loggers were used to collect climatic data in the buildings, and the third one was
situated in the outdoor area as a benchmark. The climatic variables investigated are;
air temperature and relative humidity. The fully enclosed courtyard residential building
is seen to have a better air temperature difference of 2 oC to 4 oC and the relative
humidity of 2 % to 6 %. In conclusion, the fully enclosed courtyard residential building
has confirmed a more favorable microclimatic performance, and future studies
towards its optimization are recommended.
The plug-in hybrid electric vehicle (PHEV) has received extensive attention due to the alternatives it provides for reducing the dependency on petroleum. Nowadays, many simulation software such as ADVISOR and AUTONOMIE, were built to help in PHEV research. In this paper, the effect of three main PHEV powertrains such as engine power, traction motor power and battery capacity on fuel consumption, electric consumption and carbon oxide emission is studied using AUTONOMIE. The simulation is designed and run using AUTONOMIE with example of commands used in MATLAB. The overall simulation results show that the fuel consumption decreases as the motor power increases with the same battery capacity and engine power. In additions, the simulation results also show that the electric and fuel consumptions are contrary to each other. Meanwhile, the carbon oxide emission and fuel consumption increase following each other’s.
Laterite soils are occasionally associated with geotechnical problems such as road deformation, erosion, settlement, dam seepage, slope instability, leachate permeation through hydraulic barriers, etc. Numerous soil improvement techniques were being applied to overcome these problems, including mixing the laterite soil with cements, limes, bitumen, chemicals, pozzolanas, etc. These additives may not be locally available and cheap, and could significantly increase the cost of construction. Likewise, in many cases, these stabilizing agents are not environmentally friendly. Different percentages of fines, sand and gravel in laterite soils exhibit different engineering characteristics and behaviour, making it difficult to obtain suitable and appropriate gradation for specific construction purposes. Thus, the essence of this review is to determine the fundamental engineering properties of laterite soil as a standalone material at different gradations to harness its potentiality for various construction purposes. It proposes step-by-step procedures on how to achieve a better soil by varying its gradation and moisture content. Laboratory testing in accordance with BS1377:1990 and ASTM D698 are adopted to examine the engineering characteristics with respect to hydraulic conductivity, shear strength, and volumetric shrinkage. In this experimental technique where molding water content and compaction energy are carefully controlled at different laterite gradations, the engineering design is anticipated to provide greater accuracy, safety, and sustainability.
Computer technology has become a very important element in an advanced manufacturing system. The good and systematic data model for the exchange of manufacturing information between different stages of development of product life cycle is paramount to ensure the product is manufactured and delivered to the market successfully. As a result, ISO 10303, an international standard, or well known as Standard for Exchange of Product Model Data (STEP) is not just for providing a neutral data format within the heterogenous CAD systems, its functionality has extended to the whole life cycle of product. STEP Part 21 is the first implementation method from EXPRESS modelling language and implemented successfully as neutral product data to integrate heterogeneous CAD platform. However, this CAD STEP Part21 text file is hardly to be applied in manufacturing processes since it consists of purely geometrical and topological data. In this research, a nonprocedural approach is presented to translate the EXPRESS language model of STEP CAD data into a new product database system model. A new nonprocedural approach of data enrichment and automated machining feature recognition is proposed and implemented on this newly developed product database system and provide a solution for the interrelated tasks of automated machining feature recognition: (1) extraction of geometrical feature from STEP CAD model data of the part (2) formation of part representation suitable for form feature identification (3) matching of form features. This paper proves the validity of this newly developed product database system by translating STEP Part21 file from a commercial CAD system to database system format, data enrichment, performing automated machining feature recognition and lastly generating STEP standard data according to AP224 for supporting STEP based process planning and manufacturing applications.
In this paper, the water driving cycle had been chosen to determine and compare the component sizing of conventional boat and Plug-in Hybrid Electric Recreational Boat (PHERB) powertrains. PHERB is an improvement on conventional boat to reduce the fuel consumption and emissions. The locations of water driving cycle in this research are at Pulau Kapas and Tasik Kenyir, Terengganu. Boat energy and power requirement was calculated according boat parameters, specifications and performance requirements to study the differences component sizing of conventional boat and PHERB powertrains. Power flow analyses are used to decide the size and capacity of main components for achieving the design specifications and requirements of conventional boat and PHERB powertrains. The results for PHERB powertrain requirement using steady state velocity are 20 kW at 3000 rpm for Internal Combustion Engine (ICE), 30 kW for Electric Machine (EM) and 5 kWh for Energy System Storage (ESS). The acquired results show that the PHERB gained the most existing powertrains and has extraordinary potential in applications to marine transportation in reducing fuel consumption and emission.